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Synthesis and characterization of new glasses based on Li2S-P2S5-Sb2S3 system

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Abstract

There is great interest in sulfide glasses because of their high lithium ion conductivity. New sulfide glasses based on Li2S-P2S5-Sb2S3 system have been synthesized by a classical quenching technique. A summary of thermal and structural characterization is presented. Electrical conductivities of the samples have been determined by Impedance Spectroscopy. The compositions of low lithium content (below 20% mol) have presented low electronic conductivities close to 10−8 S/cm at room temperature. The compositions of medium lithium content (30–50% mol) have presented mixed ionic-electronic behavior with predominant on ionic conductivity with a maximum values around 10−6 S/cm for samples up to 50% Li2S at room temperature. Arrhenius behavior is verified between 25°C and Tg for all glasses with activation energies about 0.55–0.64 eV. A comparative study of conductivities with glasses belonging to the other chalcogenide systems has been undertaken.

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References

  1. J.P. Malugani, G. Robert, Solid State Ionics 1, 519 (1980)

    Article  CAS  Google Scholar 

  2. J.L. Souquet, E. Robinel, B. Barrau, M. Ribes, Solid State Ionics 3/4, 317 (1981)

    Article  Google Scholar 

  3. M. Yamashita, H. Yamanaka, H. Wakabayashi, Solid State Ionics 89, 299 (1996)

    Article  CAS  Google Scholar 

  4. M. Menetrier, C. Estournes, A. Levasseur, K.J. Rao, Solid State Ionics 53–56, 1208 (1992)

    Article  Google Scholar 

  5. S. Kondo, K. Takada, Y. Yamamura, Solid State Ionics 53/56, 1183 (1992)

    Article  Google Scholar 

  6. Z. Zhang, J.H. Kennedy, Solid State Ionics 38, 217 (1990)

    Article  CAS  Google Scholar 

  7. J.H. Kennedy, C. Schaupp, H. Eckert, M. Ribes, Solid State Ionics 45, 21–27 (1991)

    Article  CAS  Google Scholar 

  8. M.C.R. Shastry, M. Menetrier, A. Levasseur, Solid State Comm 85, 887 (1993)

    Article  CAS  Google Scholar 

  9. M. Ribes, E. Bychkov, A. Pradel, J. of Optoelectronics and Advanced Materials 3(3), 665 (2001)

    CAS  Google Scholar 

  10. Z. Nagamedianova, E. Sánchez, J. Non-Cryst Solids 311(1), 1 (2002)

    Article  CAS  Google Scholar 

  11. Z. Nagamedianova, E. Sánchez, J. Non-Cryst Solids 329, 13 (2003)

    Article  CAS  Google Scholar 

  12. J.A. Cabral, C. Fredericci, E.D. Zanotto, J. Non-Cryst Solids 219, 182 (1997)

    Article  CAS  Google Scholar 

  13. L. Bih, M. Omari, J.M. Reau, M. Haddad, D. Boudlich, A. Yacoubi, A. Nadiri, Solid State Ionics 132, 71 (2000)

    Article  CAS  Google Scholar 

  14. M.D. Ingram, Physica A. 266, 390 (1999)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

Financial support from programs NSF-CONACYT (35998U), CONACYT (46919) and PAYCyT-UANL is gratefully acknowledged.

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  1. Laboratorio de Investigación del Vidrio, Facultad de Ciencias Químicas, Universidad Autónoma de Nuevo León, Pedro de Alba s/n, Cd. Universitaria, San Nicolás de los Garza, NL, 66400, Mexico

    Z. Nagamedianova & E. Sánchez

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  1. Z. Nagamedianova
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  2. E. Sánchez
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Correspondence to E. Sánchez.

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Nagamedianova, Z., Sánchez, E. Synthesis and characterization of new glasses based on Li2S-P2S5-Sb2S3 system. J Mater Sci: Mater Electron 18, 547–552 (2007). https://doi.org/10.1007/s10854-006-9074-7

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  • DOI: https://doi.org/10.1007/s10854-006-9074-7

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