Abstract
CaO–SrO–Li2O–Ln2O3–TiO2 ceramics were prepared by solid state reaction method, where Ln2O3 consists of equal proportions of Nd2O3 and Sm2O3. Dielectric properties and crystal structure were investigated with respect to the content of TiO2. Single phase with an orthorhombic perovskites structure was formed within the composition range of investigation. The frequency dependence of dielectric properties of the present ceramics was extensively investigated. Dielectric constant was less sensitive to frequency. However, dielectric loss and temperature coefficients were both very sensitive to frequency and gradually decreased with increasing frequency, such as the variation was more than ten times between 1 MHz and several GHz. The relationship between the temperature coefficient and dielectric loss was also discussed at different frequencies. And the mechanism of the frequency dependence was discussed in term of the role of Li ions.
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Acknowledgments
The present work was supported by Fujian Key Technologies R and D Program (2005HZ02-03), Program for New Century Excellent Talents in University of Fujian Province (XSJRC2007-16) and Fuzhou University Science Foundation (2010-XQ-01).
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Zheng, X.H., Jiang, X.C., Tang, D.P. et al. Frequency dependence of dielectric properties of CaO–SrO–Li2O–Ln2O3–TiO2 ceramics. J Mater Sci: Mater Electron 22, 781–784 (2011). https://doi.org/10.1007/s10854-010-0211-y
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DOI: https://doi.org/10.1007/s10854-010-0211-y