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Effect of fluoride doping on impedance spectra of barium strontium titanate glass ceramics

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Abstract

A system of barium strontium titanate glass ceramics with different fluoride concentrations were prepared by melt-annealing technique. The effect of fluoride doping on impedance spectra of the barium strontium titanate glass ceramics were investigated. According to the impedance spectroscopy studies, three (low, middle, and high frequency) electrical responses, which corresponds to glass phase, crystal–glass interface and crystal interior were identified. It is shown that with the increase of fluoride concentration, the resistivity of the glass phase passed through a minimum and then increased. In addition, the capacitance of the crystal–glass interface increased and the capacitance of the crystal phase decreased with the increase of the fluoride concentration. Moreover, as a result of ac conductivity calculation and analysis, it is believed that the dc conduction was affected by the glass and crystal–glass interface regions and ac regime was attributed to the crystal phase. Based on the results, a change of the compensation mechanism from electronic to ionic one with variation in fluoride concentration was proposed.

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References

  1. S.D. Stookey, Ind. Eng. Chem 51, 805 (1959)

    Article  Google Scholar 

  2. A. Herczog, IEEE Trans. Parts Hybrids Packag. PHP 9, 247 (1973)

    Article  Google Scholar 

  3. K. Kageyama, J. Takahashi, J. Am. Ceram. Soc 87, 1602 (2004)

    Article  Google Scholar 

  4. A. Herczog, J. Am. Ceram. Soc 47, 107 (1964)

    Article  Google Scholar 

  5. D. McCauley, R.E. Newnham, C.A. Randall, J. Am. Ceram. Soc 81, 979 (1998)

    Article  Google Scholar 

  6. A. Herczog, J. Am. Ceram. Soc 67, 484 (1984)

    Article  Google Scholar 

  7. M.S. Al-Assiri, M.M. El-Desoky, J. Mater. Sci. Mater. Electron 24, 784 (2012)

    Article  Google Scholar 

  8. J.-J. Shyu, H.-W. Peng, J. Mater. Res. 16, 2057 (2001)

    Article  Google Scholar 

  9. P.B. Jamieson, J. Chem. Phys 48, 5048 (1968)

    Article  Google Scholar 

  10. E.P. Gorzkowski, M.J. Pan, B. Bender, C.C.M. Wu, J. Electroceram 18, 269 (2007)

    Article  Google Scholar 

  11. A. R. West, D. C. Sinclair, N. Hirose J. Electroceram 1:1, 65 (1997)

  12. X.R. Wang, Y. Zhang, T. Ma, Z.B. Yuan, Q. Zhang, C.S. Deng, T.X. Liang, Int. J. Appl. Ceram. Technol 10, 301 (2013)

    Article  Google Scholar 

  13. J.C. Chen, Y. Zhang, C.S. Deng, X.M. Dai, J. Am. Ceram. Soc 92, 1863 (2009)

    Article  Google Scholar 

  14. C. J. Peng, H.-Y. Lu, J. Am. Ceram. Soc. 71, C-44 (1988)

  15. F.D. Morrison, A.M. Coats, D.C. Sinclair, A.R. West, J. Electroceram 6, 219 (2001)

    Article  Google Scholar 

  16. B. Rangarajan, S.S.N. Bharadwaja, E. Furman, T. Shrout, M. Lanagan, J. Am. Ceram. Soc 93, 522 (2010)

    Article  Google Scholar 

  17. M.J. Wang, X.L. Liu, X.R. Wang, Y. Zhang, J. Mater. Sci 47, 2535 (2012)

    Article  Google Scholar 

  18. A. Dutta, T.P. Sinha, P. Jena, S. Adak, J. Non-cryst, Solids 354, 3952 (2008)

    Google Scholar 

  19. A. Grandjean, M. Malki, C. Simonnet, J. Non-cryst, Solids 352, 2731 (2006)

    Google Scholar 

  20. A.K. Jonscher, Nature 267, 673 (1977)

    Article  Google Scholar 

  21. M.J. Wang, Y. Zhang, X.L. Liu, X.R. Wang, Ceram. Int 39, 2069 (2013)

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by International Science & Technology Cooperation Program of China (No. 2012DFR50560).

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Authors and Affiliations

  1. Beijing Key Laboratory of Fine Ceramics, State Key Laboratory of New Ceramics and Fine Processing, Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing, 100084, China

    Jia Zhu, Yong Zhang, Qian Zhang & Xiaozhen Song

  2. Ferroelectric Laboratory, Institute of Natural Science, Ural Federal University, 620000, Yekaterinburg, Russia

    Ivan Baturin

Authors
  1. Jia Zhu
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  2. Yong Zhang
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  3. Qian Zhang
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  4. Xiaozhen Song
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  5. Ivan Baturin
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Correspondence to Yong Zhang.

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Zhu, J., Zhang, Y., Zhang, Q. et al. Effect of fluoride doping on impedance spectra of barium strontium titanate glass ceramics. J Mater Sci: Mater Electron 25, 4916–4922 (2014). https://doi.org/10.1007/s10854-014-2252-0

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  • DOI: https://doi.org/10.1007/s10854-014-2252-0

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