Abstract
In order to obtain well-dispersed CuO–SiO2 nanocomposites, we used a new synthesized Cu-nanocomplex, which was prepared by ultrasonic method. The CuO–SiO2 nanocomposites were synthesized by a sol–gel method. The as-synthesized products were characterized by XRD, TEM, SEM, and FT-IR techniques. Photo catalyst activity of the products was investigated by photodegradation of methylene blue dye test. The results show that CuO–SiO2 nanocomposites with high photocatalytic activity can be synthesized using the novel nanocomplex without addition any modifier. This new nanocomposite showed a high photocatalytic activity in comparing to previous reports.
Similar content being viewed by others
References
R. Mohammadzadeh Kakhki, Arab. J. Chem. (2014). doi:10.1016/j.arabjc.2014.11.058
R. Mohammadzadeh Kakhki, J. Incl. Phenom. Macrocycl. Chem. 82, 301–310 (2015)
R. Mohammadzadeh Kakhki, M. Rakhshanipour, Arab. J. Chem. (2015). doi:10.1016/j.arabjc.2015.07.012
G. Rounaghi, R. Mohammadadeh Kakhki, H. Azizi-toupkanloo, Mater. Sci. Eng. C 32, 172 (2012)
G. Rounaghi, R. Mohammadzadeh Kakhki, J. Electrochem. Soc. 158, F121 (2011)
G.H. Ronaghi, R. Mohammadzadeh Kakhki, H. Sadeghian, Electrochim. Acta 101, 9756 (2011)
R. Mohammadzadeh Kakhki, G. Rounaghi, Mater. Sci. Eng. C 31, 1637 (2011)
P.M. Ajayan, L.S. Schadler, P.V. Braun, Nanocomposites Science and Technology (Wiley, New York, 2003)
D.R. Ulrich, Prospects for sol-gel process. J. Non Cryst. Sol. 121, 465 (1990)
S.S. Fu, G.A. Samorijai, Role of medium-chain alcohols in interfacial films of nonionle microemulsion. J. Phys. Chem. 96, 4542 (1992)
Li Yue-ming, Liang Jing, Tao Zhan-liang, Chen Jun, CuO particles and plates: synthesis and gas-sensor application. Mater. Res. Bull. 43, 2380–2385 (2008)
H. Zhang, M. Zhang, Synthesis of CuO nanocrystalline and their application as electrode materials for capacitors. Mater. Chem. Phys. 108, 184–187 (2008)
T.I. Arbuzova, B.A. Gizhevskii, S.V. Naumov, A.V. Korolev, V.L. Arbuzov, K.V. Shal’nov, A.P. Druzhkov, Temporal changes in magnetic properties of high-density CuO nanoceramics. J. Magn. Magn. Mater. 258/259, 342–344 (2003)
P. Gao, Y. Chen, H. Lu, X. Li, Y. Wang, Q. Zhang, Synthesis of CuO nanoribbon arrays with noticeable electrochemical hydrogen storage ability by a simple precursor dehydration route at lower temperature. Int. J. Hydrog. Energy 34, 3065–3069 (2009)
T. Maruyama, Copper oxide thin films prepared by chemical vapor deposition from copper dipivaloylmethanate. Sol. Energy Mater. Sol. Cells 56, 85–92 (1998)
D. Barreca, P. Fornasiero, A. Gasparotto, V. Gombac, C. Maccato, T. Montini, E. Tondello, The potential of supported Cu2O and CuO nanosystems in photocatalytic H2 production. ChemSusChem 2(3), 230–233 (2009)
F. Orgaz, H. Rawson, Inorganic–organic composites by sol gel technology. J. Non Cryst. Solids 82, 390 (1986)
A.M. Buckley, M. Greebblatt, The preparation and characterization of silica gels. J. Non Cryst. Solids 146, 97 (1992)
A. Celzard, Application of the sol gel process using well-tested recipes. J. Chem. Educ. 79, 854–859 (2002)
A.P.L. Batista, H.W.P. Carvalho, G.H.P. Luz, P.F.Q. Martins, M. Gonçalves, L.C.A. Oliveira, Environ. Chem. Lett. 8, 63–67 (2010)
V. Niraimathi, A. Jerad Suresh, J. Jaisudha, Int. J. Pharma Sci. Res. 6(2), 459–462 (2015)
S. Esposito, M. Turco, G. Ramis, G. Bagnasco, P. Pernice, C. Pagliuca, M. Bevilacqua, A. Aronne, Cobalt–silicon mixed oxide nanocomposites by modified sol-gel method. J. Solid State Chem. 180, 3341 (2007)
J. Martinez, F. Ruiz, M. Gonzalez-Chavez, A. Valle-Aguilera, Mapeo structural de silica xerogel utilizando espectroscopia. Rev. Mex. Fis. 44, 575–581 (1998)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Mohammadzadeh Kakhki, R., Ahsani, F. & Mir, N. Enhanced photocatalytic activity of CuO–SiO2 nanocomposite based on a new Cu nanocomplex. J Mater Sci: Mater Electron 27, 11509–11517 (2016). https://doi.org/10.1007/s10854-016-5279-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-016-5279-6