Abstract
The high-temperature dielectric and microwave absorption property of plasma sprayed Ti3SiC2/cordierite coatings at temperature ranging from 25 to 700 °C in the frequency of 8.2–12.4 GHz were investigated. Both the real and imaginary part of permittivity increase with the elevating temperature, which can be ascribed to the shortened relaxation time and the enhanced electrical conductivity, respectively. Moreover, for as-sprayed Ti3SiC2/cordierite coatings, the results show that the relaxation loss dominates the ε″ at a lower temperature and the electrically conductive loss dominates the ε″ at a higher temperature. Further investigations of microwave absorption property were carried out based on the calculated reflection loss and indicated that the Ti3SiC2/cordierite coating was an excellent absorber at high temperature. At the temperature of 400, 500 and 600 °C, the coating with a thickness of 1.5 mm exhibits a proper microwave absorption property with an effective absorption bandwidth (≤−5 dB) across the whole measured frequency, which indicates the Ti3SiC2/cordierite coating is an excellent absorber at high temperature.
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C.H. Peng, P.S. Chen, C.C. Chang, High-temperature microwave bilayer absorber based on lithium aluminum silicate/lithium aluminum silicate–SiC composite. Ceram. Int. 40, 47–55 (2014)
J. Yuan, H.J. Yang, Z.L. Hou, W.L. Song, H. Xu, Y.Q. Kang, H.B. Jin, X.Y. Fang, M.S. Cao, Ni-decorated SiC powders: enhanced high-temperature dielectric properties and microwave absorption performance. Powder Technol. 237, 309–313 (2013)
W.L. Song, M.S. Cao, Z.L. Hou, J. Yuan, X.Y. Fang, High-temperature microwave absorption and evolutionary behavior of multiwalled carbon nanotube nanocomposite. Scripta Mater. 61, 201–204 (2009)
J. Yuan, W.L. Song, X.Y. Fang, X.L. Shi, Z.L. Hou, M.S. Cao, Tetra-needle zinc oxide/silica composites: high-temperature dielectric properties at X-band. Solid State Commun. 154, 64–68 (2013)
B. Wen, M.S. Cao, Z.L. Hou, W.L. Song, L. Zhang, M.M. Lu, H.B. Jin, X.Y. Fang, W.Z. Wang, J. Yuan, Temperature dependent microwave attenuation behavior for carbon-nanotube/silica composites. Carbon 65, 124–139 (2013)
H.T. Guan, Y.D. Wang, G. Chen, J. Zhu, Frequency and temperature effects on dielectric and electrical characteristics of α-MnO2 nanorods. Powder Technol. 224, 356–359 (2012)
M.W. Barsoum, T. El-Raghy, Synthesis and characterization of a remarkable ceramic: Ti3SiC2. J. Am. Ceram. Soc. 79, 1953–1956 (1996)
M.W. Barsoum, T. El-Raghy, C.J. Rawn, W.D. Porter, H. Wang, E.A. Payzant, C.R. Hubbard, Thermal properties of Ti3SiC2. J. Phys. Chem. Solids 60, 429–439 (1999)
Y.L. Liu, J.X. Chen, Y.C. Zhou, Effect of Ti5Si3 on wear properties of Ti3Si(Al)C2. J. Eur. Ceram. Soc. 29, 3379–3385 (2009)
T.T. Ai, High-temperature oxidation behavior of un-dense Ti3AlC2 material at 1000 °C in air. Ceram. Int. 38, 2537–2541 (2012)
S.L. Shi, L.Z. Zhang, J.S. Li, Ti3SiC2 material: an application for electromagnetic interference shielding. Appl. Phys. Lett. 93, 172903 (2008)
J. Su, W. Zhou, Y. Liu, Y. Qing, F. Luo, D. Zhu, Effect of Ti3SiC2 addition on microwave absorption property of Ti3SiC2/cordierite coatings. Surf. Coat. Technol. 270, 39–46 (2015)
Y. Liu, F. Luo, J. Su, W. Zhou, D. Zhu, Z. Li, Enhanced mechanical, dielectric and microwave absorption properties of cordierite based ceramics by adding Ti3SiC2 powders. J. Alloys Compd. 619, 854–860 (2015)
Y. Liu, F. Luo, Y. Wang, J. Su, W. Zhou, D. Zhu, Influences of milling on the dielectric and microwave absorption properties of Ti3SiC2/cordierite composite ceramics. J. Alloys Compd. 629, 208–213 (2015)
Y. Liu, F. Luo, J. Su, W. Zhou, D. Zhu, Electromagnetic and microwave absorption properties of the Nickel/Ti3SiC2 hybrid powders in X-band. J. Magn. Magn. Mater. 365, 126–131 (2014)
Y. Liu, F. Luo, J. Su, W. Zhou, D. Zhu, Mechanical, dielectric, and microwave-absorption properties of alumina ceramic containing dispersed Ti3SiC2. J. Electron. Mater. 44, 867–873 (2015)
Y. Liu, F. Luo, J. Su, W. Zhou, D. Zhu, L. Zhou, Influence of oxidation on the dielectric and microwave absorption properties of the milled Ti3SiC2 powders. J. Alloys Compd. 644, 404–410 (2015)
Y. Liu, F. Luo, J. Su, W. Zhou, D. Zhu, Dielectric and microwave absorption properties of Ti3SiC2/cordierite composite ceramics oxidized at high temperature. J. Alloys Compd. 632, 623–628 (2015)
Y. Zhou, W. Zhou, Y. Qing, F. Luo, D. Zhu, Temperature dependence of the electromagnetic properties and microwave absorption of carbonyl iron particles/silicone resin composites. J. Magn. Magn. Mater. 374, 345–349 (2015)
M.S. Cao, W.L. Song, Z.L. Hou, B. Wen, J. Yuan, The Effects of temperature and frequency on the dielectric properties, electromagnetic interference shielding and microwave-absorption of short carbon fiber/silica composites. Carbon 48, 788–796 (2010)
D. Micheli, R. Pastore, C. Apollo, M. Marchetti, Broadband electromagnetic absorbers using carbon nanostructure-based composites. IEEE. Trans. Microw. Theory 59, 2633–2645 (2011)
D. Micheli, C. Apollo, R. Pastore, M. Marchetti, X-Band microwave characterization of carbon-based nanocomposite material, absorption capability comparison and RAS design simulation. Compos. Sci. Technol. 70, 400–409 (2010)
J.E. Atwater, R.R. Wheeler, Microwave permittivity and dielectric relaxation of a high surface area activated carbon. Appl. Phys. A 79, 125–129 (2004)
T.A. Baeraky, Determination of microwave electrical characteristics of boron nitride at high temperature. Phys. Stat. Sol. (C) 2, 2577–2580 (2005)
B. Wang, Z. Guo, Y. Han, T. Zhang, Electromagnetic wave absorbing properties of multi-walled carbon nanotube/cement composites. Constr. Build. Mater. 46, 98–103 (2013)
Acknowledgments
This work was supported by Chinese National Natural Science Foundation (Grant No. 51072165), National Natural Science Foundation of China (No. 51402239), Fundamental Research Funds for the Central Universities (No. 3102014JCY01002), States Key Laboratory of the Solidification Processing in NWPU, Nos. KP201307 and KP201422.
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Su, J., Zhou, W., Liu, Y. et al. High-temperature dielectric and microwave absorption property of plasma sprayed Ti3SiC2/cordierite coatings. J Mater Sci: Mater Electron 27, 2460–2466 (2016). https://doi.org/10.1007/s10854-015-4046-4
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DOI: https://doi.org/10.1007/s10854-015-4046-4