Luminescence and energy transfer of Tm/Tb/Mn tri-doped phosphate glass for white light-emitting diodes

  • H.-J. Zhong
  • G.-H. ChenEmail author
  • S.-C. Cui
  • J.-S. Chen
  • Y. Yang
  • C.-R. Zhou
  • C.-L. Yuan


The luminescent glasses composed of P2O5–ZnO–SrO–K2O (PZSK) tri-doped thulium oxide (Tm2O3), terbium oxide (Tb4O7) and manganese carbonate (MnCO3) were synthesized by conventional melting method. The full colors including blue, green and reddish orange emitting are observed simultaneously in the photoluminescent spectra of Tm/Tb/Mn tri-doped PZSK glasses excited by 354 nm. The combination of these three emitting allows the realization of white light emitting in the glass samples. Furthermore, the tunable luminescent color and chromaticity parameters can be realized by varying the content of dopant in the glass matrix, which makes these as-prepared phosphate glasses promising candidate for white light-emitting diodes. It is confirmed that energy transfer from Tm3+ (Tb3+) to Mn2+ occurs, which is reasonably interpreted based on energy level diagrams and the analysis of the fluorescence lifetimes.


Glass Sample Manganese Carbonate Tm2O3 Chromaticity Parameter Terbium Oxide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.



This work was financially supported by the Natural Science Foundation of China (NSFC No. 51362005), Natural Science Foundation of Guangxi Province (2013GXNSFDA019026), and Program for Postgraduate Joint Training Base of GUET-GLESI (No. 20141103-12-Z).


  1. 1.
    S. Singh, S. P. Khatkar, V. B. Taxak, J Mater Sci: Mater Electron. 24, 4677(2013)Google Scholar
  2. 2.
    W.B. Xu, C. Jiang, J. Display Technol. 6, 298 (2010)CrossRefGoogle Scholar
  3. 3.
    J. Zhang, B. Han, P.J. Li, Y. Bian, J.L. Li, H.Z. Shi, J. Mater. Sci.: Mater. Electron. 25, 3498 (2014)Google Scholar
  4. 4.
    L. Zhou, J. Wei, J. Wu, F. Gong, L. Yi, J. Huang, J. Alloys Compd. 476, 390 (2009)CrossRefGoogle Scholar
  5. 5.
    T. Jüstel, H. Nikol, C. Ronda, Angew. Chem. Int. Ed. 37, 3084 (1998)CrossRefGoogle Scholar
  6. 6.
    J.H. Park, A.J. Steckl, Appl. Phys. Lett. 85, 4588 (2004)CrossRefGoogle Scholar
  7. 7.
    D.A. Steigerwald, J.C. Bthat, D. Collins, R.M. Fletcher, M.O. Holcomb, M.J. Ludowise, P.S. Martin, S.L. Rudaz, IEEE J. Sel. Top. Quantum Electron. 8, 310 (2002)CrossRefGoogle Scholar
  8. 8.
    Z.F. Zhu, Y.B. Zhang, Y.P. Qiao, D.G. Liu, B.Q. Wang, Z.C. Zhang, J. Non-Cryst, Solids 358, 1550 (2012)Google Scholar
  9. 9.
    R.G. Ye, S.Q. Xu, D.G. Deng, Y.J. Hua, H.P. Wang, C.X. Li, S.L. Zhao, L.H. Huang, J. Lumin. 130, 2385 (2010)CrossRefGoogle Scholar
  10. 10.
    R.F. Wei, H. Zhang, F. Li, H. Guo, J. Am. Ceram. Soc. 95, 34 (2012)CrossRefGoogle Scholar
  11. 11.
    C.F. Zhu, X.L. Liang, Y.X. Yang, G.R. Chen, J. Lumin. 130, 74 (2010)CrossRefGoogle Scholar
  12. 12.
    R. Mart´ınez-Mart´ınez, A. Speghini, M. Bettinelli, C. Faltriny, U. Caldiño, J. Lumin. 129, 1276 (2009)Google Scholar
  13. 13.
    P.K.D. Sagar, P. Kistaiah, B.A. Rao, C.V.V. Reddy, K.S.N. Murthy, J. Mater. Sci. Lett. 18, 55 (1999)CrossRefGoogle Scholar
  14. 14.
    M. Seshadri, L.C. Barbosa, C.M.B. Cordeiro, M. Radha, F.A. Sigoli, Y.C. Ratnakaram, J. Lumin. 166, 8 (2005)CrossRefGoogle Scholar
  15. 15.
    A. Kelemena, M. Ignatovychb, V. Holoveyc, T. Vidoczyd, P. Baranyai, Radiat. Phys. Chem. 76, 1531 (2007)CrossRefGoogle Scholar
  16. 16.
    T. Hayakawa, N. Kamata, K. Yamada, J. Lumin. 68, 179 (1996)CrossRefGoogle Scholar
  17. 17.
    J. Fu, M. Kobayashi, J.M. Parker, J. Lumin. 128, 99 (2008)CrossRefGoogle Scholar
  18. 18.
    W.J. Yang, T.M. Chen, Appl. Phys. Lett. 88, 1019031 (2006)Google Scholar

Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • H.-J. Zhong
    • 2
  • G.-H. Chen
    • 1
    • 2
    Email author
  • S.-C. Cui
    • 2
  • J.-S. Chen
    • 2
  • Y. Yang
    • 1
  • C.-R. Zhou
    • 1
    • 2
  • C.-L. Yuan
    • 1
    • 2
  1. 1.Guangxi Key Laboratory of Information MaterialsGuilin University of Electronic TechnologyGuilinChina
  2. 2.School of Material Science and EngineeringGuilin University of Electronic TechnologyGuilinChina

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