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Synthesis of Co2P/Co nanocomposites using single source precursor by thermal decomposition method

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Abstract

In this article, the synthesis and characterization of Co2P/Co nanocomposites are reported. Three kinds of precursors are studied: bis(salicylidene)cobalt(II) [Co(sal)2], bis(salicylate)cobalt(II) [Co(Hsal)2] and cobalt oxalate [Co(O4C2)·4H2O]. The cobalt(II) acetate tetrahydrate Co(CH3COO)2·4H2O is used as reference. The nanocomposites are prepared by thermal decomposition method using triphenylphosphine as a surfactant solvent and phosphorus precursor. A possible mechanism of the formation of the nanocomposites is put forward to explain the experimental observations. This is the first time that Co2P/Co nanocomposites are synthesized. To study the crystalline structure, composition, size, morphology and magnetic property of the products, characterization techniques including XRD, SEM, TEM, FT-IR and VSM are employed.

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Acknowledgments

Authors are grateful to the council of University of Bojnord and University of Kashan for providing financial support to undertake this work by Grant No. (159271/588).

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Authors and Affiliations

  1. Department of Chemistry, Kosar University of Bojnord, Bojnord, Islamic Republic of Iran

    Azam Sobhani

  2. Institute of Nano Science and Nano Technology, University of Kashan, P. O. Box. 87317–51167, Kashan, Islamic Republic of Iran

    Masoud Salavati-Niasari

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  1. Azam Sobhani
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  2. Masoud Salavati-Niasari
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Correspondence to Azam Sobhani or Masoud Salavati-Niasari.

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Sobhani, A., Salavati-Niasari, M. Synthesis of Co2P/Co nanocomposites using single source precursor by thermal decomposition method. J Mater Sci: Mater Electron 27, 3271–3280 (2016). https://doi.org/10.1007/s10854-015-4155-0

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  • DOI: https://doi.org/10.1007/s10854-015-4155-0

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