Skip to main content
Log in

Effect of copper vanadate sintering aid on the microstructure and dielectric properties of (Zn, Mg)TiO3 ceramics

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

Copper vanadate compounds (abbreviated to CVO) were synthesized to accelerate the sinterability of (Zn0.7Mg0.3)TiO3 ceramics (abbreviated to ZMT). CVO-doped ZMT ceramics were prepared by a conventional mixed-oxide method. The phase structure, morphology and dielectric properties of ceramics were investigated. The results show that ZMT ceramics with 0.2 wt% CVO addition can be well sintered to approach 98 % theoretical density at 950 °C. At the same time, CVO addition inhibits the exaggerated grain growth and improves morphology of ceramics samples effectively. 0.2 wt% CVO doped ZMT ceramics sintered at 950 °C exhibits good microwave dielectric properties of ε r  = 22 and Q × f = 11,700 GHz. Due to their good dielectric properties, low firing characteristics, 0.2 wt% CVO doped ZMT ceramics can serve as the promising high-frequency dielectric capacitor requiring low sintering temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. W.-R. Yang, P.-Z. Huang, C.-L. Huang, Microwave dielectric properties of low-loss (Zn1−x Co x )3Nb2O8 ceramics for LTCC applications. J. Alloys Compd. 620, 18–23 (2015)

    Article  Google Scholar 

  2. Y. Wu, D. Zhou, J. Guo, L.X. Pang, Microwave dielectric properties and low temperature sintering of Li2Zn(Ti1−x Sn x )3O8 (x ≤ 0.20) ceramics with B2O3–CuO addition. J. Mater. Sci. Mater. Electron. 24, 4942–4946 (2013)

    Article  Google Scholar 

  3. C.-F. Tseng, P.-H. Chen, P.-A. Lin, Low temperature sintering and microwave dielectric properties of Zn0.5Ti0.5NbO4 ceramics with ZnO additive for LTCC applications. J. Alloys Compd. 632, 810–815 (2015)

    Article  Google Scholar 

  4. E. Li, P. Zhang, S. Duan, J. Wang, Y. Yuan, B. Tang, Low temperature sintering of low-loss ZnTiO3 microwave dielectric ceramics with Zn–B–Si glass. J. Alloys Compd. 647, 866–872 (2015)

    Article  Google Scholar 

  5. X.C. Liu, F. Gao, L.L. Zhao, C.S. Tian, Low-temperature sintering and phase transition of zinc titanate ceramics with V2O5 and B2O3 addition. J. Alloys Compd. 436, 285–289 (2007)

    Article  Google Scholar 

  6. H.T. Kim, S. Nahm, J.D. Byun, Low-temperature sintering and microwave dielectric properties of zinc metatitanate–rutile mixtures using boron. J. Am. Ceram. Soc. 82, 3043–3048 (1999)

    Article  Google Scholar 

  7. H.T. Kim, S. Nahm, J.D. Byun, J.D. Byun, Y. Kim, Low-fired (Zn, Mg)TiO3 microwave dielectrics. J. Am. Ceram. Soc. 82, 3476–3480 (1999)

    Article  Google Scholar 

  8. Y.R. Wang, S.F. Wang, Y.M. Lin, Low temperature sintering of (Zn1−x , Mg x )TiO3 microwave dielectrics. Ceram. Int. 31, 905–909 (2005)

    Article  Google Scholar 

  9. X.C. Liu, F. Gao, M. Zhao, C.S. Tian, Low-temperature sintering and dielectric properties of (Zn, Mg)TiO3 ceramics with V2O5 addition. Mater. Sci. Forum 546–549, 2215–2218 (2007)

    Article  Google Scholar 

  10. M. He, H. Zhang, Microwave properties of low-fired Li2ZnTi3O8 ceramics doped with CuO–Bi2O3–V2O5. J. Alloys Compd. 586, 627–632 (2014)

    Article  Google Scholar 

  11. W.W. Cho, K. Kakimoto, H. Ohsato, Microwave dielectric properties and low-temperature sintering of MgTiO3–SrTiO3 ceramics with B2O3 or CuO. Mater. Sci. Eng. B 121, 48–53 (2005)

    Article  Google Scholar 

  12. Q.L. Zhang, H. Yang, Low-temperature firing and microwave dielectric properties of ZnO–Nb2O5–TiO2–SnO2 ceramics with CuO–V2O5. Mater. Res. Bull. 40, 1891–1898 (2005)

    Article  Google Scholar 

  13. Y. Wu, D. Zhou, J. Guo, L.X. Pang, Microwave dielectric properties and low temperature firing of (1 − x)Li2Zn3Ti4O12xLi2TiO3 (0.2 ≤ x ≤ 0.8) ceramics with B2O3–CuO addition. J. Mater. Sci.: Mater. Electron. 24, 1505–1510 (2013)

    Google Scholar 

  14. E.S. Kim, B.S. Chun, J.D. Kim, K.H. Yoon, Low-temperature sintering and microwave dielectric properties of [Ca0.6(Li0.5Nd0.5)0.4]0.45Zn0.55TiO3 ceramics. Mater. Sci. Eng. B99, 243–246 (2003)

    Google Scholar 

  15. X.C. Liu, M. Zhao, F. Gao, L.L. Zhao, C.S. Tian, Effects of WO3 additions on the phase structure and transition of zinc titanate ceramics. J. Alloys Compd. 450, 440–445 (2008)

    Article  Google Scholar 

  16. X.C. Liu, F. Gao, L.L. Zhao, M. Zhao, C.S. Tian, Effects of V2O5 addition on the phase-structure and dielectric properties of zinc titanate ceramics. J. Electroceram. 18, 103–109 (2007)

    Article  Google Scholar 

Download references

Acknowledgments

The work was supported by National Natural Science Foundation of China (Project 51372197) and the Scientific Research Program Funded by Shaanxi Provincial Education Department (Project 14JK1483).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Xiangchun Liu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Liu, X., Zuo, C. Effect of copper vanadate sintering aid on the microstructure and dielectric properties of (Zn, Mg)TiO3 ceramics. J Mater Sci: Mater Electron 27, 5462–5467 (2016). https://doi.org/10.1007/s10854-016-4450-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-016-4450-4

Keywords

Navigation