Abstract
Nanoporous ZnO thin films were deposited by electrochemical anodization of high purity Zn at room temperature using Pt counter electrode, calomel reference electrode and oxalic acid as the electrolyte. The crystallinity and the surface morphology were studied by X-ray diffraction (XRD) and Field emission scanning electron microscope (FESEM). The variation in molar concentration of oxalic acid during anodization had significant effect on the crystal size and the pore size particularly in the presence of UV light. An increase in room temperature band gap from 3.25 to 3.87 eV of ZnO film grown in 0.3 M oxalic acid indicates a quantum confinement effect and it was further confirmed by a blue shift of the photoluminescence (PL) spectra. A possible mechanism of the anodization and the photoetching in the presence of UV light of the ZnO film have been suggested.
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M.M. Driscoll et al., in Proceedings IEEE International Ultrasonic Symposium, pp. 365–369 (1986)
M.S. Wu, A. Azuma, T. Shiosaki, T. Kawabata, IEEE Trans. Ultrason. Ferroelectr. Freq. Control 36, 442–445 (1989)
M.H. Huang et al., Science 292, 1897 (2001)
G.D. Mahan, J. Appl. Phys. 54, 7 (1983)
K. Keis, E. Magnusson, H. Lindstrom, S.E. Lindquist, A. Hagfeldt, Sol. Energy Mater. Sol. Cells 73, 51 (2002)
D. Gruber, F. Kraus, J. Muller, Sens. Actuators B 92, 81 (2003)
S.W. Kim, S. Fujita, S. Fujita, Appl. Phys. Lett. 81, 5036 (2002)
X.W. Sun, H.S. Kwok, J. Appl. Phys. 86, 408 (1999)
D.K. Hwang, S.H. Kang, J.H. Lim, E.J. Yang, J.Y. Oh, J.H. Yang, S.J. Parka, Appl. Phys. Lett. 86, 222101 (2005)
Z.K. Tang, G.K.L. Wong, P. Yu, M. Kawasaki, A. Ohtomo, H. Koinuma, Y. Segawa, Appl. Phys. Lett. 72, 25 (1998)
P. Bhattacharyya, P.K. Basu, H. Saha, S. Basu, Sens. Lett. 4, 371–376 (2006)
F.K. Shan, Y.S. Yu, J. Eur. Ceram. Soc. 24, 1869 (2004)
N.K. Zayer, R. Greef, K. Rogers, A.J.C. Grellier, C.N. Pannell, Thin Sol. Films 179, 352 (1999)
D. Bao, A. Kuang, H. Gu, Thin Sol. Films 37, 312 (1998)
H. Ishizaki, M. Imaizumi, S. Matsuda, M. Izaki, T. Ito, Thin Sol. Films 65, 411 (2002)
P.N. Bartlett, J.J. Baumberg, P.R. Birkin, M.A. Ghanem, M.C. Netti, Chem. Mater. 14, 2199 (2002)
Q.B. Meng, C.H. Fu, Y. Einaga, Z.Z. Gu, A. Fujishima, O. Sato, Chem. Mater. 14, 83 (2002)
H. Yan, Y. Yang, Z. Fu, B. Yang, L. Xia, S. Fu, F. Li, Electrochem. Commun. 7, 1117 (2005)
G.S Wua T. Xiea, X.Y. Yuana, Y. Lia, L. Yanga, Y.H. Xiaoa, L.D. Zhanga, Solid State Commun. 134, 485 (2005)
E.A. Davis, N.F. Mott, Philos. Mag. 22, 903 (1970)
Z.H. Hwang, J.M. Hwang, H.L. Hwang, W.H. Hung, Appl. Phys. Lett. 84, 19 (2004)
L. Brus, J. Phys. Chem. 90, 2555 (1986)
Y. Kayanuma, Phys. Rev. B 38, 9797 (1988)
K.K. Kim, N. Koguchi, Y.W. Ok, T.Y. Seong, S.J. Park, Appl. Phys. Lett. 84, 3810 (2004)
S.T. Tan, B.J. Chen, X.W. Sun, W.J. Fan, H.S. Kwok, X.H. Zhang, S.J. Chua, J. Appl. Phys. 98, 013505 (2005)
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Basu, P.K., Saha, N., Maji, S. et al. Nanoporous ZnO thin films deposited by electrochemical anodization: effect of UV light. J Mater Sci: Mater Electron 19, 493–499 (2008). https://doi.org/10.1007/s10854-008-9604-6
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DOI: https://doi.org/10.1007/s10854-008-9604-6