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Tuning of upper critical field in a vanadium-based A15 superconductor by the compositionally-complex-alloy concept

Journal of Materials Science volume 57, pages 15990–15998 (2022)Cite this article

Abstract

Compositionally complex alloys (CCAs) are a new category of multi-principal-element materials, which are closely related to high-entropy alloys, but contain more than two phases in an alloy sample. We applied the concept of CCA to a A15-type compound superconductor V3X by aiming to occupy the X site by a mixture of Al, Si, Ga, Ge and Sn. The V3X sample showed bulk superconductivity with a transition temperature Tc of 6.3 K, which is close to the Tc of V3Ge. The upper critical field Bc2(0) of V3X estimated from magnetic susceptibility is 8.8 T, which is ~ 50% higher than that of V3Ge (Bc2(0) = 5.8 T). Using synchrotron X-ray diffraction, the presence of at least five different A15 phases were revealed, which could not be understood by simple phase separation into V3Al, V3Si, V3Ga, V3Ge, and V3Sn. We consider that the CCA states in V3X resulted in the improvement of Bc2. The CCA concept would be useful for improvement of superconducting properties of practical superconductors.

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Acknowledgements

The authors thank O. Miura, Md. R. Kasem, and T. D. Matsuda for their support in experiments. This work was partly supported by Grant-in-Aid for Scientific Research (KAKENHI) [Nos.: 18KK0076, 21H00151, 21K18834]; and Tokyo Metropolitan Government Advanced Research [H31-1].

Funding

Grant-in-Aid for Scientific Research (KAKENHI), 18KK0076, Yoshikazu Mizuguchi, 21H00151, Yoshikazu Mizuguchi, 21K18834, Yoshikazu Mizuguchi, Tokyo Metropolitan Government Advanced Research, H31-1, Yoshikazu Mizuguchi

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Authors and Affiliations

  1. Department of Physics, Tokyo Metropolitan University, 1-1, Minami-osawa, Hachioji, 192-0397, Japan

    Yuki Nakahira, Ryosuke Kiyama, Aichi Yamashita, Yosuke Goto & Yoshikazu Mizuguchi

  2. Quantum Beam Science Research Directorate, National Institutes for Quantum Science and Technology, 1-1-1, Kouto, Sayo-cho, Sayo-gun, Hyogo, 679-5148, Japan

    Yuki Nakahira

  3. Faculty of Engineering, Hokkaido University, Kita 13 Nishi 8, Sapporo, 060-8628, Japan

    Hiroaki Itou & Akira Miura

  4. Graduate School of Advanced Science and Engineering, Hiroshima University, 1-3-1, Kagamiyama, Higashihiroshima, Hiroshima, 739-8526, Japan

    Chikako Moriyoshi

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  1. Yuki Nakahira
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Contributions

YN, AY, and YM: conception and experimental design; All the authors: carrying out measurements; YN and YM: manuscript composition.

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Correspondence to Yuki Nakahira.

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Nakahira, Y., Kiyama, R., Yamashita, A. et al. Tuning of upper critical field in a vanadium-based A15 superconductor by the compositionally-complex-alloy concept. J Mater Sci 57, 15990–15998 (2022). https://doi.org/10.1007/s10853-022-07607-9

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