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6-N,N-diarylsubstituted 1H-pyrazolo[3,4-b]quinoxalines-novel materials for single-layered photovoltaic devices

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Abstract

At present work organic single layered photovoltaic device, which can use polaron-assisted transport has been developed using a ITO/PEDOT:PSS (poly(3,4-ethylene dioxythiophene)-poly-(styrene sulphonate)/Active Layer/Al) architecture. We have achieved a large photovoltaic response for single layered device (yielding up to 0.82%) by varying the values of state dipole moments of the chromophore. Interaction of chromophore with polymer chains and resulting polaronic transport mechanism seems to be very important as well.

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Acknowledgments

This work was supported by grant 66/N-Singapore/2007/0. One of the authors (AD) would like to thank for a financial support from the Professor Janusz Żmija (The Rector of the University of Agriculture in Krakow).

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Authors and Affiliations

  1. Institute of Physics, Technical University of Cracow, Podchorążych 1, Krakow, Poland

    E. Gondek

  2. Department of Chemistry, University of Agriculture, ul.Balicka 122, 31-149, Krakow, 30-059, Poland

    A. Danel

  3. Faculty of Chemistry, Silesian University of Technology, ul. M. Strzody 9, 44-100, Gliwice, Poland

    I. V. Kityk

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  1. E. Gondek
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  3. I. V. Kityk
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Correspondence to E. Gondek.

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Gondek, E., Danel, A. & Kityk, I.V. 6-N,N-diarylsubstituted 1H-pyrazolo[3,4-b]quinoxalines-novel materials for single-layered photovoltaic devices. J Mater Sci: Mater Electron 20, 461–468 (2009). https://doi.org/10.1007/s10854-008-9751-9

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