Abstract
Al/graphite composites with small amounts of Al–Si alloy were consolidated by spark plasma sintering and hot-extrusion processes. The effect of Al–Si alloy addition on densification behavior, microstructure, thermal conductivity (TC), coefficient of thermal expansion (CTE), and compressive strength has been systematically investigated. The results showed that the addition of Al–Si alloy resulted in improvements in relative density of the composites, interfacial bonding between Al and graphite, and orientation degree of graphite. The composites with Al–Si alloy showed improved TC and reduced CTE values in comparison with those without Al–Si alloy. For example, the 450 °C-extruded Al/60 vol% graphite/9 vol% Al–Si composite showed a maximum TC of 297 W m−1 K−1 and a minimum CTE of 7.95 ppm K−1. Moreover, the hot-extruded Al/graphite composites containing Al–Si alloy exhibited higher compressive strength compared to conventional squeeze-cast composites and hot-extruded composites without Al–Si alloy.
Similar content being viewed by others
References
Zweben C (1998) Advances in composite materials for thermal management in electronic applications. JOM 50:47–51
Luedtke A (2004) Thermal management materials for high-performance applications. Adv Eng Mater 6:142–144
Mallik S, Ekere N, Best C, Bhatti R (2011) Investigation of thermal management materials for automotive electronic control units. Appl Therm Eng 31:355–362
Qu XH, Zhang L, Wu M, Ren SB (2011) Review of metal matrix composites with high thermal conductivity for thermal management applications. Prog Nat Sci: Mater Int 21:189–197
Mizuuchi K, Inoue K, Agari Y, Morisada Y, Sugioka M, Tanaka M, Takeuchi T, Tani JI, Kawahara M, Makino Y (2011) Processing of diamond particle dispersed aluminum matrix composites in continuous solid–liquid co-existent state by SPS and their thermal properties. Compos Part B: Eng 42:825–831
Liu TT, He XB, Liu Q, Ren SB, Kang QP, Zhang L, Qu XH (2014) Effect of chromium carbide coating on thermal properties of short graphite fiber/Al composites. J Mater Sci 49:6705–6715. https://doi.org/10.1007/s10853-014-8272-6
Li WJ, Liu Y, Wu GH (2015) Preparation of graphite flakes/Al with preferred orientation and high thermal conductivity by squeeze casting. Carbon 95:545–551
Zhou C, Huang W, Chen Z, Ji G, Wang ML, Chen D, Wang HW (2015) In-plane thermal enhancement behaviors of Al matrix composites with oriented graphite flake alignment. Compos Part B 70:256–262
Molina JM, Rodriguez-Guerrero A, Louis E, Rodriguez-Reinoso F, Narciso J (2017) Porosity effect on thermal properties of Al-12 wt% Si/graphite composites. Materials 10(2):177–187
Kurita H, Miyazaki T, Kawasaki A, Lu YF, Silvain JF (2015) Interfacial microstructure of graphite flake reinforced aluminum matrix composites fabricated via hot pressing. Compos Part A: Appl Sci Manuf 73:125–131
Chamroune N, Mereib D, Delange F, Caillault N, Lu YF, Grosseau-Poussard JL, Silvain JF (2018) Effect of flake powder metallurgy on thermal conductivity of graphite flakes reinforced aluminum matrix composites. J Mater Sci 53:8180–8192. https://doi.org/10.1007/s10853-018-2139-1
Bauccio M (1994) ASM engineered materials reference book, 2nd edn. ASM International, Materials Park, pp 181–182
Yi LF, Yoshida N, Onda T, Chen ZC (2019) Effect of processing conditions on microstructure and thermal conductivity of hot-extruded aluminum/graphite composites. Mater Trans 60(1):136–143
Lotgering FK (1959) Topotactical reactions with ferrimagnetic oxides having hexagon crystal structures—I. J Inorg Chem 9:113–123
Kim D (1992) Mechanical properties of pyrolytic graphite flakes. Carbon 30:729–737
Nan CW, Birringer R, Clarke DR, Gleiter H (1997) Effective thermal conductivity of particulate composites with interfacial thermal resistance. J Appl Phys 81(10):6692–6699
Nan CW, Li XP, Birringer R (2000) Inverse problem for composites with imperfect interface: determination of interfacial thermal resistance, thermal conductivity of constituents, and microstructural parameters. J Am Ceram Soc 83(4):848–854
Molina JM, Prieto R, Narciso J, Louis E (2009) The effect of porosity on the thermal conductivity of Al-12 wt% Si/SiC composites. Scr Mater 60(7):582–585
Swartz ET, Pohl RO (1989) Thermal boundary resistance. Rev Mod Phys 61(3):605–668
Tan ZQ, Li ZQ, Xiong DB, Fan GL, Ji G, Zhang D (2014) A predictive model for interfacial thermal conductance in surface metallized diamond aluminum matrix composites. Mater Des 55:257–262
Dewar B, Nicholas M, Scott PM (1976) The solid phase bonding of copper, nickel and some of their alloys to diamonds. J Mater Sci 11(6):1083–1090. https://doi.org/10.1007/BF00553116
Schmidt AJ, Collins KC, Minnich AJ, Chen G (2010) Thermal conductance and phonon transmissivity of metal–graphite interfaces. J Appl Phys 107(10):104907. https://doi.org/10.1063/1.3428464
Yuan GM, Li XK, Dong ZJ, Aidan W, Cui ZW, Ye C, Du HD, Kang FY (2012) Graphite blocks with preferred orientation and high thermal conductivity. Carbon 50(1):175–182
Murakami M, Nishiki N, Nakamura K, Ehara J, Okada H, Kouzaki T, Watanabe K, Hoshi T, Yoshimura S (1992) High quality and highly oriented graphite block from polycon-densation polymer films. Carbon 30(2):255–262
Kerner EH (1956) The elastic and thermos-electric properties of composite media. Proc Phys Soc 69(8):808–813
Acknowledgements
This work was supported in part by the Light Metal Educational Foundation. The authors would like to thank T. Yoshioka and T. Harada of Shimane Institute for Industrial Technology, Prof. S. Morito of Shimane University, and T. Murata of Tottori Institute of Industrial Technology for their experimental supports and fruitful discussion.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Yi, LF., Yoshida, N., Yamamoto, T. et al. Microstructure and thermal/mechanical properties of hot-extruded aluminum/graphite composites with Al–Si alloy addition. J Mater Sci 54, 9933–9944 (2019). https://doi.org/10.1007/s10853-019-03583-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-019-03583-9