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Microstructure and energy-storage performance of BaO–B2O3–SiO2 glass added (Na0.5Bi0.5)TiO3 thick films

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Abstract

(Na0.5Bi0.5)TiO3 lead-free thick films were successfully fabricated on alumina substrates via a screen printing method with 0–10 wt% BaO–B2O3–SiO2 glass addition. Microstructure, dielectric properties and energy-storage performance of the thick films were systematically investigated. The results show that the denser thick films were obtained by addition of glass. Thus, the breakdown strength, the energy-storage density and efficiency were greatly improved. The maximum recoverable energy-storage density and efficiency of sample with 1 wt% glass were 2.0 J/cm3 and 44.1 %, respectively. Meanwhile, a low leakage current density of about 10−6 A/cm2 was obtained for all samples at 100 kV/cm.

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Acknowledgments

The authors would like to acknowledge the financial support from the National Natural Science Foundation of China under Grant No. 51002071, the Program for New Century Excellent Talents in University, the Program for Young Talents of Science and Technology in Universities of Inner Mongolia Autonomous Region, and the Innovation Program of Inner Monglia University of Science and Technology no. 2011NCL035.

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Zhang, L., Hao, X., Zhang, L. et al. Microstructure and energy-storage performance of BaO–B2O3–SiO2 glass added (Na0.5Bi0.5)TiO3 thick films. J Mater Sci: Mater Electron 24, 3830–3835 (2013). https://doi.org/10.1007/s10854-013-1325-9

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