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Electrospinning preparation and luminescence properties of one-dimensional SrWO4: Sm3+ nanofibers

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Abstract

One-dimensional Sm3+ doped SrWO4 with or without different charge compensation approaches (co-doping Li+, Na+ and K+) nanofibers were prepared by electrospinning. The structure, morphology and luminescence properties of the obtained nanofiber phosphors were investigated. The X-ray diffraction, Fourier transformation infrared and thermogravimetric results show that the Sr(1−x)WO4: Sm 3+x samples crystallize at 700 °C. Scanning electron microscope results indicate that as prepared nanofibers before/after calcination present uniform fiberlike morphology. The luminescence results show that Sr(1−x)WO4: Sm 3+x phosphors can be excited efficiently by ultraviolet (UV) and near-UV light. The emission spectrum consists of three emission peaks at 561, 596 and 643 nm, corresponding to 4G5/2 → 6H5/2, 4G5/2 → 6H7/2 and 4G5/2 → 6H9/2 transitions of Sm3+, respectively. The optimal doping concentration of Sm3+ in SrWO4 is experimentally ascertained to be 4 mol%. The introduction of charge compensator R+ (R = Li, Na and K) can enhance the emission intensity of phosphors significantly. The co-doping of Li+ has the best compensation effect. The present investigation indicates that Sm3+ doped SrWO4 is a promising orange phosphor for light-emitting diode based on UV chip technology.

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Authors and Affiliations

  1. Faculty of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 511458, People’s Republic of China

    Xuetao Xu & Suqing Zhao

  2. Faculté des Sciences et Techniques, Université du Maine Avenue Olivier Messiaen, 972085, Le Mans Cedex, France

    Kanyi Liang

  3. School of Materials Science and Engineering, South China University of Technology, Guangzhou, 510000, People’s Republic of China

    Jiaying Zeng

Authors
  1. Xuetao Xu
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  2. Suqing Zhao
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  4. Jiaying Zeng
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Correspondence to Xuetao Xu.

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Xu, X., Zhao, S., Liang, K. et al. Electrospinning preparation and luminescence properties of one-dimensional SrWO4: Sm3+ nanofibers. J Mater Sci: Mater Electron 25, 3324–3331 (2014). https://doi.org/10.1007/s10854-014-2021-0

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  • DOI: https://doi.org/10.1007/s10854-014-2021-0

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