Abstract
The xPrTiTaO6 (1 − x) YTiNbO6 dielectric ceramic composites are fabricated through the solid state ceramic route. The compositions are calcined in the temperature range 1,200–1,260 °C and sintered in the range 1,350–1,410 °C. Structural analysis of the materials is done using X-ray Diffraction analysis. The composites contain both aeschynite and euxenite orthorhombic phases. The surface morphology of the sintered pellets is examined by scanning electron microscopy. The dielectric constant, conductance and loss factor are measured in the radio frequency region. The UV–visible spectra are recorded and the band gap is calculated. The photoluminescence spectra of the compositions are recorded and the transitions causing emission are identified. The elemental composition of the composites is confirmed using energy dispersive spectroscopy. The materials are suitable for substrate and optoelectronic applications.
Similar content being viewed by others
References
X. Qi, T.P.J. Han, H.G. Gallagher, B. Henderson, R. Illingworth, I.S. Ruddock, Optical spectroscopy of PrTiNbO6, NdTiNbO6 and ErTiNbO6 single crystals. J. Phys. Condensed Matter 8, 4837–4845 (1996)
M.-S. Zhang, J. Yu, J. Chu, Q. Chen, W. Chen, Microstructures and photoluminescence of barium titanate nanocrystals synthesized by hydrothermal process. J. Mater. Process. Technol. 137, 78–81 (2003)
G. Qian, S. Baccaro, M. Falconieri, J. Bei, A. Cecilia, G. Chen, J. Non-Cryst. Solids 354, 4626–4629 (2008)
L. Yang, Y. Tany, A. Hu, X. Chen, K. Liang, L. Zhang, Raman scattering and luminescence study on arrays of ZnO doped with Tb3+. Physica B 403, 2230–2234 (2008)
M.K. Suresh, P.R.S. Wariar, J.K. Thomas, Sam Solomon, Microwave and photoluminescent characterization of Ca2Mg3X1.75Sb0.25TiO12 (X = Nb & Ta) ceramics. J. Mater. Sci.: Mater. Electron. (2010). doi:10.1007/s10854-009-0045-7
K.P. Surendran, Sam. Solomon, M.R. Varma, P. Mohanan, M.T. Sebastian, Microwave dielectric properties of RETiTaO6 [RE = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Y, Er, Yb, Al, In] ceramics. J. Mater. Res. 17(10), 2561–2566 (2002)
M.T. Sebastian, S. Solomon, R. Ratheesh, J. George, P. Mohanan, Preparation Characterization and Microwave properties of RETiNbO6 [RE = Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Y &Yb] dielectric ceramics. J. Am. Ceramic Soc. 84(7), 1487–1489 (2001)
L. Jacob, H. Padmakumar, K.G. Gopchandran, J.K. Thomas, S. Solomon, Photoluminescence and dielectric properties of LnTiTaO6 (Ln = Ce, Pr, Sm) polycrystals. J. Mater. Sci.: Mater. Electronics 18(8), 831–835 (2007)
T. Oishi, A. Kan, H. Ohsato, H. Ogawa, Crystal structure–microwave dielectric property relations in Sm(Nb1 − x Tax)(Ti1−yZry)O6 ceramics. J. Eur. Ceramic Soc. 26, 2075–2079 (2006)
D.A. Skoog, F. James Holler, T.A. Nieman, Principles of Instrumental Analysis, 5th edn. (Harcourt Asia Pte Ltd, 1998), pp. 335–337, 355–358
Richard Payling and Peter Larkins (2008) Wiley, New York
Acknowledgments
Dr. Sam Solomon acknowledges University Grants Commission for the Post Doctoral Research award.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Dhwajam, D.B., Thomas, J.K., Joy, K. et al. Optical and dielectric properties of lanthanide titanium tantalate and niobate ceramic composites. J Mater Sci: Mater Electron 22, 384–388 (2011). https://doi.org/10.1007/s10854-010-0147-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-010-0147-2