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FT-IR, Raman and UV–VIS spectroscopic studies of copper doped 3Bi2O3 ·B2O3 glass matix

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Abstract

FT-IR, Raman and UV–VIS experimental results were presented for xCuO·(100-x)[3Bi2O3·B2O3] glass system, where 0 ≤ x ≤ 50 mol%. The FT-IR measurements indicate the presence in xCuO·(100-x)[3Bi2O3·B2O3] glasses of BO3, BO4 units, BiO3 pyramidal and distorted BiO6 octahedral units and their dependence of CuO content. The Raman scattering data indicate that for 0 ≤ x ≤ 10 mol% the structure of studied glasses consist from BiO3 pyramidal and distorted BiO6 octahedral units, ring and chain type of metaborate groups, ortoborate and pyroborate groups. For higher concentration the Raman spectra suggest that the structure become more disordered. The FT-IR and Raman bands characteristic for CuO were not directly evidenced, but the absorption bands specific for the glass matrix are influenced by the presence of copper ions in the glass network structure. The optical absorption confirms the presence of Cu2+ in the CuO doped 3Bi2O3·B2O3 glass matrix.

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  1. Faculty of Physics, Babes-Bolyai University, Cluj-Napoca, 400084, Romania

    Ioan Ardelean & Simona Cora

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  1. Ioan Ardelean
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  2. Simona Cora
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Correspondence to Ioan Ardelean.

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Ardelean, I., Cora, S. FT-IR, Raman and UV–VIS spectroscopic studies of copper doped 3Bi2O3 ·B2O3 glass matix. J Mater Sci: Mater Electron 19, 584–588 (2008). https://doi.org/10.1007/s10854-007-9393-3

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  • DOI: https://doi.org/10.1007/s10854-007-9393-3

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