Abstract
Colored textiles with thermal management capabilities have attracted increasing attention for satisfying aesthetics, comfort, and energy saving demands. In this work, we report a universal approach based on physical vapor deposition of TiO2/SiO2/Si (cool) and Ag/Si (warm) nanophotonic structures, which enables various types of textiles with similar color but different thermal management capabilities. By controlling the thickness of the Si layer in the cool and warm nanophotonic structures, cool and or warm nylon textiles with different colors, such as yellow, orange, pink, purplish red, violet grey, indigo and grey, were obtained. Compared with IR-opaque conventional blank nylon, the temperature of artificial skin increased by 10.2 °C/1.7 °C and 2.4 °C/0 °C under mid-day sunlight exposure/indoor conditions, respectively, for similar rose-brown warm and cool nanophotonic-structured nylon textiles; compared with IR-transparent blank nanoporous polyethylene (nanoPE) textiles, the temperature of artificial skin increased by 19.8 °C/3.6 °C and 4.1°C/0 °C under mid-day sunlight exposure/indoor conditions, respectively, for similar pink warm and cool nanophotonic-structured nanoPE textiles. Moreover, the developed nanophotonic structures and materials used here endowed the textile with excellent anti-UV and antibacterial properties. This work provides a green strategy for dye-free coloring, thermal management, and textile multifunctionalization.
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Hu R, Liu Y, Shin S et al (2020) Emerging materials and strategies for personal thermal management. Adv Energy Mater 10:1903921. https://doi.org/10.1002/aenm.201903921
Yue X, Zhang T, Yang D et al (2019) Multifunctional Janus fibrous hybrid membranes with sandwich structure for on-demand personal thermal management. Nano Energy 63:103808. https://doi.org/10.1016/j.nanoen.2019.06.004
Wang QW, Bin ZH, Liu J et al (2019) Multifunctional and water-resistant mxene-decorated polyester textiles with outstanding electromagnetic interference shielding and joule heating performances. Adv Funct Mater 29:1806819. https://doi.org/10.1002/adfm.201806819
Liu Q, Huang J, Zhang J et al (2018) Thermal, waterproof, breathable, and antibacterial cloth with a nanoporous structure. ACS Appl Mater Interfaces 10:2026–2032. https://doi.org/10.1021/acsami.7b16422
Hazarika A, Deka BK, Jeong C et al (2019) Biomechanical energy-harvesting wearable textile-based personal thermal management device containing epitaxially grown aligned Ag-tipped-NixCo1−xSe nanowires/reduced graphene oxide. Adv Funct Mater 29:1903144. https://doi.org/10.1002/adfm.201903144
Gao T, Yang Z, Chen C et al (2017) Three-dimensional printed thermal regulation textiles. ACS Nano 11:11513–11520. https://doi.org/10.1021/acsnano.7b06295
Peng Y, Cui Y (2020) Advanced textiles for personal thermal management and energy. Joule 4:724–742. https://doi.org/10.1016/j.joule.2020.02.011
Steketee J (1973) Spectral emissivity of skin and pericardium. Phys Med Biol 18:686–694. https://doi.org/10.1088/0031-9155/18/5/307
Hardy JD, DuBois EF (1937) Regulation of heat loss from the human body. Proc Natl Acad Sci 23:624–631. https://doi.org/10.1073/pnas.23.12.624
Song YN, Li Y, Yan DX et al (2020) Novel passive cooling composite textile for both outdoor and indoor personal thermal management. Compos Part A Appl Sci Manuf 130:105738. https://doi.org/10.1016/j.compositesa.2019.105738
Belliveau RG, DeJong SA, Boltin ND et al (2020) Mid-infrared emissivity of nylon, cotton, acrylic, and polyester fabrics as a function of moisture content. Text Res J 90:1431–1445. https://doi.org/10.1177/0040517519888825
Hsu PC, Song AY, Catrysse PB et al (2016) Radiative human body cooling by nanoporous polyethylene textile. Science 353:1019–1023. https://doi.org/10.1126/science.aaf5471
Peng Y, Chen J, Song AY et al (2018) Nanoporous polyethylene microfibres for large-scale radiative cooling fabric. Nat Sustain 1:105–112. https://doi.org/10.1038/s41893-018-0023-2
Cai L, Song AY, Li W et al (2018) Spectrally selective nanocomposite textile for outdoor personal cooling. Adv Mater 30:1802152. https://doi.org/10.1002/adma.201802152
Cai L, Song AY, Wu P et al (2017) Warming up human body by nanoporous metallized polyethylene textile. Nat Commun 8:496. https://doi.org/10.1038/s41467-017-00614-4
Luo H, Zhu Y, Xu Z et al (2021) Outdoor personal thermal management with simultaneous electricity generation. Nano Lett 21:3879–3886. https://doi.org/10.1021/acs.nanolett.1c00400
Cai L, Peng Y, Xu J et al (2019) Temperature regulation in colored infrared-transparent polyethylene textiles. Joule 3:1478–1486. https://doi.org/10.1016/j.joule.2019.03.015
Luo H, Li Q, Du K et al (2019) An ultra-thin colored textile with simultaneous solar and passive heating abilities. Nano Energy 65:103998. https://doi.org/10.1016/j.nanoen.2019.103998
Gita S, Hussan A, Choudhury TG (2017) Impact of textile dyes waste on aquatic environments and its treatment. Environ Ecol 35:2349–2353
Kishor R, Purchase D, Saratale GD et al (2021) Ecotoxicological and health concerns of persistent coloring pollutants of textile industry wastewater and treatment approaches for environmental safety. J Environ Chem Eng 9:105012. https://doi.org/10.1016/j.jece.2020.105012
Matsuoka M (1990) Infrared absorbing dyes, 1st edn. Springer, US, New York
Lee J, Kang MH, Lee KB, Lee Y (2013) Characterization of natural dyes and traditional korean silk fabric by surface analytical techniques. Materials 6:2007–2025. https://doi.org/10.3390/ma6052007
Swann S (1988) Magnetron sputtering. Phys Technol 19:67–75. https://doi.org/10.1088/0305-4624/19/2/304
Jiang S, Miao D, Yang G et al (2015) Fabrication of Ag thin film on polyester fabric by roll to roll magnetron sputtering system. J Mater Sci Mater Electron 26:3364–3369. https://doi.org/10.1007/s10854-015-2841-6
Depla D, Segers S, Leroy W et al (2011) Smart textiles: an explorative study of the use of magnetron sputter deposition. Text Res J 81:1808–1817. https://doi.org/10.1177/0040517511411966
Tan XQ, Liu JY, Niu JR et al (2018) Recent progress in magnetron sputtering technology used on fabrics. Materials 11:1953. https://doi.org/10.3390/ma11101953
Sun J, Bhushan B, Tong J (2013) Structural coloration in nature RSC Adv 3:14862–14889. https://doi.org/10.1039/c3ra41096j
Huang M, Lu SG, Ren Y et al (2020) Structural coloration and its application to textiles: a review. J Text Inst 111:756–764. https://doi.org/10.1080/00405000.2019.1663623
Yuan X, Xu W, Huang F et al (2017) Structural colors of fabric from Ag/TiO2 composite films prepared by magnetron sputtering deposition. Int J Cloth Sci Technol 29:427–435. https://doi.org/10.1108/IJCST-04-2016-0038
Yuan X, Ye Y, Lian M, Wei Q (2018) Structural coloration of polyester fabrics coated with Al/TiO2 composite films and their anti-ultraviolet properties. Materials 11:1011. https://doi.org/10.3390/ma11061011
Yuan X, Wei Q, Ke H et al (2019) Structural color and photocatalytic property of polyester fabrics coated with Ag/ZnO composite films. Int J Cloth Sci Technol 31:487–494. https://doi.org/10.1108/IJCST-09-2018-0112
Zhang X, Jiang S, Cai M et al (2020) Magnetron sputtering deposition of Ag/Ag2O bilayer films for highly efficient color generation on fabrics. Ceram Int 46:13342–13349. https://doi.org/10.1016/j.ceramint.2020.02.113
Huang ML, Cai Z, Wu YZ et al (2020) Metallic coloration on polyester fabric with sputtered copper and copper oxides films. Vacuum 178:109489. https://doi.org/10.1016/j.vacuum.2020.109489
Li W, Shi Y, Chen Z, Fan S (2018) Photonic thermal management of coloured objects. Nat Commun 9:4240. https://doi.org/10.1038/s41467-018-06535-0
Kats MA, Capasso F (2016) Optical absorbers based on strong interference in ultra-thin films. Laser Photonics Rev 10:735–749. https://doi.org/10.1002/lpor.201600098
Li Y, Zhou L, Zhang G et al (2017) Study on the effects of the characteristics of textile substrates on the photonic crystal films and the related structural colors. Surf Coat Technol 319:267–276. https://doi.org/10.1016/j.surfcoat.2017.04.017
Bennett HE, Porteus JO (1961) Relation between surface roughness and specular reflectance at normal incidence. J Opt Soc Am 51:123–129. https://doi.org/10.1364/josa.51.000123
AATCC Test Method 183–2010 Transmittance or blocking of erythemally weighted ultraviolet radiation through fabrics (2010). AATCC Tech Man 317–320
AS/NZS 4399:1996 Sun protective clothing–Evaluation and classification. Australian/New Zealand Standard
Müller J, Rech B, Springer J, Vanecek M (2004) TCO and light trapping in silicon thin film solar cells. Sol Energy 77:917–930. https://doi.org/10.1016/j.solener.2004.03.015
Alizadehgiashi M, Nemr CR, Chekini M et al (2021) Multifunctional 3D-printed wound dressings. ACS Nano 15:12375–12387. https://doi.org/10.1021/acsnano.1c04499
Le Ouay B, Stellacci F (2015) Antibacterial activity of silver nanoparticles: a surface science insight. Nano Today 10:339–354. https://doi.org/10.1016/j.nantod.2015.04.002
Shaheen TI, Salem SS, Zaghloul S (2019) A new facile strategy for multifunctional textiles development through in situ deposition of SiO2/TiO2 nanosols hybrid. Ind Eng Chem Res 58:20203–20212. https://doi.org/10.1021/acs.iecr.9b04655
Dhineshbabu NR, Arunmetha S, Manivasakan P et al (2016) Enhanced functional properties of cotton fabrics using TiO2/SiO2 nanocomposites. J Ind Text 45:674–692. https://doi.org/10.1177/1528083714538684
Acknowledgements
This work was supported by the National Science Foundation of China (Nos. 61774160 and 61875209), Natural Science Foundation of Zhejiang Province (No. LY19F040003), Ningbo Key Laboratory of Silicon and Organic Thin Film Optoelectronic Technologies.
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Hu, Q., Huang, J., Wang, J. et al. A universal green coating strategy on textiles for simultaneous color and thermal management. J Mater Sci 57, 11477–11490 (2022). https://doi.org/10.1007/s10853-022-07286-6
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DOI: https://doi.org/10.1007/s10853-022-07286-6


