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Photochemical properties of SnO2 nanorods arrays grown on nanoporous stainless steel

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Abstract

The synthesis and characterization of SnO2 nanomaterials have been extensively studied as photoelectrodes for the potential applications in optoelectronic devices. In this work, SnO2 nanorods arrays have been synthesized by hydrothermal method on the nanoporous surface of the anodized stainless steel. The prepared SnO2 nanorods of 1.3–1.4 µm in length and 250–350 nm in width, were uniformly distributed on the anodized stainless steel. This one-dimensional SnO2 nanostructure directly fabricated on the substrate provides an electron transfer pathway and a Schottky-type contact, resulting in improved photocatalytic and photoelectrochemical performance. The SnO2 nanorods arrays exhibit fast response towards H2O2 determination, producing a linear range from 100 to 3000 μM with a correlation coefficient of 0.984 and a sensitivity of 0.66 μA cm−2 mM−1. The results indicate the potential applications of SnO2 nanorods arrays as the non-enzymatic H2O2 sensor.

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References

  1. U. Hiroaki, Y. Masashi, K. Hiromitsu, Photoelectrochemical properties of Fe2O3–SnO2 films prepared by sol-gel method. J. Phys. Chem. C 115, 7050–7055 (2011)

    Article  Google Scholar 

  2. X.M. Zhou, W.Y. Fu, H.B. Yang, Y.N. Mu, J.W. Ma, L.C. Tian, B. Zhao, M.H. Li, Facile fabrication of transparent SnO2 nanorods array and their photoelectrochemical properties. Mater. Lett. 93, 95–98 (2013)

    Article  Google Scholar 

  3. X.Y. An, F. Teng, P. Zhang, C.H. Zhao, X.J. Pan, Z.X. Zhang, E.Q. Xie, Enhanced photoelectrochemical sensor based on ZnO-SnO2 composite nanotubes. J. Alloy. Compd. 614, 373–378 (2014)

    Article  Google Scholar 

  4. A. Biaggi-Labiosa, F. Sola, M. Lebron-Colon, L.J. Evans, J.C. Xu, G. Hunter, G.M. Berger, J.M. Gonzalez, A novel methane sensor based on porous SnO2 nanorods: room temperature to high temperature detection. Nanotechnology 23, 455501 (2012)

    Article  Google Scholar 

  5. W.J. Lee, M.H. Park, Y. Wang, J.Y. Lee, J. Cho, Nanoscale Si coating on the pore walls of SnO2 nanotube anode for Li rechargeable batteries. Chem. Commun. 46, 622–624 (2010)

    Article  Google Scholar 

  6. Y.G. Li, L. Qiao, D. Yan, L.L. Wang, Y. Zeng, H.B. Yang, Preparation of Au-sensitized 3D hollow SnO2 microspheres with an enhanced sensing performance. J. Alloy. Compd. 586, 399–403 (2014)

    Article  Google Scholar 

  7. D.D. Vuong, V.X. Hien, K.Q. Trung, N.D. Chien, Synthesis of SnO2 micro-spheres, nano-rods and nano-flowers via simple hydrothermal route. Physica E 44, 345–349 (2011)

    Article  Google Scholar 

  8. S.H. Jung, S.W. Choi, S.S. Kim, Fabrication and properties of trench-structured networked SnO2 nanowire gas sensors. Sensor Actuat. B-Chem. 171, 672–678 (2012)

    Article  Google Scholar 

  9. E.M. El-Maghraby, A. Qurashi, T. Yamazaki, Synthesis of SnO2 nanowires their structural and H2 gas sensing properties. Ceram. Int. 39, 8475–8480 (2013)

    Article  Google Scholar 

  10. S. Liu, B. Yu, F. Li, Y. Ji, T. Zhang, Coaxial electrospinning route to prepare Au-loading SnO2 hollow microtubes for non-enzymatic detection of H2O2. Electrochim. Acta 141, 161–166 (2014)

    Article  Google Scholar 

  11. A. Enesca, L. Andronic, A. Duta, Optimization of opto-electrical and photocatalytic properties of SnO2 thin films using Zn2+ and W6+ dopant ions. Catal. Lett. 142, 224–230 (2012)

    Article  Google Scholar 

  12. C.C. Lin, Y.J. Chiang, Preparation of coupled ZnO/SnO2 photocatalysts using a rotating packed bed. Chem. Eng. J. 181–182, 196–205 (2012)

    Article  Google Scholar 

  13. J. Kaur, J. Shah, R.K. Kotnala, K.C. Verma, Raman spectra, photoluminescence and ferromagnetism of pure, Co and Fe doped SnO2 nanoparticles. Ceram. Int. 38, 5563–5570 (2012)

    Article  Google Scholar 

  14. A.K.L. Sajjad, S. Shamaila, B.Z. Tian, F. Chen, J.L. Zhang, One step activation of WOx/TiO2 nanocomposites with enhanced photocatalytic activity. Appl. Catal. B-Environ. 91, 397–405 (2009)

    Article  Google Scholar 

  15. K. Zhang, W.Z. Wang, L. Yu, Y.J. Liang, G.L. Zhang, J.H. Xiao, Tailoring optical properties of TiO2 nanowires coated with Ag nanoparticles by plasmon coupling of Ag nanoparticles. Solid State Commun. 151, 2008–2011 (2011)

    Article  Google Scholar 

  16. Q.X. Yu, J.H. Zhu, Z.Y. Xu, X.T. Huang, Facile synthesis of α-Fe2O3@SnO2 core–shell heterostructure nanotubes for high performance gas sensors. Sensor. Actuat. B-Chem. 213, 27–34 (2015)

    Article  Google Scholar 

  17. J. Luo, Y. Ma, H.Y. Wang, J.Y. Chen, Preparation of polypyrrole sensitized TiO2 nanotube arrays hybrids for efficient photoelectrochemical water splitting. Electrochim. Acta 167, 119–125 (2015)

    Article  Google Scholar 

  18. M. Xu, P.M. Da, H.Y. Wu, D.Y. Zhao, G.F. Zheng, Controlled Sn-doping in TiO2 nanowire photoanodes with enhanced photoelectrochemical conversion. Nano Lett. 12, 1503–1508 (2012)

    Article  Google Scholar 

  19. T. ZhanW, H.W. Ni, R.S. Chen, Z.Y. Wang, C. Zhang, R. Lei, Tin oxide nanocrystals embedded in nanopore arrays on stainless steel surface for photocatalytic applications. Appl. Phys. A-Mater. 115, 1381–1386 (2014)

    Article  Google Scholar 

  20. W.T. Zhan, H.W. Ni, R.S. Chen, Z.Y. Wang, Y.W. Li, J.H. Li, One-step hydrothermal preparation of TiO2/WO3 nanocomposite films on anodized stainless steel for photocatalytic degradation of organic pollutants. Thin Solid Films 548, 299–305 (2013)

    Article  Google Scholar 

  21. M.Z. Li, Q. Zhou, Y.W.Y. Duan, Nanostructured porous platinum electrodes for the development of low-cost fully implantable cortical electrical stimulator. Sensor. Actuat. B-Chem. 221, 179–186 (2015)

    Article  Google Scholar 

  22. C.K. Chung, O.K. Khor, C.J. Syu, S.W. Chen, Effect of oxalic acid concentration on the magnetically enhanced capacitance and resistance of AAO humidity sensor. Sensor. Actuat. B-Chem. 210, 69–74 (2015)

    Article  Google Scholar 

  23. C.H. Zhao, W.Q. Hu, Z.X. Zhang, J.Y. Zhou, X.J. Pan, E.Q. Xie, Effects of SnO2 additives on nanostructure and gas-sensing properties of α-Fe2O3 nanotubes. Sensor. Actuat. B-Chem. 195, 486–493 (2014)

    Article  Google Scholar 

  24. M.T. Niu, F. Huang, L.F. Cui, P. Huang, Y.L. Yu, Y.S. Wang, Hydrothermal synthesis, structural characteristics, and enhanced photocatalysis of SnO2/α-Fe2O3 semiconductor nanoheterostructures. ACS Nano 4, 681–688 (2010)

    Article  Google Scholar 

  25. J. Cao, X. Li, H.L. Lin, B.Y. Xu, B.D. Luo, S.F. Chen, Low temperature synthesis of novel rodlike Bi5O7I with visible light photocatalytic performance. Mater. Lett. 76, 181–183 (2012)

    Article  Google Scholar 

  26. I.S. Cho, M. Logar, C.H. Lee, L.L. Cai, F.B. Prinz, X.L. Zheng, Rapid flame reduction of TiO2 nanowires for solar water-splitting. Nano Lett. 14, 24–31 (2014)

    Article  Google Scholar 

  27. Y.C. Pu, C.M. Wang, K.D. Chang, Y.C. Ling, Y.K. Ling, B.C. Fitzmorris, C.M. Liu, X. Lu, Y. Tong, J.Z. Zhang, Y.J. Hsu, Y. Li, Au nanostructure-decorated TiO2 Nanowires exhibiting photoactivity across entire UV–visible region for photoelectrochemical water splitting. Nano Lett. 13, 3817–3823 (2013)

    Article  Google Scholar 

  28. Z.H. Zhang, M.F. Hossain, T. Takahashi, Self-assembled hematite (α-Fe2O3) nanotube arrays for photoelectrocatalytic degradation of azo dye under simulated solar light irradiation. Appl. Catal. B-Environ. 95, 423–429 (2010)

    Article  Google Scholar 

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (Nos. 51471122, 51171133), the China Postdoctoral Science Foundation (2014M552092), a Special Financial Grant from the China Postdoctoral Science Foundation (2015T80842) and the Key program of Natural Science Foundation of Hubei Province of China (2015CFA128).

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Correspondence to Hongwei Ni.

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Zhan, W., Hu, W., Hu, L. et al. Photochemical properties of SnO2 nanorods arrays grown on nanoporous stainless steel. J Mater Sci: Mater Electron 27, 9989–9995 (2016). https://doi.org/10.1007/s10854-016-5069-1

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  • DOI: https://doi.org/10.1007/s10854-016-5069-1

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