Skip to main content

Advertisement

SpringerLink
Log in

Structural and optical properties of Zn doped CdO nanoparticles synthesized by chemical precipitation method

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

In this article, synthesis of undoped and zinc doped cadmium oxide with different zinc concentration (0, 2, and 5 wt%) using simple chemical precipitation method has been discussed. Influence of zinc dopant on crystal structure, microstructure and optical properties of the nanoparticles was investigated by means of X-ray diffractometer, field emission scanning electron microscope, ultraviolet–visible spectrometer, and photoluminescence spectrometer. Crystal structure analysis reveals that zinc doping appreciably increases the crystalline size and also it shows the polycrystalline nature of the samples. Microstructural investigation shows that the samples contain nanoparticles. Optical bandgap of the prepared samples found to vary from 2.67 to 2.61 eV for various dopant concentrations. With these specifications we can fabricate semiconductor nanocrystals and these can be used for some large scale applications of nanotechnology.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. K. Pushpanathan, S. Sathya, M. Jaychithra, S. Gowthami, R. Santhi, Influence of reaction temperature on crystal structure and band gap of ZnO nanoparticles. Mater. Manuf. Process. 27, 1334–1342 (2012)

    Article  Google Scholar 

  2. T. Prakash, G. Neri, A. Bonavita, E. Ranjith Kumar, K. Gnanamoorthi. Structural, morphological and optical properties of Bi-doped ZnO nanoparticles synthesized by a microwave irradiation method. J. Mater. Sci.: Mater. Electron. 26, 4913–4921 (2015)

    Google Scholar 

  3. M. Jay Chithra, K. Pushpanathan, M. Loganathan, Structural and optical properties of Co-doped ZnO nanoparticles synthesized by precipitation method. Mater. Manuf. Process. 29, 771–779 (2014)

    Article  Google Scholar 

  4. M. Jay Chithra, M. Sathya, K. Pushpanathan, Effect of pH on crystal size and photoluminescence property of ZnO nanoparticles prepared by chemical precipitation method. Acta Metall. Sin. 28, 394–404 (2015)

    Article  Google Scholar 

  5. Z. Yang, W. Zhong, Y. Yin, X. Du, Y. Deng, C. Au, Y.W. Du, Controllable synthesis of single-crystalline CdO and Cd(OH)2 nanowires by a simple hydrothermal approach. Nanoscale Res. Lett. 5, 961–965 (2010)

    Article  Google Scholar 

  6. A.K. Barve, S.M. Gadegone, M.R. Lanjewar, R.B. Lanjewar, Synthesis and characterization of CdO nanomaterial and their photocatalyticactivity. Int. J. Recent Innov. Trends Comput. Commun. 2, 2806–2810 (2014)

    Google Scholar 

  7. B.S. Anandakumar, M.B. Madhusudana Reddy, K.V. Thipperudraiah, M. Afzal Pasha, G.T. Chandrappa, Combustion-derived CdO nanopowder as a heterogeneous basic catalyst for efficient synthesis of sulfonamides from aromatic amines using p-toluenesulfonyl chloride. Chem. Pap. 67, 135–144 (2013)

    Article  Google Scholar 

  8. Y. Dou, R.G. Egdell, D.S.L. Law, N.M. Harrison, B.G. Searle, An experimental and theoretical investigation of electronic structure of CdO. J. Phys. Condens. Mater. 10, 8447–8458 (1998)

    Article  Google Scholar 

  9. R. Srinivasaraghavan, R. Chandiramouli, B.G. Jeyaprakash, S. Seshadri, Quantum chemical studies on CdO nanoclusters stability. Spectrochim. Acta A Mol. Biomol. Spectrosc. 102, 242–249 (2013)

    Article  Google Scholar 

  10. S. Sonmezoglu, T.A. Termeli, S. Akın, I. Askeroglu, Synthesis and characterization of tellurium-doped CdO nanoparticles thin films by sol–gel method. J. Sol-Gel. Sci. Technol. 67, 97–104 (2013)

    Article  Google Scholar 

  11. R. Kumaravel, K. Ramamurthi, V. Krishnakumar, Effect of indium doping in CdO thin films prepared by spray pyrolysis technique. J. Phys. Chem. Solids 71, 1545–1549 (2010)

    Article  Google Scholar 

  12. Z. Serbetci, R.K. Gupta, F. Yakuphanoglu, Preparation and characterization of nanorods Sb doped CdO films by sol–gel technique. J. Sol-Gel Sci. Technol. 61, 477–483 (2012)

    Article  Google Scholar 

  13. R. Maity, K.K. Chattopadhyay, Synthesis and characterization of aluminium-doped CdO thin films by sol–gel process. Sol. Energy Mater. Sol. Cells 90, 597–606 (2006)

    Article  Google Scholar 

  14. M. Benhaliliba, C.E. Benouis, A. Tiburcio-Silver, F. Yakuphanoglu, A. Avil-García, A. Tavira, R.R. Trujillo, Z. Mouffak, Luminescence and physical properties of copper doped CdO derived nanostructures. J. Lumin. 132, 2653–2658 (2012)

    Article  Google Scholar 

  15. R. Ferro, J.A. Rodrı, Some physical properties of F-doped CdO thin films deposited by spray pyrolysis. Thin Solid Films 347, 295–298 (1999)

    Article  Google Scholar 

  16. G.L.R. Leon, R.J.J. Cayente, T.J.M. Peza, C.E. Barrera, F.J.C. Martinez, L.M. Ortega, Some physical properties of Sn-doped CdO thin films prepared by chemical bath deposition. Mater. Lett. 60, 3866–3870 (2006)

    Article  Google Scholar 

  17. A.A. Dakhel, Influence of Yb-doping on optoelectrical properties of CdO nanocrystalline films. J. Mater. Sci. 46, 1455–1461 (2011)

    Article  Google Scholar 

  18. A.A. Dakhel, A.Y. Ali-Mohamed, Optical and transport phenomena in CdO: La films prepared by sol–gel method. J. Sol-Gel. Sci. Technol. 44, 241–247 (2007)

    Article  Google Scholar 

  19. B. Saha, R. Thapa, K.K. Chattopadhyay, Bandgap widening in highly conducting CdO thin film by Ti incorporation through radio frequency magnetron sputtering technique. Solid State Commun. 145, 33–37 (2008)

    Article  Google Scholar 

  20. R.K. Guptaa, K. Ghosha, R. Patelb, P.K. Kahol, Effect of oxygen partial pressure on structural, optical and electrical properties of titanium-doped CdO thin films. Appl. Surf. Sci. 255, 2414–2418 (2008)

    Article  Google Scholar 

  21. V. Bilgin, I. Akyuz, S. Kose, F. Atay, Characterization of Mn-incorporated CdO films grown by ultrasonic spray pyrolysis. Semicond. Sci. Technol. 21, 579–585 (2006)

    Article  Google Scholar 

  22. A.A.M. Farag, M. Cavas, F. Yakuphanoglu, Electrical performance and interface states studies of undoped and Zn-doped CdO/p-Si heterojunction devices. Mater. Chem. Phys. 132, 550–558 (2012)

    Article  Google Scholar 

  23. A.A. Dakhel, Structural and optoelectronic properties of Zn-incorporated CdO films prepared by sol–gel method. J. Alloy. Compd. 539, 26–31 (2012)

    Article  Google Scholar 

  24. K. Usharani, A.R. Balu, Structural, optical, and electrical properties of Zn-doped CdO thin films fabricated by a simplified spray pyrolysis technique. Acta Metall. Sin. 28, 64–71 (2015)

    Article  Google Scholar 

  25. S. Sivakumar, A. Venkatesan, P. Soundhirarajan, C.P. Khatiwada, Synthesis, characterizations and anti-bacterial activities of pure and Ag doped CdO nanoparticles by chemical precipitation method. Spectrochim. Acta A Mol. Biomol. Spectrosc. 136, 1751–1759 (2015)

    Article  Google Scholar 

  26. B. Chena, P. Yua, J.F. Liub, L. Liua, Wang, Investigation of nano-sized ZnO particles fabricated by various synthesis routes. J. Ceram. Process. Res. 12, 420–425 (2011)

    Google Scholar 

  27. A. Tadjarodi, M. Imani, H. Kerdari, K. Bijanzad, D. Khaledi, M. Rad, Preparation of CdO Rhombus-like nanostructure and its photocatalytic degradation of azo dyes from aqueous solution. Nanomater. Nanotechnol. 4, 16 (2014). doi:10.5772/58464

    Google Scholar 

  28. C. Sravani, K.T. Ramakrishna Reddy, P. Jayarama Reddy, Influence of oxygen partial pressure on the physical behaviour of CdO films prepared by activated reactive evaporation. Mater. Lett. 15, 356–358 (1993)

    Article  Google Scholar 

  29. C.H. Bhosale, A.V. Kambale, K.Y. Kokate, Structural, optical and electrical properties of chemically sprayed CdO thin films. Mater. Sci. Eng. B 122, 67–71 (2005)

    Article  Google Scholar 

  30. S.J. Helen, D. Suganthi, T. Mahalingam, Effect of Zinc doping on CdO Thin Films Prepared by Spray Pyrolysis Technique. National Conference on Advanced Technology Oriented Materials (ATOM-2014), 8–9th Dec 2014

  31. W.T. Dong, C.S. Zhu, Optical properties of surface-modified CdO nanoparticles. Opt. Mater. 22, 227–233 (2003)

    Article  Google Scholar 

  32. Lower Hutt, A Book on Review of Near Infrared Reflectance Properties of Metal Oxide Nanostructures, January 2013, Publisher: GNS Science, ISBN: 9781972192849

Download references

Acknowledgments

One of the authors Dr. A.T. Ravichandran gratefully acknowledge the financial assistance given by the University Grants Commission of India through the Major Research Project (UGC-MRP:F.NO 41-937/2012 (SR)).

Author information

Authors and Affiliations

  1. PG & Research Department of Physics, National College, Tiruchirapalli, Tamilnadu, 620 001, India

    A. T. Ravichandran & A. Robert Xavier

  2. PG & Research Department of Physics, Government Arts College, Karur, Tamilnadu, 639 005, India

    K. Pushpanathan

  3. Department of Chemistry, M.S. Ramaiah Institute of Technology, Bengaluru, 560 054, India

    B. M. Nagabhushana

  4. PG & Research Department of Physics, Sree Sevugan Annamalai College, Devakotai, Tamilnadu, 630 303, India

    R. Chandramohan

Authors
  1. A. T. Ravichandran
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Robert Xavier
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. K. Pushpanathan
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. B. M. Nagabhushana
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. R. Chandramohan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. T. Ravichandran.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ravichandran, A.T., Robert Xavier, A., Pushpanathan, K. et al. Structural and optical properties of Zn doped CdO nanoparticles synthesized by chemical precipitation method. J Mater Sci: Mater Electron 27, 2693–2700 (2016). https://doi.org/10.1007/s10854-015-4079-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-015-4079-8

Keywords

Search

Navigation