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Tuning anisotropic thermal conductivity of unidirectional carbon/carbon composites by incorporating carbonaceous fillers

Journal of Materials Science volume 55, pages 5079–5098 (2020)Cite this article

Abstract

Mesophase pitch-based large-diameter fibers were used to prepare unidirectional carbon/carbon (C/C) composite blocks, and mesophase pitch incorporated by various carbonaceous fillers was selected as a modified binder. The C/C composites were produced through a hot-pressing method, followed by carbonization and graphitization treatments. The influence of the carbonaceous fillers on the microstructure and physical properties of the C/C composites in different directions was investigated. The results show that both filler type and volume fraction have an important effect on the directional thermal conductivity of resulting composites. The through-thickness thermal conductivity of composites is significantly improved to be as high as 40–60 W/m K due to the incorporation of some carbonaceous dopants, which can tune their thermal conduction performance in different directions and thus solve the limitation of one-directional high thermal conduction. A three-dimensional carbon-based conductive network is diagramed to illustrate the thermal conduction mechanism of various carbon materials. The reinforcing effect on the directional thermal conductivity depends on the geometrical and physical characteristics, volume fractions and spatially distributed status of carbonaceous fillers. The flexural strengths of the composites are obviously improved owing to the decrease in porosity in the composites and the enhanced interfacial interaction between the carbon fibers and pitch-derived carbon matrix by doping with natural graphite flakes or carbon nanotubes.

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Acknowledgements

This work was sponsored by the National Natural Science Foundation of China (Grant Nos. 51372177, U1960106), the Key Laboratory of Hubei Province for Coal Conversion and New Carbon Materials (Grant No. WKDM201701) and the China Scholarship Council Fund (201808420114).

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Authors and Affiliations

  1. The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan, 430081, People’s Republic of China

    Guanming Yuan, Zhengwei Cui, Zhijun Dong, Ye Cong, Jiang Zhang & Xuanke Li

  2. Department of Chemical Engineering, Imperial College London, London, SW7 2AZ, UK

    Guanming Yuan & Xiangyi Long

  3. Guangzhou Iron and Steel Group Co., Ltd., Guangzhou, 510380, People’s Republic of China

    You Li

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  1. Guanming Yuan
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Yuan, G., Li, Y., Long, X. et al. Tuning anisotropic thermal conductivity of unidirectional carbon/carbon composites by incorporating carbonaceous fillers. J Mater Sci 55, 5079–5098 (2020). https://doi.org/10.1007/s10853-020-04357-4

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  • DOI: https://doi.org/10.1007/s10853-020-04357-4

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