Skip to main content
SpringerLink
Log in

Effect of oxide film on corrosion behavior of NiTi coating prepared by extreme high-speed laser cladding

  • Metals & corrosion
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

NiTi alloy has excellent corrosion resistance and wear resistance, and is an important protective coating being developed for marine equipment. In this paper, the crack and pore-free high-quality NiTi coatings were firstly synthesized in situ by extreme high-speed laser cladding (EHLA) technology under high temperature oxidation environment. The effects of laser power of EHLA on the temperature field, stress field and coating properties of NiTi coatings were studied by combining finite element calculation and experiments. The results show that a corrosion-resistant and wear-resistant TiO2 oxide film was generated in situ on the coating surface during EHLA process. Furthermore, the denser oxide film can be obtained by proper annealing treatment, and the wear resistance and corrosion resistance of the sample can be further improved. This provides a feasible fashion for EHLA to in situ synthesize wear-resistant and corrosion-resistant alloy coatings with low defects.

Graphical abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Figure 1
Figure 2
Figure 3
Figure 4
Figure 5
Figure 6
Figure 7
Figure 8
Figure 9
Figure 10
Figure 11
Figure 12
Figure 13
Figure 14
Figure 15
Figure 16
Figure 17
Figure 18

Similar content being viewed by others

Data availability

Not Applicable.

References

  1. Xiao M, Gao H, Sun L et al (2021) Microstructure and mechanical properties of Fe-based amorphous alloy coatings prepared by ultra-high speed laser cladding. Mater Lett 297:130002. https://doi.org/10.1016/j.matlet.2021.130002

    Article  CAS  Google Scholar 

  2. Schopphoven T, Gasser A, Wissenbach K, Poprawe R (2016) Investigations on ultra-high-speed laser material deposition as alternative for hard chrome plating and thermal spraying. J Laser Appl 28:022501. https://doi.org/10.2351/1.4943910

    Article  CAS  Google Scholar 

  3. Wang X, Xing Z, Liu Y et al (2019) Composite ceramic-Ni60 coating fabricated via supersonic plasma spraying. Chin J Phys 61:72–79. https://doi.org/10.1016/j.cjph.2019.08.012

    Article  CAS  Google Scholar 

  4. Xu G, Kutsuna M, Liu Z, Zhang H (2006) Characteristics of Ni-based coating layer formed by laser and plasma cladding processes. Mater Sci Eng A 417:63–72. https://doi.org/10.1016/j.msea.2005.08.192

    Article  CAS  Google Scholar 

  5. Wang Y, Liu X-B, Liu Y-F et al (2020) Microstructure and tribological performance of Ni60-based composite coatings on Ti6Al4V alloy with different Ti3SiC2 ceramic additions by laser cladding. Ceram Int 46:28996–29010. https://doi.org/10.1016/j.ceramint.2020.08.071

    Article  CAS  Google Scholar 

  6. Zhang M, Li Y, Feng Y et al (2021) Studies on different oxidation behaviors of TiAlN on titanium alloy and stainless steel under thermal cycling. Corros Sci 192:109865. https://doi.org/10.1016/j.corsci.2021.109865

    Article  CAS  Google Scholar 

  7. Gu J-L, Lu S-Y, Shao Y, Yao K-F (2021) Segregating the homogeneous passive film and understanding the passivation mechanism of Ti-based metallic glasses. Corros Sci 178:109078. https://doi.org/10.1016/j.corsci.2020.109078

    Article  CAS  Google Scholar 

  8. Silva DD, Campanelli LC, Bergmann L et al (2020) On the stability of the passive Ti-6Al-4V film of friction stir welds with stainless steel: effect of not native metal species. Electrochimica Acta 358:136900. https://doi.org/10.1016/j.electacta.2020.136900

    Article  CAS  Google Scholar 

  9. Liu Q, Pang M, Chen J et al (2021) Microstructure and properties characterization of Ti-containing Ni60/Graphite self-lubricating composite coatings applied on 300M ultra-high strength steel by laser cladding. Mater Chem Phys 266:124554. https://doi.org/10.1016/j.matchemphys.2021.124554

    Article  CAS  Google Scholar 

  10. Wang Q, Zhang H, Yoshida H et al (2022) Time evolution of the passivation behavior of Ti-6Al-4V in 0.5 M sulfuric acid. J Electrochem Soc 169:105505

    Article  Google Scholar 

  11. Surface treatment of NiTi for medical applications: minimally invasive therapy & allied technologies: Vol 13, No 4. https://www.tandfonline.com/doi/abs/https://doi.org/10.1080/13645700410020278. Accessed 1 Jun 2023

  12. Shao AL, Cheng Y, Zhou Y et al (2013) Electrochemistry properties of multilayer TiN/Ti coatings on NiTi alloy for cardiac occluder application. Surf Coat Technol 228:S257–S261. https://doi.org/10.1016/j.surfcoat.2012.05.129

    Article  CAS  Google Scholar 

  13. Wang S, Li Y, Zhao T (2012) Effect of thermal oxidation on the surface characteristics and corrosion behavior of a Ta-implanted Ti-50.6Ni shape memory alloy. Int J Miner Metall Mater 19:1134–1141. https://doi.org/10.1007/s12613-012-0682-3

    Article  CAS  Google Scholar 

  14. Starosvetsky D, Gotman I (2001) TiN coating improves the corrosion behavior of superelastic NiTi surgical alloy. Surf Coat Technol 148:268–276. https://doi.org/10.1016/S0257-8972(01)01356-1

    Article  CAS  Google Scholar 

  15. Li L, Shen F, Zhou Y, Tao W (2019) Comparative study of stainless steel AISI 431 coatings prepared by extreme-high-speed and conventional laser cladding. J Laser Appl 31:042009. https://doi.org/10.2351/1.5094378

    Article  CAS  Google Scholar 

  16. Xu P, Lin C, Zhou C, Yi X (2014) Wear and corrosion resistance of laser cladding AISI 304 stainless steel/Al2O3 composite coatings. Surf Coat Technol 238:9–14. https://doi.org/10.1016/j.surfcoat.2013.10.028

    Article  CAS  Google Scholar 

  17. Shen F, Tao W, Li L et al (2020) Effect of microstructure on the corrosion resistance of coatings by extreme high speed laser cladding. Appl Surf Sci 517:146085. https://doi.org/10.1016/j.apsusc.2020.146085

    Article  CAS  Google Scholar 

  18. Xu Q-L, Zhang Y, Liu S-H et al (2020) High-temperature oxidation behavior of CuAlNiCrFe high-entropy alloy bond coats deposited using high-speed laser cladding process. Surf Coat Technol 398:126093. https://doi.org/10.1016/j.surfcoat.2020.126093

    Article  CAS  Google Scholar 

  19. EHLA: extreme high‐speed laser material deposition. https://onlinelibrary.wiley.com/doi/epdf/https://doi.org/10.1002/latj.201700020. Accessed 1 Jun 2023

  20. Yuan W, Li R, Chen Z et al (2021) A comparative study on microstructure and properties of traditional laser cladding and high-speed laser cladding of Ni45 alloy coatings. Surf Coat Technol 405:126582. https://doi.org/10.1016/j.surfcoat.2020.126582

    Article  CAS  Google Scholar 

  21. Chen L, Zhang X, Wu Y et al (2022) Effect of surface morphology and microstructure on the hot corrosion behavior of TiC/IN625 coatings prepared by extreme high-speed laser cladding. Corros Sci 201:110271. https://doi.org/10.1016/j.corsci.2022.110271

    Article  CAS  Google Scholar 

  22. Liu M-X, Li Z, Chang G-R, Yin Z-F, Xiu-Ping Zhang Y, Meng Y-Y X, Ma F, Ke-Wei X (2022) An investigation of the surface quality and corrosion resistance of laser remelted and extreme high-speed laser cladded Ni-based alloy coating. Int J Electrochem Sci 17:220537. https://doi.org/10.20964/2022.05.51

    Article  CAS  Google Scholar 

  23. Zhang X, Li S, Sun W et al (2021) Study on the corrosion behavior of copper coupled with TiO2 with different crystal structures. Corros Sci 183:109352. https://doi.org/10.1016/j.corsci.2021.109352

    Article  CAS  Google Scholar 

  24. Piekarska W, Kubiak M (2011) Three-dimensional model for numerical analysis of thermal phenomena in laser–arc hybrid welding process. Int J Heat Mass Transf 54:4966–4974. https://doi.org/10.1016/j.ijheatmasstransfer.2011.07.010

    Article  Google Scholar 

  25. Rahman Chukkan J, Vasudevan M, Muthukumaran S et al (2015) Simulation of laser butt welding of AISI 316L stainless steel sheet using various heat sources and experimental validation. J Mater Process Technol 219:48–59. https://doi.org/10.1016/j.jmatprotec.2014.12.008

    Article  CAS  Google Scholar 

  26. Aghaee Attar M, Ghoreishi M, Malekshahi Beiranvand Z (2020) Prediction of weld geometry, temperature contour and strain distribution in disk laser welding of dissimilar joining between copper & 304 stainless steel. Optik 219:165288. https://doi.org/10.1016/j.ijleo.2020.165288

    Article  CAS  Google Scholar 

  27. Kong F, Ma J, Kovacevic R (2011) Numerical and experimental study of thermally induced residual stress in the hybrid laser–GMA welding process. J Mater Process Technol 211:1102–1111. https://doi.org/10.1016/j.jmatprotec.2011.01.012

    Article  Google Scholar 

  28. Sun GF, Wang ZD, Lu Y et al (2018) Numerical and experimental investigation of thermal field and residual stress in laser-MIG hybrid welded NV E690 steel plates. J Manuf Process 34:106–120. https://doi.org/10.1016/j.jmapro.2018.05.023

    Article  Google Scholar 

  29. Kong F, Kovacevic R (2010) 3D finite element modeling of the thermally induced residual stress in the hybrid laser/arc welding of lap joint. J Mater Process Technol 210:941–950. https://doi.org/10.1016/j.jmatprotec.2010.02.006

    Article  CAS  Google Scholar 

  30. A comparison of residual stresses in multi pass narrow gap laser welds and gas-tungsten arc welds in AISI 316L stainless steel-Science Direct. https://www.sciencedirect.com/science/article/pii/S0308016113001683. Accessed 1 Jun 2023

  31. Zhang Y, Gao X, Liang X et al (2020) Effect of laser remelting on the microstructure and corrosion property of the arc-sprayed AlFeNbNi coatings. Surf Coat Technol 398:126099. https://doi.org/10.1016/j.surfcoat.2020.126099

    Article  CAS  Google Scholar 

  32. Khodabakhshi F, Farshidianfar MH, Gerlich AP et al (2020) Effects of laser additive manufacturing on microstructure and crystallographic texture of austenitic and martensitic stainless steels. Addit Manuf 31:100915. https://doi.org/10.1016/j.addma.2019.100915

    Article  CAS  Google Scholar 

  33. Biesinger MC, Lau LWM, Gerson AR, Smart RStC, (2010) Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Sc, Ti, V, Cu and Zn. Appl Surf Sci 257:887–898. https://doi.org/10.1016/j.apsusc.2010.07.086

    Article  CAS  Google Scholar 

  34. Chen L, Richter B, Zhang X et al (2020) Modification of surface characteristics and electrochemical corrosion behavior of laser powder bed fused stainless-steel 316L after laser polishing. Addi Manuf 32:101013. https://doi.org/10.1016/j.addma.2019.101013

    Article  CAS  Google Scholar 

  35. Gu D, Zhang H, Dai D et al (2020) Anisotropic corrosion behavior of Sc and Zr modified Al-Mg alloy produced by selective laser melting. Corros Sci 170:108657. https://doi.org/10.1016/j.corsci.2020.108657

    Article  CAS  Google Scholar 

  36. Cao M, Liu L, Yu Z et al (2019) Electrochemical corrosion behavior of 2A02 Al alloy under an accelerated simulation marine atmospheric environment. J Mater Sci Technol 35:651–659. https://doi.org/10.1016/j.jmst.2018.09.060

    Article  CAS  Google Scholar 

  37. Xu X, Du JL, Luo KY et al (2021) Microstructural features and corrosion behavior of Fe-based coatings prepared by an integrated process of extreme high-speed laser additive manufacturing. Surf Coat Technol 422:127500. https://doi.org/10.1016/j.surfcoat.2021.127500

    Article  CAS  Google Scholar 

  38. Influence of solution heat treatment on the microstructural evolution and mechanical behavior of 60NiTi-ScienceDirect. https://www.sciencedirect.com/science/article/pii/S092583881833679X. Accessed 1 Jun 2023

  39. Effects of solution and aging treatments on corrosion resistance of as-cast 60NiTi Alloy | SpringerLink. https://link.springer.com/article/https://doi.org/10.1007/s11665-016-2402-z. Accessed 1 Jun 2023

Download references

Acknowledgements

This study was supported financially by the National Key R&D Program of China (2020YFB2010401), Key R&D Program of Zhejiang (2023C01089), Science and Technology Innovation 2025 Major Project of Ningbo (2022Z011), Zhejiang Provincial Natural Science Foundation (Grant No. LR20E050001) and "Pioneer" and "Leading Goose" R&D Program of Zhejiang.

Author information

Authors and Affiliations

  1. Taiyuan University of Science and Technology, Taiyuan, 030024, China

    Ruixue Li & Zhisheng Wu

  2. Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201, China

    Ruixue Li, Xuming Pang, Gang Liu, Yongxin Wang & Jibin Pu

Authors
  1. Ruixue Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Xuming Pang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Gang Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Zhisheng Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yongxin Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Jibin Pu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Xuming Pang or Jibin Pu.

Ethics declarations

Conflict of interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Ethical approval

Not Applicable.

Additional information

Handling Editor: Maude Jimenez.

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Li, R., Pang, X., Liu, G. et al. Effect of oxide film on corrosion behavior of NiTi coating prepared by extreme high-speed laser cladding. J Mater Sci 58, 12414–12432 (2023). https://doi.org/10.1007/s10853-023-08764-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-023-08764-1

Search

Navigation