Abstract
Magnetostrictive properties of CoMnSi are generally confined by their intrinsic brittleness and difficulty in growing into anisotropic bulk materials. In this study, we present a new type of 〈100〉-oriented CoMnSi microspheres/epoxy resin composite that exhibits a giant and reversible magnetostriction of 6700 ppm. 〈100〉-textured CoMnSi microspheres were synthesized through the non-wettability between CoMnSi liquid and solid dispersions. The microspheres/epoxy composites with a uniform 〈100〉 orientation were produced by applying a simulating rotating magnetic field. The improved magnetostriction in the composite was associated with microspheres' texture as well as their orientation. This work may shed light on the synthesis of textured metal spheres and the development of magnetic composite materials.
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References
Barcza A, Gercsi Z, Knight KS, Sandeman KG (2010) Giant magnetoelastic coupling in a metallic helical metamagnet. Phys Rev Lett 104:247202. https://doi.org/10.1103/PhysRevLett.104.247202
Barcza A, Gercsi Z, Michor H et al (2013) Magnetoelastic coupling and competing entropy changes in substituted CoMnSi metamagnets. Phys Rev B 87:064410. https://doi.org/10.1103/PhysRevB.87.064410
Gercsi Z, Sandeman KG (2010) Structurally driven metamagnetism in MnP and related Pnma compounds. Phys Rev B 81:224426. https://doi.org/10.1103/PhysRevB.81.224426
Niziol S, Bińczycka H, Szytula A et al (1978) Structure magnétique des MnCoSi. Phys Stat Solidi (a) 45:591–597. https://doi.org/10.1002/pssa.2210450231
Szytula A, Bazela W, Radenkovic S (1983) Crystal and magnetic-structure of the CoMn1-xTixSi system. J Magn Magn Mater 38:99–104. https://doi.org/10.1016/0304-8853(83)90108-7
Zhang CL, Shi HF, Nie YG et al (2019) Large reversible magnetostriction and improved mechanical properties in epoxy-reinforced MnCoSi1-xGex cast ingots. J Alloys Compd 784:16–21. https://doi.org/10.1016/j.jallcom.2019.01.004
Gong YY, Wang DH, Cao QQ et al (2015) Textured, dense and giant magnetostrictive alloy from fissile polycrystal. Acta Mater 98:113–118. https://doi.org/10.1016/j.actamat.2015.07.026
Hu QB, Hu Y, Zhang S et al (2018) Large reversible magnetostrictive effect of MnCoSi-based compounds prepared by high-magnetic-field solidification. Appl Phys Lett 112:052404. https://doi.org/10.1063/1.5011321
Zhang CL, Zheng YX, Xuan HC et al (2011) Large and highly reversible magnetic field-induced strains in textured Co1-xNixMnSi alloys at room temperature. J Phys D 44:135003. https://doi.org/10.1088/0022-3727/44/13/135003
Clark AE, Teter JP, Wunfogle M (1991) Anisotropy compensation and magnetostriction in TbxDy1-x(Fe1-yTy)1.9 (T=Co, Mn). J Appl Phys 69:5771–5773. https://doi.org/10.1063/1.347871
Sandlund L, Fahlander M, Cedell T, Clark AE, Restorff JB, Wunfogle M (1994) Magnetostriction, elastic-moduli, and coupling factors of composite Terfenol-D. J Appl Phys 75:5656–5658. https://doi.org/10.1063/1.355627
Meng H, Zhang TL, Jiang CB, Xu HB (2010) Grain-<111>-oriented anisotropy in the bonded giant magnetostrictive material. Appl Phys Lett 96:102501. https://doi.org/10.1063/1.3350891
Guruswamy S, Srisukhumbowornchai N, Clark AE, Restorff JB, Wun-Fogle M (2000) Strong, ductile, and low-field-magnetostrictive alloys based on Fe-Ga. Scr Mater 43:239–244. https://doi.org/10.1016/s1359-6462(00)00397-3
Gaitzsch U, Potschke M, Roth S, Rellinghaus B, Schultz L (2009) A 1% magnetostrain in polycrystalline 5M Ni-Mn-Ga. Acta Mater 57:365–370. https://doi.org/10.1016/j.actamat.2008.09.017
Lei CL, Huang HF, Cheng ZZ, Tang SL, Du YW (2016) Fabrication of spherical Fe-based magnetic powders via the in situ de-wetting of the liquid-solid interface. RSC Adv 6:3428–3432. https://doi.org/10.1039/c5ra22609k
Lei CL, Huang HF, Huang Y, Cheng ZZ, Tang SL, Du YW (2016) In-situ de-wetting assisted fabrication of spherical Cu-Sn alloy powder via the reduction of mixture metallic oxides. Powder Technol 301:356–359. https://doi.org/10.1016/j.powtec.2016.06.025
Cheng ZZ, Lei CL, Huang HF, Tang SL, Du YW (2016) The formation of ultrafine spherical metal powders using a low wettability strategy of solid-liquid interface. Mater Des 97:324–330. https://doi.org/10.1016/j.matdes.2016.02.100
Omori T, Kusama T, Kawata S et al (2013) Abnormal grain growth induced by cyclic heat treatment. Science 341:1500–1502. https://doi.org/10.1126/science.1238017
Omori T, Iwaizako H, Kainuma R (2016) Abnormal grain growth induced by cyclic heat treatment in Fe-Mn-Al-Ni superelastic alloy. Mater Des 101:263–269. https://doi.org/10.1016/j.matdes.2016.04.011
Kusama T, Omori T, Saito T et al (2017) Ultra-large single crystals by abnormal grain growth. Nat Commun 8:354. https://doi.org/10.1038/s41467-017-00383-0
Jin S, Huang M, Kwon Y et al (2018) Colossal grain growth yields single-crystal metal foils by contact-free annealing. Science 362:1021. https://doi.org/10.1126/science.aao3373
Huang Y, Qian J, Dong DS, Shi YG, Du YW, Tang SL (2022) Magnetostriction in <0kl>-oriented composites with CoMnSi microspheres. J Magn Magn Mater 543:168621. https://doi.org/10.1016/j.jmmm.2021.168621
Humphreys FJ, Hatherly M (2004) Recrystallization and related annealing phenomena, 2nd edn. Elsevier Ltd, Oxford
Xia J, Omori T, Kainuma R (2020) Abnormal grain growth in Fe-Mn-Al-Ni shape memory alloy with higher Al content. Scr Mater 187:355–359. https://doi.org/10.1016/j.scriptamat.2020.06.044
Clark AE, Abbundi R, Gillmor WR (1978) Magnetization and magnetic-anisotropy of TbFe2, DyFe2, Tb0.27Dy0.73Fe2 and TmFe2. IEEE Trans Magn 14:542–544. https://doi.org/10.1109/tmag.1978.1059879
Shi YG, Tang SL, Wang RL et al (2006) High-pressure synthesis of giant magnetostrictive PrxTb1-xFe1.9 alloys. Appl Phys Lett 89:202503. https://doi.org/10.1063/1.2387865
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The authors would like to thank the financial supports from the National Natural Science Foundation of China (Nos. 51671102 and 11475086).
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Funding was provided by National Natural Science Foundation of China (Grant Numbers 51671102 and 11475086).
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Huang, Y., Qian, J., Dong, D. et al. Giant and reversible magnetostriction in 〈100〉-oriented CoMnSi microspheres/epoxy resin composite. J Mater Sci 57, 6953–6962 (2022). https://doi.org/10.1007/s10853-022-07094-y
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DOI: https://doi.org/10.1007/s10853-022-07094-y