Abstract
The spectral properties of undoped and Al doped ZnO nano thin films prepared using double dip method otherwise called SILAR method (Successive Immersion Layer Adsorption Reaction) are reported. The thin films were having polycrystalline hexagonal structure. The optical properties of these films are studied and reported. The optical constants like the band gap (E g ), refractive indices (n, k), dielectric constant (ε), optical conductivity (σ), were estimated using an approximation algorithm developed from established procedures using transmittance spectrum of the thin films. The average excitation energy (E 0), oscillator strength (E d ), effective mass (m*), plasma frequency (ω p ), static dielectric constant (ε∞) and carrier concentration (N) are also estimated and reported. The highly transparent thin films showed nanowires protruding from stacked nanorods on SEM inspection that signifies the suitability of these thin films for gas sensors.
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U. Ozgur, Y.I. Alivov, C. Liu, A. Teke, M.A. Reshchikov, S. Dogan, V. Avrutin, S.-J. Cho, H. Morkoç, J. Appl. Phys. 98, 041301 (2005)
A.E. Jimenez-Gonzalez, J. Solid State Chem. 28, 176 (1997)
C. Cruz-Vázquez, F. Rocha-Alonzo, S.E. Burruel-Ibarra, M. Inoue, Superficies y Vacío 13, 89 (2001)
F. Yakuupanoglu, S. Ilican, M. Caglar, Y. Caglar, J. Optoelectron. Adv. Mater. 9, 2180 (2007)
M. Hiramatsu, K. Imaeda, N. Horio, M. Nawata, J. Vac. Sci. Technol. A 16, 669 (1998)
E.M. Kaidashev, M. Lorenz, H. von Wenckstern, A. Rahm, H.C. Semmelhack, K.H. Han, G. Benndorf, C. Bundesmann, H. Hochmuth, M. Grundmann, Appl. Phys. Lett. 82, 3901 (2003)
Z.Y. Ning, S.H. Cheng, S.B. Ge, Y. Chao, Z.Q. Gang, Y.X. Zhang, Z.G. Liu, Thin Solid Films 307, 50 (1997)
Y.G. Cao, L. Miao, S. Tanemura, M. Tanemura, Y. Kuno, Y. Hayashi, Y. Mori, Jpn. J. Appl. Phys. 45, 1623 (2006)
S.H. Jeong, B.N. Park, D.G. Yoo, J.H. Boo, J. Korean Phys. Soc. 50, 622 (2007)
J. Nishino, S. Ohshio, K. Kamata, J. Am. Ceram. Soc. 75, 3469 (1992)
M.K. Jayaraj, A. Antony, M. Ramachandran, Bull. Mater. Sci. 25, 227 (2002)
P. Suri, M. Panwar, R.M. Mehra, Mater. Sci. Poland 25, 137 (2007)
M. Suchea, S. Christoulakis, N. Katsarakis, T. Kitsopoulosa, G. Kiriakidis, Thin Solid Films 515, 6562 (2007)
T.A. Vijayan, R. Chandramohan, S. Valanarasu, J. Thirumalai, S. Venkateswaran, T. Mahalingam, S.R. Srikumar, Sci. Technol. Adv. Mater. 9, 035007 (2008)
R. Chandramohan, T.A. Vijayan, S. Arumugam, H.B. Ramalingam, V. Dhanasekaran, K. Sundaram, T. Mahalingam, Mater. Sci. Eng. B 176, 152 (2010)
I.G. Dimitrov, A.O. Dikovska, P.A. Atanasov, T.R. Stoyanchov, T. Vasilev, J. Phys. Conf. Ser. 113, 012044 (2008)
J.N. Zeng, J.K. Low, Z.M. Ren, T. Liaw, Y.F. Lu, Appl. Surf. Sci. 197, 362 (2002)
T. Mahalingam, V. Dhanasekaran, G. Ravi, S. Lee, J.P. Chu, H.-J. Lim, J. Optoelectron. Adv. Mater. 12, 1327 (2010)
A.P. Roth, J.B. Webb, D.F. Williams, Phys. Rev. B 25, 7836 (1982)
B.E. Sernelius, K.F. Berggren, Z.C. Jin, I. Hamberg, C. Granqvist, Phys. Rev. B 37, 10244 (1988)
R. Swanepoel, J. Phys. E 16, 1214 (1983)
R. Swanepoel, J. Phys. E 17, 896 (1984)
E. Marquez, A.M. Bernal-Oliva, J.M. Gonzalez-Leal, R. Prieto-Alcon, A. Ledesma, R. Jimenez-Garay, I. Martil, Mater. Chem. Phys. 60, 231 (1999)
W.G. Spitzer, H.Y. Fan, Phys. Rev. 106, 882 (1957)
T.M. Williams, D. Hunter, A.K. Pradhan, I.V. Kityk, Appl. Phys. Lett. 89, 043116 (2006)
J. Ebothe, I.V. Kityk, S. Benet, B. Claudet, K.J. Plucinski, K. Ozga, Opt. Commun. 268, 269 (2006)
S.K. Jha, C.P. Liu, Z.H. Chen, K.J. Chen, I. Bello, J.A. Zapien, W. Zhang, S.-T. Lee, J. Phys. Chem. 17, 114 (2010)
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Chandramohan, R., Dhanasekaran, V., Ezhilvizhian, S. et al. Spectral properties of aluminium doped zinc oxide thin films prepared by SILAR method. J Mater Sci: Mater Electron 23, 390–397 (2012). https://doi.org/10.1007/s10854-011-0439-1
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DOI: https://doi.org/10.1007/s10854-011-0439-1