Skip to main content
Log in

Preparation of MoS2/RGO nano heterojunction and photoelectric property

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

In this work, we utilized hydrothermal treatment method to prepare a new type of nanomaterial MoS2/reduced graphene oxide (RGO) heterojunction with the graphite oxide assisted since it can provide the oxygen containing functional groups for MoS2 precusor to attach. The morphologies and microstructures of as prepared products are characterized by X-ray diffraction, transmission electron microscopy, scanning electron microscopy, Raman spectra and X-ray photoelectron spectroscopy. It is found that the MoS2 nanosheets have about seven layers which revealed the possibility of using RGO as an ideal support material for forming fewer layered MoS2 nanosheets. In addition, the obtained MoS2/RGO nano heterojunction exhibit preferable electrical conductivity and photocurrent response activity under the illumination of simulated sunlight compared to pure MoS2.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. C.N.R. Rao, H.S.S. Ramakrishna Matte, U. Maitra, Graphene analogues of inorganic layered materials. Angew. Chem. Int. Ed. 52(50), 13162–13185 (2013)

    Article  Google Scholar 

  2. A.K. Geim, I.V. Grigorieva, Van der Waals heterostructures. Nature 499(7459), 419–425 (2013)

    Article  Google Scholar 

  3. H.X. Liu, F.L. Tang, H.T. Xue, Y. Zhang, Y.D. Feng, Lattice structures and electronic properties of WZ-CuInS2/MoS2 interface from first-principles calculations. Appl. Surf. Sci. 351, 382–391 (2015)

    Article  Google Scholar 

  4. L. Zhou, H. Liu, X. Zhang, Graphene and carbon nanotubes for the synergistic reinforcement of polyamide 6 fibers. J. Mater. Sci. 50(7), 2797–2805 (2015)

    Article  Google Scholar 

  5. M.D. Stoller, S. Murali, N. Quarles, Y. Zhu, J.R. Potts, X. Zhu, H.W. Ha, R. Ruoff, S, Activated graphene as a cathode material for Li-ion hybrid supercapacitors. Phys. Chem. Chem. Phys. 14(10), 3388–3391 (2012)

    Article  Google Scholar 

  6. C. Ataca, M. Topsakal, E. Akturk, S. Ciraci, A comparative study of lattice dynamics of three-and two-dimensional MoS2. J. Phys. Chem. C 115(33), 16354–16361 (2011)

    Article  Google Scholar 

  7. X. Zhou, J. Jiang, T. Ding, J. Zhang, B. Pan, J. Zuo, Q. Yang, Fast colloidal synthesis of scalable Mo-rich hierarchical ultrathin MoSe2−x nanosheets for high-performance hydrogen evolution. Nanoscale 6(19), 11046–11051 (2014)

    Article  Google Scholar 

  8. M. Kan, J.Y. Wang, X.W. Li, S.H. Zhang, Y.W. Li, Y. Kawazoe, Q. Sun, P. Jena, Structures and phase transition of a MoS2 monolayer. J. Phys. Chem. C 118(3), 1515–1522 (2014)

    Article  Google Scholar 

  9. D. Yang, S.J. Sandoval, W.M.R. Divigalpitiya, J.C. Irwin, R.F. Frindt, Structure of single-molecular-layer MoS2. Phys. Rev. B 43(14), 12053 (1991)

    Article  Google Scholar 

  10. F. Liu, M. Liu, X. Shao, S. Yang, ZnS/graphene hybrid nanomaterials: synthesis, characterization, and enhanced electrochemical performances. J. Mater. Sci. Mater. Electron. 26(9), 6495–6501 (2015)

    Article  Google Scholar 

  11. K.H. Hu, X.G. Hu, X.J. Sun, Morphological effect of MoS2 nanoparticles on catalytic oxidation and vacuum lubrication. Appl. Surf. Sci. 256(8), 2517–2523 (2010)

    Article  Google Scholar 

  12. D. Voiry, M. Salehi, R. Silva, T. Fujita, M. Chen, T. Asefa, V.B. Shenoy, G. Eda, M. Chhowalla, Conducting MoS2 nanosheets as catalysts for hydrogen evolution reaction. Nano Lett. 13(12), 6222–6227 (2013)

    Article  Google Scholar 

  13. Y. Zhang, C. Pan, TiO2/graphene composite from thermal reaction of graphene oxide and its photocatalytic activity in visible light. J. Mater. Sci. 46(8), 2622–2626 (2011)

    Article  Google Scholar 

  14. R. Jiang, C. Cui, H. Ma, Using graphene nanosheets as a conductive additive to enhance the capacitive performance of α-MnO2. Electrochim. Acta 104, 198–207 (2013)

    Article  Google Scholar 

  15. C. Liu, Z. Yu, D. Neff, A. Zhamu, B.Z. Jang, Graphene-based supercapacitor with an ultrahigh energy density. Nano Lett. 10, 4863–4868 (2010)

    Article  Google Scholar 

  16. S. Konwer, A.K. Guha, S.K. Dolui, Graphene oxide-filled conducting polyaniline composites as methanol-sensing materials. J. Mater. Sci. 48(4), 1729–1739 (2013)

    Article  Google Scholar 

  17. K.K. Liu, W. Zhang, Y.H. Lee, Y.C. Lin, M.T. Chang, C.Y. Su, C.S. Chang, H. Li, Y. Shi, H. Zhang, C.S. Lai, L.J. Li, Growth of large-area and highly crystalline MoS2 thin layers on insulating substrates. Nano Lett. 12(3), 1538–1544 (2012)

    Article  Google Scholar 

  18. M.A. Lukowski, A.S. Daniel, F. Meng, A. Forticaux, L. Li, S. Jin, Enhanced hydrogen evolution catalysis from chemically exfoliated metallic MoS2 nanosheets. J. Am. Chem. Soc. 135(28), 10274–10277 (2013)

    Article  Google Scholar 

  19. Q. Ding, F. Meng, C.R. English, M. Cabán-Acevedo, M.J. Shearer, D. Liang, A.S. Daniel, R.J. Hamers, S. Jin, Efficient photoelectrochemical hydrogen generation using heterostructures of Si and chemically exfoliated metallic MoS2. J. Am. Chem. Soc. 136(24), 8504–8507 (2014)

    Article  Google Scholar 

  20. H.S. Lee, S.W. Min, Y.G. Chang, M.K. Park, T. Nam, H. Kim, J. Kim, S. Ryu, S. Im, MoS2 nanosheet phototransistors with thickness-modulated optical energy gap. Nano Lett. 12, 3695–3700 (2012)

    Article  Google Scholar 

  21. Y. Liu, H. Nan, X. Wu, W. Pan, W. Wang, J. Bai, W. Zhao, L. Sun, X. Wang, Z. Ni, Layer-by-layer thinning of MoS2 by plasma. ACS Nano 7(5), 4202–4209 (2013)

    Article  Google Scholar 

  22. X. Jiang, Q. Lin, Q. Ye et al., Optical and photoelectron-chemical properties of TiO2 films by using hydrothermal method. J. Mater. Sci. Mater. Electron. 26(9), 6557–6562 (2015)

    Article  Google Scholar 

  23. N. Liu, L. Yang, S. Wang, Z. Zhong, S. He, X. Yang, Q. Gao, Y. Tang, Ultrathin MoS2 nanosheets growing within an in situ-formed template as efficient electrocatalysts for hydrogen evolution. J. Power Sources 275, 588–594 (2015)

    Article  Google Scholar 

  24. N. Zhang, S. Gan, T. Wu, W. Ma, D. Han, L. Niu, Growth control of MoS2 Nanosheets on carbon cloth for maximum active edges exposed: an excellent hydrogen evolution 3D cathode. ACS Appl Mater Interfaces 7(22), 12193–12202 (2015)

    Article  Google Scholar 

  25. X. Zhou, J. Xu, L. Yang et al., Effects of tin content on structure, properties, electrical repeatability, uniformity and stability of high sheet resistance ITO thin films for touch panels. J. Mater. Sci. Mater. Electron. 26(9), 6954–6960 (2015)

    Article  Google Scholar 

  26. M. Bernardi, M. Palummo, J.C. Grossman, Extraordinary sunlight absorption and one nanometer thick photovoltaics using two-dimensional monolayer materials. Nano Lett. 13(8), 3664–3670 (2013)

    Article  Google Scholar 

  27. Z. Ji, J. Wu, X. Shen et al., Preparation and characterization of graphene/NiO nanocomposites. J. Mater. Sci. 46(5), 1190–1195 (2011)

    Article  Google Scholar 

  28. B. Baert, M. Schmeits, N.D. Nguyen, Study of the energy distribution of the interface trap density in a GeSn MOS structure by numerical simulation of the electrical characteristics. Appl. Surf. Sci. 291, 25–30 (2014)

    Article  Google Scholar 

Download references

Acknowledgments

This work has been supported by the National Natural Science Foundation of China (Grant Nos. 51372201, 21476183, 21306150), the Research Fund for the Doctoral Program of Higher Education (Grant No. 20136101110009), and the Shaanxi Provincial Natural Science Foundation (No. 2015JM5159).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Xiaoyun Hu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sun, Q., Miao, H., Hu, X. et al. Preparation of MoS2/RGO nano heterojunction and photoelectric property. J Mater Sci: Mater Electron 27, 4665–4671 (2016). https://doi.org/10.1007/s10854-016-4345-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-016-4345-4

Keywords

Navigation