Skip to main content

Synthesis and characterization of electrochemically grown CdSe nanowires with enhanced photoconductivity

Abstract

CdSe nanowires were grown in polycarbonate track etched membrane with pore diameter of 80 nm by an electrochemical deposition technique. The mechanism of the growth was studied during the potentiostatic deposition of nanowires. X-ray photoelectron spectroscopy and energy dispersive spectrometry results showed binding of fragments and fraction of atoms for the CdSe nanowires. Microstructure and morphology of synthesized CdSe nanowires were observed by scanning electron microscopy. Optical spectrophotometry technique was used to determine the energy band gap of CdSe nanowires. It was found that the nanowires were resistive in the dark and exhibited a pronounced visible light photoconductivity. Photoconductivity of CdSe nanowire-based nanodevice (an integrated multilayer nanodevice of Cu/CdSe nanowire array/Au thin films) was investigated which indicated an enhanced photoconductive response in contrast to the previously reported results. The photosensitivity of this multilayer nanodevice was found to be about 110, which this sensitivity is one order of magnitude greater than that reported in similar works.

This is a preview of subscription content, access via your institution.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

References

  1. D. Xu, X. Shi, G. Guo, L. Gui, Y. Tang, Electrochemical preparation of CdSe nanowire arrays. J. Phys. Chem. B 104, 5061–5063 (2000)

    Article  Google Scholar 

  2. R. Singh, R. Kumar, S. Chakarvarti, Non-galvanic template synthesis of CdSe nanowires using anodic alumina membrane and their optical band gap determination. Mater. Lett. 62, 874–877 (2008)

    Article  Google Scholar 

  3. Y.S. Zhou, K. Wang, W. Han, S.C. Rai, Y. Zhang, Y. Ding, C. Pan, F. Zhang, W. Zhou, Z.L. Wang, Vertically aligned CdSe nanowire arrays for energy harvesting and piezotronic devices. ACS Nano 6, 6478–6482 (2012)

    Article  Google Scholar 

  4. L. Vj, J. Oh, A.P. Nayak, A.M. Katzenmeyer, K.H. Gilchrist, S. Grego, N.P. Kobayashi, S.-Y. Wang, A. Talin, N.K. Dhar, A perspective on nanowire photodetectors: current status, future challenges, and opportunities. IEEE J. Sel. Top. Quantum Electron. 17, 1002–1032 (2011)

    Article  Google Scholar 

  5. H. Choi, M. Kuno, G.V. Hartland, P.V. Kamat, CdSe nanowire solar cells using carbazole as a surface modifier. J. Mater. Chem. A 1, 5487–5491 (2013)

    Article  Google Scholar 

  6. F. Gu, P. Wang, H. Yu, B. Guo, L. Tong, Optical quenching of photoconductivity in CdSe single nanowires via waveguiding excitation. Opt. Express 19, 10880–10885 (2011)

    Article  Google Scholar 

  7. Y. Huang, X. Duan, Q. Wei, C.M. Lieber, Directed assembly of one-dimensional nanostructures into functional networks. Science 291, 630–633 (2001)

    Article  Google Scholar 

  8. Y. Cui, Z. Zhong, D. Wang, W.U. Wang, C.M. Lieber, High performance silicon nanowire field effect transistors. Nano Lett. 3, 149–152 (2003)

    Article  Google Scholar 

  9. F. Qian, S. Gradecak, Y. Li, C.-Y. Wen, C.M. Lieber, Core/multishell nanowire heterostructures as multicolor, high-efficiency light-emitting diodes. Nano Lett. 5, 2287–2291 (2005)

    Article  Google Scholar 

  10. H. Kind, H. Yan, B. Messer, M. Law, P. Yang, Nanowire ultraviolet photodetectors and optical switches. Adv. Mater. 14, 158 (2002)

    Article  Google Scholar 

  11. P. Zhang, C. Cheng, P. Jiao, Y. Li, Z. He, H. Zhang, Well improved photoswitching characteristic of CdSe nanorods via CdS nanoparticle-decoration. Mater. Lett. 62, 1151–1154 (2008)

    Article  Google Scholar 

  12. F. Gu, H. Yu, W. Fang, L. Tong, Broad spectral response in composition-graded CdSSe single nanowires via waveguiding excitation. Appl. Phys. Lett. 99, 181111 (2011)

    Article  Google Scholar 

  13. C. Soci, A. Zhang, B. Xiang, S.A. Dayeh, D. Aplin, J. Park, X. Bao, Y.-H. Lo, D. Wang, ZnO nanowire UV photodetectors with high internal gain. Nano Lett. 7, 1003–1009 (2007)

    Article  Google Scholar 

  14. R. Ashiri, A. Nemati, M.S. Ghamsari, Crack-free nanostructured BaTiO3 thin films prepared by sol–gel dip-coating technique. Ceram. Int. 40, 8613–8619 (2014)

    Article  Google Scholar 

  15. R. Ashiri, A. Nemati, M.S. Ghamsari, M. Dastgahi, Nanothickness films, nanostructured films, and nanocrystals of barium titanate obtained directly by a newly developed sol–gel synthesis pathway. J. Mater. Sci.: Mater. Electron. 25, 5345–5355 (2014)

    Google Scholar 

  16. M. Ranjbar, A.H. Fini, H. Kalhori, P. Kameli, H. Salamati, Gasochromic effect in colloidal nanoparticles of tungsten oxide dihydrate synthesized via a simple anodizing method. Sol. Energy Mater. Sol. Cells 132, 329–336 (2015)

    Article  Google Scholar 

  17. R. Ashiri, A mechanistic study of nanoscale structure development phase transition, morphology evolution, and growth of ultrathin barium titanate nanostructured films. Metall. Mater. Trans. A 45, 4138–4154 (2014)

    Article  Google Scholar 

  18. R. Ashiri, Analysis and characterization of phase evolution of nanosized BaTiO3 powder synthesized through a chemically modified sol-gel process. Metall. Mater. Trans. A 43, 4414–4426 (2012)

    Article  Google Scholar 

  19. R. Ashiri, Analysis and characterization of relationships between the processing and optical responses of amorphous BaTiO3 nanothin films obtained by an improved wet chemical process. Metall. Mater. Trans. B 45, 1472–1483 (2014)

    Article  Google Scholar 

  20. R. Ashiri, A. Moghtada, Carbonate-free strontium titanium oxide nanosized crystals with tailored morphology: facile synthesis characterization, and formation mechanism. Metall. Mater. Trans. B 45, 1979–1986 (2014)

    Article  Google Scholar 

  21. G. Riveros, J. Vasquez, H. Gomez, T. Makarova, D. Silva, R. Marotti, E. Dalchiele, Single-step electrodeposition of polycrystalline CdSe microwire arrays: structural and optical properties. Appl. Phys. A 90, 423–430 (2008)

    Article  Google Scholar 

  22. U. Mohanty, Electrodeposition: a versatile and inexpensive tool for the synthesis of nanoparticles, nanorods, nanowires, and nanoclusters of metals. J. Appl. Electrochem. 41, 257–270 (2011)

    Article  Google Scholar 

  23. A. Ghahremaninezhad, A. Dolati, A study on electrochemical growth behavior of the Co–Ni alloy nanowires in anodic aluminum oxide template. J. Alloy. Compd. 480, 275–278 (2009)

    Article  Google Scholar 

  24. F. Nasirpouri, P. Southern, M. Ghorbani, W. Schwarzacher, GMR in multilayered nanowires electrodeposited in track-etched polyester and polycarbonate membranes. J. Magn. Magn. Mater. 308, 35–39 (2007)

    Article  Google Scholar 

  25. M.P. Zach, K.H. Ng, R.M. Penner, Molybdenum nanowires by electrodeposition. Science 290, 2120–2123 (2000)

    Article  Google Scholar 

  26. K. Yu-Zhang, D. Guo, J. Mallet, M. Molinari, A. Loualiche, M. Troyon, Electrodeposition and characterization of CdSe semiconducting nanowires. J. Nanosci. Nanotechnol. 8, 2022–2028 (2008)

    Article  Google Scholar 

  27. D. Azulai, U. Givan, N. Shpaisman, T.L. Belenkova, H. Gilon, F. Patolsky, G. Markovich, On-surface formation of metal nanowire transparent top electrodes on CdSe nanowire array-based photoconductive devices. ACS Appl. Mater. Interfaces 4, 3157–3162 (2012)

    Article  Google Scholar 

  28. S.-C. Kung, W.E. van der Veer, F. Yang, K.C. Donavan, R.M. Penner, 20 μs photocurrent response from lithographically patterned nanocrystalline cadmium selenide nanowires. Nano Lett. 10, 1481–1485 (2010)

    Article  Google Scholar 

  29. D.J. Pena, J.K. Mbindyo, A.J. Carado, T.E. Mallouk, C.D. Keating, B. Razavi, T.S. Mayer, Template growth of photoconductive metal-CdSe-metal nanowires. J. Phys. Chem. B 106, 7458–7462 (2002)

    Article  Google Scholar 

  30. A. Azarian, A. Dolati, An optical study of cobalt nanowires dispersed in liquid phase. Opt. Commun. 274, 471–476 (2007)

    Article  Google Scholar 

  31. M. Motoyama, Y. Fukunaka, T. Sakka, Y.H. Ogata, S. Kikuchi, Electrochemical processing of Cu and Ni nanowire arrays. J. Electroanal. Chem. 584, 84–91 (2005)

    Article  Google Scholar 

  32. G. Tan, J. Du, Q. Zhang, Structural evolution and optical properties of CdSe nanocrystals prepared by mechanical alloying. J. Alloy. Compd. 468, 421–431 (2009)

    Article  Google Scholar 

  33. R. Ashiri, A. Nemati, M.S. Ghamsari, H. Aadelkhani, Characterization of optical properties of amorphous BaTiO3 nanothin films. J. Non-Cryst. Solids 355, 2480–2484 (2009)

    Article  Google Scholar 

  34. F. Davar, M.R. Loghman-Estarki, M. Salavati-Niasari, R. Ashiri, Synthesis of volcano-like CdS/organic nanocomposite. Int. J. Appl. Ceram. Technol. 11, 637–644 (2014)

    Article  Google Scholar 

  35. S. Baskoutas, A.F. Terzis, Size-dependent band gap of colloidal quantum dots. J. Appl. Phys. 99, 013708 (2006)

    Article  Google Scholar 

  36. R. Ashiri, R. Ajami, A. Moghtada, Sonochemical synthesis of SrTiO3 nanocrystals at low temperature. Int. J. Appl. Ceram. Technol. (2014). doi:10.1111/ijac.12315

  37. R. Ashiri, Detailed FT-IR spectroscopy characterization and thermal analysis of synthesis of barium titanate nanoscale particles through a newly developed process. Vib. Spectrosc. 66, 24–29 (2013)

    Article  Google Scholar 

  38. R. Ashiri, A. Moghtada, A. Shahrouzianfar, R. Ajami, Low Temperature synthesis of carbonate-free barium titanate nanoscale crystals: toward a generalized strategy of titanate-based perovskite nanocrystals synthesis. J. Am. Ceram. Soc. 97, 2027–2031 (2014)

    Article  Google Scholar 

  39. R. Ashiri, A. Nemati, M.S. Ghamsari, S. Sanjabi, M. Aalipour, A modified method for barium titanate nanoparticles synthesis. Mater. Res. Bull. 46, 2291–2295 (2011)

    Article  Google Scholar 

  40. H.B. Yao, Y. Guan, J. Zheng, G. Huang, J. Xu, J.W. Liu, H.P. Cong, S.H. Yu, Chloride anion triggered synthesis and assembly of gold nanoparticle-ultrathin cadmium selenide nanowire networks with enhanced photoconductivity. Part. Part. Syst. Charact. 30, 97–101 (2013)

    Article  Google Scholar 

  41. P. George, A. Sanchez-Juarez, P. Nair, Modification of electrical, optical and crystalline properties of chemically deposited CdS films by thermal diffusion of indium and tin. Semicond. Sci. Technol. 11, 1090 (1996)

    Article  Google Scholar 

  42. H. Zhuang, S. Xue, S. Zhang, L. Hu, B. Li, C. Xue, Growth of GaN nanorods prepared by ammoniating Ga2O3/ZnO films on Si substrates and their properties: structure, morphology, chemical state and photoluminescence. Physica E: Low-Dimens. Syst. Nanostruct. 40, 828–832 (2008)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. Irajizad.

Rights and permissions

Reprints and Permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kalhori, H., Irajizad, A., Azarian, A. et al. Synthesis and characterization of electrochemically grown CdSe nanowires with enhanced photoconductivity. J Mater Sci: Mater Electron 26, 1395–1402 (2015). https://doi.org/10.1007/s10854-014-2553-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-014-2553-3

Keywords