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Microstructure analysis and quantitative strengthening evaluation of medium carbon bainitic multiphase steel

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Abstract

The microstructure and properties of bainitic multiphase steels with bainitic ferrite as the main phase are the focus of the current research. In the work, multiphase microstructures of pre-formed martensite (PM), bainitic ferrite (BF), and retained austenite (RA) was obtained via austempering processes in medium carbon bainitic steel. The relationship between the multiphase characteristics and mechanical properties was analyzed quantitatively. The results show that the thickness of bainitic ferrite laths and the size of blocky retained austenite of the PM-BF-RA samples are smaller than those of the BF-RA samples. The dislocation density of bainitic ferrite and carbon content in retained austenite of the PM-BF-RA samples are higher. The PM-BF-RA samples obtain higher strength. The yield strength that was calculated by measured microstructural parameters is similar to the tested value. The dominant strengthening phases of PM-BF-RA samples are pre-formed martensite and bainitic ferrite dual phases, while those of the BF-RA samples are the bainitic ferrite. The main of the strengthening mechanism of bainitic ferrite is grain boundary strengthening, while it is solid solution strengthening for martensite and retained austenite. Small and stable retained austenite with high carbon content effectively ensures the high plasticity of PM-BF-RA samples. Moreover, the high toughness of PM-BF-RA samples can be attributed to fine bainitic ferrite and small blocky retained austenite. This study demonstrates that medium carbon bainitic multiphase steel with PM-BF-RA microstructure exhibits excellent combination of strength, plasticity, and toughness.

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References

  1. Caballero FG, Bhadeshia HKDH (2004) Very strong bainite. Curr Opin Solid St M 8(3):251–257

    Article  CAS  Google Scholar 

  2. Haiko O, Kaikkonen P, Somani M, Valtonen K, Kmi J (2020) Characteristics of carbide-free medium-carbon bainitic steels in high-stress abrasive wear conditions. Wear 456–457:203386

    Article  Google Scholar 

  3. Kumar A, Makineni SK, Dutta A, Goulas C, Steenbergen M, Petrov RH, Sietsma J (2019) Design of high-strength and damage-resistant carbide-free fine bainitic steels for railway crossing applications. Mater Sci Eng A 759:210–223

    Article  CAS  Google Scholar 

  4. Zhao J, Wang TS, Lv B, Zhang FC (2015) Microstructures and mechanical properties of a modified high-C-Cr bearing steel with nano-scaled bainite. Mater Sci Eng A 628:327–331

    Article  CAS  Google Scholar 

  5. Ravi AM, Navarro-López A, Sietsma J, Santofimia MJ (2020) Influence of martensite/austenite interfaces on bainite formation in low-alloy steels below Ms. Acta Mater 188:1–12

    Article  Google Scholar 

  6. Lu XH, Yang ZH, Qian DS, Lan J, Hua L (2021) Effect of martensite pre-quenching on bainite transformation kinetics, martensite/bainite duplex microstructures, mechanical properties and retained austenite stability of GCr15 bearing steel. J Mater Res Technol 15:2429–2438

    Article  CAS  Google Scholar 

  7. Zhao JL, Lv B, Zhang FC, Yang ZN, Qian LH, Chen C, Long XY (2019) Effects of austempering temperature on bainitic microstructure and mechanical properties of a high-C high-Si steel. Mater Sci Eng A 742:179–189

    Article  CAS  Google Scholar 

  8. Baradari S, Boutorabi SMA (2015) Effects of isothermal transformation conditions on the microstructure and hardness values of a high-carbon Al-Si alloyed steel. Mater Des 86:603–609

    Article  CAS  Google Scholar 

  9. Jian F, Frankenbach T, Wettlaufer M (2017) Strengthening 42CrMo4 steel by isothermal transformation below martensite start temperature. Mater Sci Eng A 683:110–115

    Article  Google Scholar 

  10. Yang ZN, Liu CB, Zhang CY, Fang QW, Li YG, El-Fallah GMAM, Ooi SW, Zhang FC (2021) Microplasticity behavior of multiphase high-strength nanobainitic steel based on a modified law of mixtures. Mater Sci Eng A 825:141848

    Article  CAS  Google Scholar 

  11. Zhao JL, Zhang FC, Lv B, Yang ZN, Chen C, Long XY, Zhao XJ, Chu CH (2019) Inconsistent effects of austempering time within transformation stasis on monotonic and cyclic deformation behaviors of an ultrahigh silicon carbide-free nanobainite steel. Mater Sci Eng A 751:80–89

    Article  CAS  Google Scholar 

  12. Long XY, Zhao GC, Zhang FC, Xu S, Yang ZN, Du GJ, Branco R (2020) Evolution of tensile properties with transformation temperature in medium-carbon carbide-free bainitic steel. Mater Sci Eng A 775:138964

    Article  CAS  Google Scholar 

  13. Qian LH, Li Z, Wang TL, Li DD, Zhang FC, Meng JY (2022) Roles of pre-formed martensite in below-Ms bainite formation, microstructure, strain partitioning and impact absorption energies of low-carbon bainitic steel. J Mater Sci Technol 96:69–84

    Article  Google Scholar 

  14. Pashangeh S, Somani M, Banadkoukia SSG (2020) Microstructural evolution in a high-silicon medium carbon steel following quenching and isothermal holding above and below the Ms temperature. J Mater Sci Technol 9(3):3438–3446

    CAS  Google Scholar 

  15. Garcia-Mateo C, Caballero FG, Bhadeshia HKDH (2005) Mechanical properties of low-temperature bainite. Mater Sci Forum 500–501:495–502

    Article  Google Scholar 

  16. Tan X, Xu Y, Yang X, Wu D (2014) Microstructure-properties relationship in a one-step quenched and partitioned steel. Mater Sci Eng A 589:101–111

    Article  CAS  Google Scholar 

  17. Zhao LJ, Qian LH, Zhou Q, Li DD, Wang TL, Jia ZG, Zhang FC, Meng JY (2019) The combining effects of ausforming and below-Ms or above-Ms austempering on the transformation kinetics, microstructure and mechanical properties of low-carbon bainitic steel. Mater Des 183:108–123

    Article  Google Scholar 

  18. Guo H, Feng XY, Zhao AM, Li Q, Ma J (2019) Influence of prior martensite on bainite transformation, microstructures, and mechanical properties in ultra-fine bainitic steel. Materials 12(3):527

    Article  CAS  Google Scholar 

  19. Navarro-López A, Hidalgo J, Sietsma J, Santofimia MJ (2018) Influence of the prior athermal martensite on the mechanical response of advanced bainitic steel. Mater Sci Eng A 735:343–353

    Article  Google Scholar 

  20. Hasan HS, Peet MJ, Avettand-Fènoël M-N, Bhadeshia HKDH (2014) Effect of tempering upon the tensile properties of a nanostructured bainitic steel. Mater Sci Eng A 615:340–347

    Article  CAS  Google Scholar 

  21. Fostera D, Paladugu M, Hughes J, Kapousidou M, Barcellini C, Daisenberger D, Jimenez-Melero E (2020) Comparative micromechanics assessment of high-carbon martensite/bainite bearing steel microstructures using in-situ synchrotron X-ray diffraction. Materialia 14:100948

    Article  Google Scholar 

  22. Abbaszadeh P, Kheirandish S, Saghafian H, Goodarzy MH (2017) Effect of austenitizing temperature on mechanical properties of the mixed bainite-martensite microstructure in CrMoV steel. Mater Res 21(1):0469

    Article  Google Scholar 

  23. Garcia-Mateo C, Caballero FG, Sourmail T, Kuntz M, Cornide J, Smanio V, Elvira R (2012) Tensile behaviour of a nanocrystalline bainitic steel containing 3 wt% silicon. Mater Sci Eng A 549:185–192

    Article  CAS  Google Scholar 

  24. Zhao JL, Zhao XM, Dong CY, Zhao XY, Kang SX (2018) Effect of bainitic transformation combined with hot forming on the microstructure and mechanical properties of bainite-martensite multiphase steel. Mater Sci Eng A 731:102–106

    Article  CAS  Google Scholar 

  25. Avishana B, Khoshkebari SM, Yazdani S (2021) Effect of pre-existing martensite within the microstructure of nano bainitic steel on its mechanical properties. Mater Chem Phys 260:124160

    Article  Google Scholar 

  26. Long XY, Sun DY, Wang K, Zhang FC, Yang ZN, Li YG, Zheng CL (2022) Effect of carbon distribution range in mixed bainite/martensite/retained austenite microstructure on mechanical properties. J Mater Res Technol 17:898–912

    Article  CAS  Google Scholar 

  27. De AK, Murdock DC, Mataya MC, Speer JG, Matlock DK (2004) Quantitative measurement of deformation-induced martensite in 304 stainless steel by X-ray diffraction. Scripta Mater 50(12):1445–1449

    Article  CAS  Google Scholar 

  28. Williamson GK, Smallman RE III (1956) Dislocation densities in some annealed and cold-worked metals from measurements on the X-ray debye-scherrer spectrum. Philos Mag 1(1):34–46

    Article  CAS  Google Scholar 

  29. Germain L, Gey N, Mercier R, Blaineau P, Humbert M (2012) An advanced approach to reconstructing parent orientation maps in the case of approximate orientation relations: Application to steels. Acta Mater 60:4551–4562

    Article  CAS  Google Scholar 

  30. Garcia-Mateo C, Caballero FG, Bhadeshia HKDH (2003) Acceleration of Low-temperature Bainite. ISIJ Int 43(11):1821–1825

    Article  CAS  Google Scholar 

  31. Koistinen D, Marburger R (1959) A general equation prescribing the extent of the austenite-martensite transformation in pure iron-carbon alloys and plain carbon steels. Acta Metall 7:59–60

    Article  Google Scholar 

  32. Dyson DJ, Holmes B (1970) Effect of alloying additions on the lattice parameter of austenite. J Iron Steel Inst 208:469–474

    CAS  Google Scholar 

  33. Rakha K, Beladi H, Timokhina H, Xiong XY, Kabra S, Liss K-D, Hodgson P (2014) On low temperature bainitic transformation characteristics using in-situ neutron diffraction and atom probe tomography. Mater Sci Eng A 589:303–309

    Article  CAS  Google Scholar 

  34. Wang XB, Liu CB, Qin YM, Li YG, Yang ZN, Long XY, Wang MM, Zhang FC (2022) Effect of tempering temperature on microstructure and mechanical properties of nanostructured bainitic steel. Mater Sci Eng A 832:142357

    Article  CAS  Google Scholar 

  35. Xiong XC, Chen B, Huang MX, Wang JF, Wang L (2013) The effect of morphology on the stability of retained austenite in a quenched and partitioned steel. Scr Mater 68:321–324

    Article  CAS  Google Scholar 

  36. M. Peet, H.K.D.H. Bhadeshia, Available online: https://www.msm.cam.ac.uk/map/steel/tar/mucg83.exe

  37. Yoozbashi MN, Yazdani S, Wang TS (2011) Design of a new nanostructured, high-Si bainitic steel with lower cost production. Mater Des 32(6):3248–3253

    Article  CAS  Google Scholar 

  38. Kawata H, Hayashi K, Sugiura N, Yoshinaga N, Takahashi M (2010) Effect of martensite in initial structure on bainite transformation. Mater Sci Forum 638–642:3307–3312

    Article  Google Scholar 

  39. Gong W, Tomota Y, Harjo S, Su YH, Aizawa K (2015) Effect of prior martensite on bainite transformation in nanobainite steel. Acta Mater 85:243–249

    Article  CAS  Google Scholar 

  40. Toji Y, Matsuda H, Raabe D (2016) Effect of Si on the acceleration of bainite transformation by pre-existing martensite. Acta Mater 116:250–262

    Article  CAS  Google Scholar 

  41. Yan JJ, Song H, Dong YP, Quach WM, Yan M (2020) High strength (~2000MPa) or highly ductile (~11%) additively manufactured H13 by tempering at different conditions. Mater Sci Eng A 773:138845

    Article  CAS  Google Scholar 

  42. Carretero Olalla V, Bliznuk V, Sanchez N, Thibaux P, Kestens LAI, Petrov RH (2014) Analysis of the strengthening mechanisms in pipeline steels as a function of the hot rolling parameters. Mater Sci Eng A 604:46–56

    Article  CAS  Google Scholar 

  43. Kamikawa N, Sato K, Miyamoto G, Murayama M, Sekido N, Tsuzaki K, Furuhara T (2016) Stress-strain behavior of ferrite and bainite with nano-precipitation in low carbon steels. Acta Mater 83:383–396

    Article  Google Scholar 

  44. Winchell PG, Cohen M (1962) The strength of martensite. Trans ASM 55:347

    CAS  Google Scholar 

  45. Langford G, Cohen M (1970) Calculation of cell-size strengthening of wire-drawn iron. Metall Mater Trans B 1:1478–1480

    Article  CAS  Google Scholar 

  46. Young CH, Bhadeshia HKDH (1994) Strength of mixtures of bainite and martensite. Mater Sci Technol 10:209

    Article  CAS  Google Scholar 

  47. Hutchinson B, Hagström J, Karlsson O, Lindell D, Tornberg M, Lindberg F, Thuvander M (2011) Microstructures and hardness of as-quenched martensites (0.1–0.5%C). Acta Mater 59:5845–5858

    Article  CAS  Google Scholar 

  48. Cao J, Yong Q, Liu Q, Sun X (2007) Precipitation of MC phase and precipitation strengthening in hot rolled Nb–Mo and Nb–Ti steels. J of Mater Sci 42(24):10080–10084

    Article  CAS  Google Scholar 

  49. Zhou Q, Qian LH, Meng JY, Zhao LJ, Zhang FC (2015) Low-cycle fatigue behavior and microstructural evolution in a low-carbon carbide-free bainitic steel. Mater Des 85:487–496

    Article  CAS  Google Scholar 

  50. Navarro-López A, Hidalgo J, Sietsma J, Santofimia MJ (2020) Unravelling the mechanical behaviour of advanced multiphase steels isothermally obtained below Ms. Mater Des 188:108484

    Article  Google Scholar 

  51. Bhadeshia HKDH (2015) Bainite in steels: theory and practice, Third Edition. pp 92–94, University of Cambridge

  52. Gao G, Zhang H, Gui X, Luo P, Tan Z, Bai B (2014) Enhanced ductility and toughness in an ultrahigh-strength Mn-Si-Cr-C steel: the great potential of ultrafine filmy retained austenite. Acta Mater 76:425–433

    Article  CAS  Google Scholar 

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Acknowledgements

This work was funded by the National Natural Science Foundation of China (No. 51471147) and Innovation Ability Promotion Program of Hebei (22567609H).

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XS and TW were involved in conceptualization; YW and GS helped in methodology; XS contributed to formal analysis; XS and YW were involved in investigation; TW helped in resources; XS and DS contributed to data curation; XS and DS were involved in writing—original draft preparation; XS and DS were involved in writing—review and editing; XS and YH helped in visualization; TW contributed to supervision; TW helped in funding support.

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Correspondence to Tiansheng Wang.

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Sun, X., Sun, D., Wang, Y. et al. Microstructure analysis and quantitative strengthening evaluation of medium carbon bainitic multiphase steel. J Mater Sci 57, 17462–17480 (2022). https://doi.org/10.1007/s10853-022-07712-9

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