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Studies on SILAR deposited Cu2O and ZnO films for solar cell applications

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Abstract

SILAR deposited ZnO/Cu2O/ITO heterostructures were prepared and their photoresponse property was studied for various thickness of Cu2O layer. The ZnO thin films were grown using a solution comprising of high purity zinc sulphate, and sodium hydroxide, and the Cu2O films were deposited using an aqueous bath containing copper sulphate pentahydrate, sodium thiosulfate and sodium hydroxide, respectively. X-ray diffractometer analysis of the films have shown highly oriented growth of Cu2O and ZnO films along (111) and (002) planes, respectively. Scanning electron microscope study has shown the nanorod morphology of both Cu2O and ZnO films, the Cu2O film has shown increased thickness and grain size with the increasing dipping cycles. Optical absorption measurements of the films have shown increase of absorbance with the increase of thickness of Cu2O films, and the ZnO film has shown a maximum of 80 % transmittance. The solar cell efficiency of Cu2O/ZnO structure was measured and it has been found to increase with the increase of the Cu2O film thickness.

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References

  1. V. Fthenakis, J.E. Mason, K. Zweibel, Energy Policy 37, 387 (2009)

    Article  Google Scholar 

  2. J.A. Rodríguez, M. Fernández-García, Synthesis, Properties, and Applications of Oxide Nanomaterials (Wiley, Hoboken, 2007)

    Book  Google Scholar 

  3. M. Lorenz, A. Rahm, B.Q. Cao, J. Zuñiga-Perez, E.M. Kaidashev, N. Zhakarov, G. Wagner, T. Nobis, C. Czekalla, G. Zimmermann, M. Grundmann, Phys. Status Solidi B 247, 1265 (2010)

    Article  Google Scholar 

  4. A.L. Daltin, A. Addad, P. Baudart, J.P. Chopart, Cryst. Eng. Comm. 13, 3373 (2011)

    Article  Google Scholar 

  5. L. Li, T.Y. Zhai, H.B. Zeng, X.S. Fang, Y. Bando, D. Golberg, J. Mater. Chem. 21, 40 (2011)

    Article  Google Scholar 

  6. L.C. Jia, W.P. Cai, H.Q. Wang, F.Q. Sun, Y. Li, ACS Nano 3, 2697 (2009)

    Article  Google Scholar 

  7. Y. Jiao, H.J. Zhu, X.F. Wang, L. Shi, Y. Liu, L.M. Peng, Q. Li, Cryst. Eng. Comm. 12, 940 (2010)

    Article  Google Scholar 

  8. W.Y. Wu, J.M. Ting, C.K. Chang, Cryst. Eng. Comm. 12, 1433 (2010)

    Article  Google Scholar 

  9. W.W. Zhou, B. Yan, C.W. Cheng, C.X. Cong, H.L. Hu, H.J. Fan, T. Yu, Cryst. Eng. Comm. 11, 2291 (2009)

    Article  Google Scholar 

  10. O. Porat, I. Riess, Solid State Ion. 81, 29 (1995)

    Article  Google Scholar 

  11. K. Akimoto, S. Ishizuka, M. Yanagita, Y. Nawa, G.K. Paul, T. Sakurai, Sol. Energy 80, 715 (2006)

    Article  Google Scholar 

  12. Y. Hames, S. ErenSan, Sol. Energy 77, 291 (2004)

    Article  Google Scholar 

  13. H. Tanaka, T. Shimakawa, T. Miyata, H. Sato, T. Minami, Thin Solid Films 469, 80 (2004)

    Article  Google Scholar 

  14. R.P. Wijesundera, Semicond. Sci. Technol. 25, 045015 (2010)

    Article  Google Scholar 

  15. F.Y. Hsu, S.J. Liu, Y.I. Lu, L.Y. Chen, H.W. Fang, Jpn. J. Appl. Phys. 48, 035501 (2009)

    Article  Google Scholar 

  16. V. Georgieva, M. Ristov, Sol. Energy Mater. Sol. Cells 73, 67 (2002)

    Article  Google Scholar 

  17. M. Izaki, T. Shinagawa, K.T. Mizuno, Y. Ida, M. Inaba, A. Tasaka, J. Phys. D Appl. Phys. 40, 3326 (2007)

    Article  Google Scholar 

  18. T.J. Hsueh, C.L. Hsu, S.J. Chang, P.W. Guo, J.H. Hsieh, I.C. Chen, Scr. Mater. 57, 53 (2007)

    Article  Google Scholar 

  19. S.M. Chou, M.H. Hon, I.C. Leu, Y.H. Lee, J. Electrochem. Soc. 155, H923 (2008)

    Article  Google Scholar 

  20. A. Mittiga, E. Salza, F. Sarto, M. Tucci, R. Vasanthi, Appl. Phys. Lett. 88, 163502 (2006)

    Article  Google Scholar 

  21. S. Xu, Z.L. Wang, Nano Res. 10, 13 (2011)

    Google Scholar 

  22. A. Roos, B. Karlsson, Sol. Energy Mater. 7, 467 (1983)

    Article  Google Scholar 

  23. N. Kikuchi, K. Tonooka, Thin Solid Films 486, 33 (2005)

    Article  Google Scholar 

  24. D.A. Firmansyah, T. Kim, S. Kim, K. Sullivan, M.R. Zachariah, D. Lee, Langmuir 25, 7063 (2009)

    Article  Google Scholar 

  25. A.H. Jayatissa, K. Guo, A.C. Jayasuriya, Appl. Surf. Sci. 255, 9474 (2009)

    Article  Google Scholar 

  26. A.J. Morfa, G. Beane, B. Mashford, B. Singh, E. Della Gaspera, A. Martucci, P. Mulvaney, J. Phys. Chem. C 114, 19815 (2010)

    Article  Google Scholar 

  27. C.L. Chu, H.C. Lu, C.Y. Lo, C.Y. Lai, Y.H. Wang, Phys. B 404, 4831 (2009)

    Article  Google Scholar 

  28. J.L. Campbell, M. Breedon, K. Latham, K. Kalantar-zadeh, Langmuir 24, 5091 (2008)

    Article  Google Scholar 

  29. R. Chandramohan, J. Thirumalai, T.A. Vijayan, S. Valanarasu, S. Elhil Vizhian, M. Srikanth, V. Swaminathan, Adv. Sci. Lett. 3, 1 (2000)

    Google Scholar 

  30. P.B. Ahirrao, S.R. Gosavi, D.R. Patil, M.S. Shinde, R.S. Patil, Arch. Appl. Sci. Res. 3, 288 (2011)

    Google Scholar 

  31. S.W. Shin, S.M. Pawar, C.Y. Park, J.H. Yun, J.H. Moon, J.H. Kim, J.Y. Lee, Sol. Energy Mater. Sol. Cells 95, 3202 (2010)

    Article  Google Scholar 

  32. X. Mathew, N.R. Mathews, P.J. Sebastian, Sol. Energy Mater. Sol. Cells 70, 277 (2001)

    Article  Google Scholar 

  33. T. Mahalingam, J.S.P. Chitra, J.P. Chu, S. Velumani, P.J. Sebastian, Sol. Energy Mater. Sol. Cells 88, 209 (2005)

    Article  Google Scholar 

  34. L. Li, G. Meng, H.Q. Wang, T.Y. Zhai, X.S. Fang, U.K. Gautam, X.D. Fang, Y. Bando, D. Golberg, Chem. Commun. 47, 8247 (2011)

    Article  Google Scholar 

  35. J.B. Cui, U.J. Gibson, J. Phys. Chem. C 114, 6408 (2010)

    Article  Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Physics, Sree Sevugan Annamalai College, Devakottai, 630303, India

    N. Soundaram & R. Chandramohan

  2. PG and Research Department of Physics, Arul Anandar College, Karumathur, 625514, India

    S. Valanarasu & R. Thomas

  3. Millimeter-Wave Innovation Technology Research Center (MINT), Dongguk University, Seoul, 100-715, Republic of Korea

    A. Kathalingam

Authors
  1. N. Soundaram
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  2. R. Chandramohan
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  3. S. Valanarasu
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  4. R. Thomas
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  5. A. Kathalingam
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Correspondence to S. Valanarasu.

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Soundaram, N., Chandramohan, R., Valanarasu, S. et al. Studies on SILAR deposited Cu2O and ZnO films for solar cell applications. J Mater Sci: Mater Electron 26, 5030–5036 (2015). https://doi.org/10.1007/s10854-015-3020-5

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  • DOI: https://doi.org/10.1007/s10854-015-3020-5

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