Abstract
CuO thin films were synthesized at relatively low temperature by employing an inexpensive SILAR method. Effect of immersion time on the properties of grown film was studied using structural, morphological and optical characterizations. Structural, morphological, optical and electrical studies of the prepared CuO films were done using X-ray diffraction, field emission scanning electron microscope, and UV–Vis–NIR spectrometer and Hall probe, respectively. The films were found show different nanostructures depending on immersion time. The calculated crystalline size of the films is found increase with the increase of immersion time, and it is found to be 19 nm for 30 s immersion time. Vibration peaks of Cu–O and O–Cu–O bonds have been identified using Fourier transformation infrared spectroscopy. Optical band gap energy of the grown CuO films is calculated and it is found vary from 1.8 to 1.6 eV depending on the immersion time and annealing temperature. Hall effect measurements have shown a p-type conductivity of the grown films.
Similar content being viewed by others
References
M. Kawwam, F.H. Alharbi, T. Kayed, A. Aldwayyan, A. Alyamani, N. Tabet, K. Lebbou, Appl. Surf. Sci. 276, 7 (2013)
J. Medina-valtierra, C. Frausto-Reyes, G. Camarillo-Martinez, J.A. Ramirez-Ortiz, Appl. Catal. A: General 356, 36 (2009)
R.M. Mohamed, F.A. Harraz, A. Shawky, Ceram. Int. 40, 2127 (2014)
D.M. Jundale, P.B. Joshi, S. Sen, V.B. Patil, J. Mater. Sci.: Mater. Electron. 23, 1492 (2012)
D.P. Singh, N. Ali, Sci. Adv. Mater. 2, 295 (2010)
J. Kuusisto, J.P. Millola, P. Perez Casal, H. Karhu, J. Vayrynen, T. Salmi, Chem. Eng. J. 115, 93 (2005)
A. Manivel, S. Naveenraj, P. Selvam, S. Kumar, S. Anandan, Sci. Adv. Mater. 2, 51 (2010)
X.P. Gao, J.L. Bao, G.L. Pan, H.Y. Zhu, P.X. Huang, F. Wu, D.Y. Song, J. Phys. Chem. B 108, 5547 (2004)
A. Catana, J.P. Locquet, S.M. Paik, I.K. Schuller, Phys. Rev. B 46, 15477 (1992)
V.P. Godbole, R.D. Vispute, S.M. Chaudhari, S.M. Kanetkar, S.B. Ogale, J. Mater. Res. 5, 372 (1990)
R.K. Singh, J. Narayan, Phys. Rev. B 41, 8843 (1990)
K. Akimoto, S. Ishizuka, M. Yanagita, Y. Nawa, G.K. Paul, T. Sakurai, Sol. Energy 80, 715 (2005)
A. Chen, G. Yang, H. Long, F. Li, Y. Li, P. Lu, Thin Solid Films 517, 4277 (2008)
S.B. Ogale, P.G. Bilurkar, N. Mate, S.M. Kanetkar, N. Parikh, B. Patnaik, J. Appl. Phys. 27, 3765 (1992)
N. Kikuchi, K. Tonooka, Thin Solid Films 486, 33 (2005)
M.T.S. Nair, L. Guerrero, O.L. Arenas, P.K. Nair, Appl. Surf. Sci. 150, 143 (1999)
N.A. Okereke, A.J. Ekpunobi, Res. J. Chem. Sci. 1(6), 64 (2011)
J. Medina-Valtierraa, S. Calixto, F. Ruiz, Thin Solid Films 460, 58 (2004)
N. Serin, T. Serin, S. Horzum, Y. Celik, Semicond. Sci. Technol. 20, 398 (2005)
I.Y. Erdogan, O. Gullu, J. Alloys Compd. 492, 378 (2010)
K. Mageshwari, R. Sathyamoorthy, Mater. Sci. Semicond. Process. 16, 337–343 (2013)
R. Sathyamoorthy, K. Mageshwari, Phys. E 47, 157 (2013)
Z. Zang, A. Nakamura, J. Temmyo, Opt. Express 21, 11448 (2013)
A. Vasuhi, R. John Xavier, R. Chandramohan, S. Muthukumaran, K. Dhanabalan, M. Ashokkumar, P. Parameswaren, J. Mater. Sci.: Mater. Electron. 25, 824 (2014)
S. Valanarasu, V. Dhanasekaran, M. Karunakaran, R. Chandramohan, T. Mahalingam, J. Nanosci. Nanotech. 13, 5613 (2013)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Ravichandran, A.T., Dhanabalan, K., Valanarasu, S. et al. Role of immersion time on the properties of SILAR deposited CuO thin films. J Mater Sci: Mater Electron 26, 921–926 (2015). https://doi.org/10.1007/s10854-014-2483-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-014-2483-0