Abstract
Copper vanadate compounds (abbreviated to CVO) were synthesized to accelerate the sinterability of (Zn0.7Mg0.3)TiO3 ceramics (abbreviated to ZMT). CVO-doped ZMT ceramics were prepared by a conventional mixed-oxide method. The phase structure, morphology and dielectric properties of ceramics were investigated. The results show that ZMT ceramics with 0.2 wt% CVO addition can be well sintered to approach 98 % theoretical density at 950 °C. At the same time, CVO addition inhibits the exaggerated grain growth and improves morphology of ceramics samples effectively. 0.2 wt% CVO doped ZMT ceramics sintered at 950 °C exhibits good microwave dielectric properties of ε r = 22 and Q × f = 11,700 GHz. Due to their good dielectric properties, low firing characteristics, 0.2 wt% CVO doped ZMT ceramics can serve as the promising high-frequency dielectric capacitor requiring low sintering temperature.
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References
W.-R. Yang, P.-Z. Huang, C.-L. Huang, Microwave dielectric properties of low-loss (Zn1−x Co x )3Nb2O8 ceramics for LTCC applications. J. Alloys Compd. 620, 18–23 (2015)
Y. Wu, D. Zhou, J. Guo, L.X. Pang, Microwave dielectric properties and low temperature sintering of Li2Zn(Ti1−x Sn x )3O8 (x ≤ 0.20) ceramics with B2O3–CuO addition. J. Mater. Sci. Mater. Electron. 24, 4942–4946 (2013)
C.-F. Tseng, P.-H. Chen, P.-A. Lin, Low temperature sintering and microwave dielectric properties of Zn0.5Ti0.5NbO4 ceramics with ZnO additive for LTCC applications. J. Alloys Compd. 632, 810–815 (2015)
E. Li, P. Zhang, S. Duan, J. Wang, Y. Yuan, B. Tang, Low temperature sintering of low-loss ZnTiO3 microwave dielectric ceramics with Zn–B–Si glass. J. Alloys Compd. 647, 866–872 (2015)
X.C. Liu, F. Gao, L.L. Zhao, C.S. Tian, Low-temperature sintering and phase transition of zinc titanate ceramics with V2O5 and B2O3 addition. J. Alloys Compd. 436, 285–289 (2007)
H.T. Kim, S. Nahm, J.D. Byun, Low-temperature sintering and microwave dielectric properties of zinc metatitanate–rutile mixtures using boron. J. Am. Ceram. Soc. 82, 3043–3048 (1999)
H.T. Kim, S. Nahm, J.D. Byun, J.D. Byun, Y. Kim, Low-fired (Zn, Mg)TiO3 microwave dielectrics. J. Am. Ceram. Soc. 82, 3476–3480 (1999)
Y.R. Wang, S.F. Wang, Y.M. Lin, Low temperature sintering of (Zn1−x , Mg x )TiO3 microwave dielectrics. Ceram. Int. 31, 905–909 (2005)
X.C. Liu, F. Gao, M. Zhao, C.S. Tian, Low-temperature sintering and dielectric properties of (Zn, Mg)TiO3 ceramics with V2O5 addition. Mater. Sci. Forum 546–549, 2215–2218 (2007)
M. He, H. Zhang, Microwave properties of low-fired Li2ZnTi3O8 ceramics doped with CuO–Bi2O3–V2O5. J. Alloys Compd. 586, 627–632 (2014)
W.W. Cho, K. Kakimoto, H. Ohsato, Microwave dielectric properties and low-temperature sintering of MgTiO3–SrTiO3 ceramics with B2O3 or CuO. Mater. Sci. Eng. B 121, 48–53 (2005)
Q.L. Zhang, H. Yang, Low-temperature firing and microwave dielectric properties of ZnO–Nb2O5–TiO2–SnO2 ceramics with CuO–V2O5. Mater. Res. Bull. 40, 1891–1898 (2005)
Y. Wu, D. Zhou, J. Guo, L.X. Pang, Microwave dielectric properties and low temperature firing of (1 − x)Li2Zn3Ti4O12–xLi2TiO3 (0.2 ≤ x ≤ 0.8) ceramics with B2O3–CuO addition. J. Mater. Sci.: Mater. Electron. 24, 1505–1510 (2013)
E.S. Kim, B.S. Chun, J.D. Kim, K.H. Yoon, Low-temperature sintering and microwave dielectric properties of [Ca0.6(Li0.5Nd0.5)0.4]0.45Zn0.55TiO3 ceramics. Mater. Sci. Eng. B99, 243–246 (2003)
X.C. Liu, M. Zhao, F. Gao, L.L. Zhao, C.S. Tian, Effects of WO3 additions on the phase structure and transition of zinc titanate ceramics. J. Alloys Compd. 450, 440–445 (2008)
X.C. Liu, F. Gao, L.L. Zhao, M. Zhao, C.S. Tian, Effects of V2O5 addition on the phase-structure and dielectric properties of zinc titanate ceramics. J. Electroceram. 18, 103–109 (2007)
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The work was supported by National Natural Science Foundation of China (Project 51372197) and the Scientific Research Program Funded by Shaanxi Provincial Education Department (Project 14JK1483).
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Liu, X., Zuo, C. Effect of copper vanadate sintering aid on the microstructure and dielectric properties of (Zn, Mg)TiO3 ceramics. J Mater Sci: Mater Electron 27, 5462–5467 (2016). https://doi.org/10.1007/s10854-016-4450-4
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DOI: https://doi.org/10.1007/s10854-016-4450-4