Skip to main content

Advertisement

Log in

Aluminum matrix composites reinforced with multi-walled carbon nanotubes and C60 manufactured by laser powder bed fusion

  • Innovation in Materials Processing
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Carbon nano-materials are widely used as reinforcing materials for aluminum-based composites due to their excellent metallurgical properties. This study presents an approach for manufacturing Al/C composites utilizing a high energy ball milling and laser powder bed fusion (LPBF) process. We prepared Al/C60 and Al/MWCNT composites under 25 different conditions to observe their microstructure and mechanical property trends according to laser power and scan speed. The relative density of LPBFed composites increased as the energy density increased due to the oxide layer present on the aluminum surface and the high laser reflectance. It was found that, as the energy density increased, the increase in nanohardness and elastic modulus of the LPBFed composites was due to the high relative density. However, the high laser power condition of 179 W resulted in the softening of materials due to grain coarsening, resulting in a decrease in nanohardness and elastic modulus. Under the same laser conditions, the nanohardness of the LPBFed Al/2 vol.% MWCNT composites was approximately 0.5 GPa higher than that of the LPBFed Al/1 vol.% C60 composites, which is explained by the high relative density and grain refinement strengthening.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Figure 1
Figure 2
Figure 3
Figure 4
Fig. 5
Figure 6
Figure 7
Figure 8
Figure 9
Figure 10

Similar content being viewed by others

References

  1. Acharya R, Sharon JA, Staroselsky A (2017) Prediction of microstructure in laser powder bed fusion process. Acta Mater 124:360–371

    Article  CAS  Google Scholar 

  2. Edwards P, Ramulu M (2014) Fatigue performance evaluation of selective laser melted Ti–6Al–4V. Mater Sci Eng A 598:327–337

    Article  CAS  Google Scholar 

  3. Hilal H, Lancaster R, Jeffs S, Boswell J, Stapleton D, Baxter G (2019) The influence of process parameters and build orientation on the creep behaviour of a laser powder bed fused Ni-based superalloy for aerospace applications. Materials 12(9):1390

    Article  CAS  Google Scholar 

  4. Levkulich N, Semiatin S, Gockel J, Middendorf J, DeWald A, Klingbeil N (2019) The effect of process parameters on residual stress evolution and distortion in the laser powder bed fusion of Ti–6Al–4V. Addit Manuf 28:475–484

    CAS  Google Scholar 

  5. Khorasani M, Gibson I, Ghasemi A, Brandt M, Leary M (2020) On the role of wet abrasive centrifugal barrel finishing on surface enhancement and material removal rate of LPBF stainless steel 316L. J Manuf Process 59:523–534

    Article  Google Scholar 

  6. Kempf A, Hilgenberg K (2020) Influence of sub-cell structure on the mechanical properties of AlSi10Mg manufactured by laser powder bed fusion. Mater Sci Eng A 776:138976

    Article  CAS  Google Scholar 

  7. Miles M, Nelson T, Decker B (2004) Formability and strength of friction-stir-welded aluminum sheets. Metall and Mater Trans A 35(11):3461–3468

    Article  Google Scholar 

  8. Lai SW, Chung D (1994) Fabrication of particulate aluminium-matrix composites by liquid metal infiltration. J Mater Sci 29(12):3128–3150. https://doi.org/10.1186/s40712-014-0006-7

    Article  CAS  Google Scholar 

  9. Li Y, Gu D (2014) Parametric analysis of thermal behavior during selective laser melting additive manufacturing of aluminum alloy powder. Mater Des 63:856–867

    Article  CAS  Google Scholar 

  10. Yang KV, Rometsch P, Davies C, Huang A, Wu X (2018) Effect of heat treatment on the microstructure and anisotropy in mechanical properties of A357 alloy produced by selective laser melting. Mater Des 154:275–290

    Article  CAS  Google Scholar 

  11. Geng K, Yang Y, Li S, Misra R, Zhu Q (2019) A general strategy for enhancing 3D printability of high laser reflectivity pure aluminum powder. Metall Mater Trans A 50(11):4970–4976

    Article  CAS  Google Scholar 

  12. Garg P, Gupta P, Kumar D, Parkash O (2016) Structural and mechanical properties of graphene reinforced aluminum matrix composites. J Mater Environ Sci 7(5):1461–1473

    CAS  Google Scholar 

  13. Pérez-Bustamante R, Gómez-Esparza C, Estrada-Guel I, Miki-Yoshida M, Licea-Jiménez L, Pérez-García S, Martínez-Sánchez R (2009) Microstructural and mechanical characterization of Al–MWCNT composites produced by mechanical milling. Mater Sci Eng A 502(1):159–163

    Article  Google Scholar 

  14. Choi H, Shin J, Min B, Park J, Bae D (2009) Reinforcing effects of carbon nanotubes in structural aluminum matrix nanocomposites. J Mater Res 24(08):2610–2616

    Article  CAS  Google Scholar 

  15. Shin SE, Bae DH (2013) Strengthening behavior of chopped multi-walled carbon nanotube reinforced aluminum matrix composites. Mater Charact 83:170–177

    Article  CAS  Google Scholar 

  16. Aboulkhair NT, Simonelli M, Salama E, Rance GA, Neate NC, Tuck CJ, Esawi AM, Hague RJ (2019) Evolution of carbon nanotubes and their metallurgical reactions in Al-based composites in response to laser irradiation during selective laser melting. Mater Sci Eng A 765:138307

    Article  CAS  Google Scholar 

  17. Komatsu K, Murata M, Murata Y (2005) Encapsulation of molecular hydrogen in fullerene C60 by organic synthesis. Science 307(5707):238–240

    Article  CAS  Google Scholar 

  18. Choi H, Shin J, Bae D (2010) Self-assembled network structures in Al/C 60 composites. Carbon 48(13):3700–3707

    Article  CAS  Google Scholar 

  19. Tokunaga T, Kaneko K, Sato K, Horita Z (2008) Microstructure and mechanical properties of aluminum–fullerene composite fabricated by high pressure torsion. Scr Mater 58(9):735–738

    Article  CAS  Google Scholar 

  20. Hernández FR, Calderon H (2012) Nanostructured Al/Al4C3 composites reinforced with graphite or fullerene and manufactured by mechanical milling and spark plasma sintering. Mater Chem Phys 132(2–3):815–822

    Article  Google Scholar 

  21. Kwangmin C, Jiyeon S, Donghyun B, Hyunjoo C (2014) Mechanical properties of aluminum-based nanocomposite reinforced with fullerenes. Trans Nonferrous Metal Soc China 24:s47–s52

    Article  Google Scholar 

  22. Yunusov F, Bobrynina E, Ma T, Larionova T, Okrepilov M, Mazin V, Kravchenko S, Yakovlev V, Chulkin S, Zaripova D (2019) Aluminum-based composite reinforced with fullerene soot. IOP Conf Ser Earth Environ Sci 337:012085

    Article  Google Scholar 

  23. Ion J (2005) Laser processing of engineering materials: principles, procedure and industrial application. Elsevier

    Google Scholar 

  24. Geng K, Li S, Yang Y, Misra R (2020) 3D printing of Al matrix composites through in situ impregnation of carbon nanotubes on Al powder. Carbon 162:465–474

    Article  CAS  Google Scholar 

  25. Poirier D, Gauvin R, Drew RA (2009) Structural characterization of a mechanically milled carbon nanotube/aluminum mixture. Compos A Appl Sci Manuf 40(9):1482–1489

    Article  Google Scholar 

  26. Yan L, Tan Z, Ji G, Li Z, Fan G, Schryvers D, Shan A, Zhang D (2016) A quantitative method to characterize the Al4C3-formed interfacial reaction: the case study of MWCNT/Al composites. Mater Charact 112:213–218

    Article  CAS  Google Scholar 

  27. Lee ER, Shin SE, Takata N, Kobashi M, Kato M (2020) Manufacturing aluminum/multiwalled carbon nanotube composites via laser powder bed fusion. Materials 13(18):3927

    Article  CAS  Google Scholar 

  28. Aboulkhair NT (2012) Strength and ductility of bulk nanostructured aluminum processed by mechanical milling. Department of Mechanical Engineering, The American University in Cairo, AUC DAR Repository

  29. Aboulkhair NT, Esawi AM (2012) Effect of milling time and annealing on the mechanical response of mechanically milled aluminium. Adv Mater Res 445:815–820

    Article  CAS  Google Scholar 

  30. Xi L, Guo S, Gu D, Guo M, Lin K (2020) Microstructure development, tribological property and underlying mechanism of laser additive manufactured submicro-TiB2 reinforced Al-based composites. J Alloys Compd 819:152980

    Article  CAS  Google Scholar 

  31. Easton M, StJohn D (2005) An analysis of the relationship between grain size, solute content, and the potency and number density of nucleant particles. Metall Mater Trans A 36(7):1911–1920

    Article  Google Scholar 

  32. Aboulkhair NT (2016) Additive manufacture of an aluminium alloy: processing, microstructure, and mechanical properties. PhD Thesis, University of Nottingham

  33. Haboudou A, Peyre P, Vannes A, Peix G (2003) Reduction of porosity content generated during Nd: YAG laser welding of A356 and AA5083 aluminium alloys. Mater Sci Eng A 363(1–2):40–52

    Article  Google Scholar 

  34. Zhang B, Li Y, Bai Q (2017) Defect formation mechanisms in selective laser melting: a review. Chin J Mech Eng 30(3):515–527

    Article  Google Scholar 

  35. Xiao R, Zhang X (2014) Problems and issues in laser beam welding of aluminum–lithium alloys. J Manuf Process 16(2):166–175

    Article  Google Scholar 

  36. Louvis E, Fox P, Sutcliffe CJ (2011) Selective laser melting of aluminium components. J Mater Process Technol 211(2):275–284

    Article  CAS  Google Scholar 

  37. Phuong DD, Van Trinh P, Van An N, Van Luan N, Minh PN, Khisamov RK, Nazarov AA (2014) Effects of carbon nanotube content and annealing temperature on the hardness of CNT reinforced aluminum nanocomposites processed by the high pressure torsion technique. J Alloys Compd 613:68–73

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (No. 2021R1I1A3050323) and the “Competency Development Program for Industry Specialists” of the Korean Ministry of Trade, Industry and Energy (MOTIE), operated by the Korea Institute for Advancement of Technology (KIAT) (No. P0002019, HRD Program for High Value-Added Metallic Material Expert).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Se-Eun Shin.

Additional information

Handling Editor: M. Grant Norton.

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yoo, S., Shin, SE., Takata, N. et al. Aluminum matrix composites reinforced with multi-walled carbon nanotubes and C60 manufactured by laser powder bed fusion. J Mater Sci 57, 17984–17999 (2022). https://doi.org/10.1007/s10853-022-07119-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-022-07119-6

Navigation