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Synthesis and luminescence properties of a novel UV-emitting phosphor Sr3P4O13:Ce3+

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Abstract

The ultraviolet (UV)-emitting Sr3P4O13:Ce3+ phosphors were synthesized via the solid-state reaction method, and their structural, morphological and luminescence properties were characterized by X-ray diffraction analysis, scanning electron microscopy, photoluminescence spectroscopy. The obtained results indicate that these phosphors can be effectively excited by short-wavelength ultraviolet (<300 nm), and exhibit long-wavelength ultraviolet (300–380 nm) emission with nanosecond-level fluorescence lifetime corresponding to the parity-allowed 5d–4f transitions of Ce3+. The concentration-quenching phenomenon of Ce3+ in Sr3P4O13 host was also studied, in which the critical energy transfer distance between Ce3+ ions and concentration quenching mechanism were determined.

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Acknowledgements

The work is financially supported by the National Natural Science Foundation of China (no. 21501153) and the Science and Technology Project of Henan Province (no. 142300410245).

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Correspondence to Bing Han or Hengzhen Shi.

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Han, B., Xue, Y., Liu, B. et al. Synthesis and luminescence properties of a novel UV-emitting phosphor Sr3P4O13:Ce3+ . J Mater Sci: Mater Electron 28, 4020–4024 (2017). https://doi.org/10.1007/s10854-016-6015-y

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