Abstract
The localized surface plasmon resonance (LSPR) behavior of indium-doped ZnO (IZO) nanocrystals synthesized in different solvents was studied. 1-octadecanol, oleic acid, oleyl alcohol, oleyl amine and 1-octadecene were used as solvent(s) and co-solvent(s) in the pyrolysis synthesis of indium-doped ZnO (IZO) nanoparticles. The results showed that the nanocrystals from a solvent system consisting of 1-octadecene, 1-octadecanol, and oleic acid exhibited enhanced LSPR near-infrared radiation absorption without sacrificing transparency in the visible region. The indium-rich core verified using ICP and XPS analysis was shown to be critical for the enhancement. The reaction mechanism of solvents on the generation of indium-rich core was elucidated through a systematic study of the reaction parameters. The interaction between the activating agent, inhibiting agent and solvent, and their effect on tuning the reactivity of dopant and host precursors were important for the formation of a nanostructure with a dopant-rich core. The solvent effect was also found in the synthesis of gallium-doped ZnO and confirmed to be a general phenomenon in the preparation of doped ZnO nanoparticles.
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References
Hamberg I, Granqvist CG (1986) Evaporated Sn-doped In2O3 films: basic optical properties and applications to energy-efficient windows. J Appl Phys 60:R123–R160
Yang C, Chen JF, Zeng X, Cheng D, Cao D (2014) Design of the alkali-metal-doped WO3 as a near-infrared shielding material for smart window. Ind Eng Chem Res 53:17981–17988
Goodman AM, Cao Y, Urban C, Neumann O, Ayala-Orozco C, Knight MW, Joshi A, Nordlander P, Halas NJ (2014) The surprising in vivo instability of near-IR-absorbing hollow Au–Ag nanoshells. ACS Nano 8:3222–3231
Chen Y, Wu H, Li Z, Wang P, Yang L, Fang Y (2012) The study of surface plasmon in Au/Ag core/shell compound nanoparticles. Plasmonics 7:509–513
Gao C, Lu Z, Liu Y, Zhang Q, Chi M, Cheng Q, Yin Y (2012) Highly stable silver nanoplates for surface plasmon resonance biosensing. Angew Chem Int Ed 51:5629–5633
Lounis SD, Runnerstrom EL, Llordés A, Milliron DJ (2014) Defect chemistry and plasmon physics of colloidal metal oxide nanocrystals. J Phys Chem Lett 5:1564–1574
Comin A, Manna L (2014) New materials for tunable plasmonic colloidal nanocrystals. Chem Soc Rev 43:3957–3975
Liu X, Swihart MT (2014) Heavily-doped colloidal semiconductor and metal oxide nanocrystals: an emerging new class of plasmonic nanomaterials. Chem Soc Rev 43:3908–3920
Shalaev VM, Kawata S (2006) Nanophotonics with surface plasmons. Elsevier, New York City
Nico J, Fischer MJ, Mol NJ, Fischer MJ (2010) Surface plasmon resonance: methods and protocols
Kanehara M, Koike H, Yoshinaga T, Teranishi T (2009) Indium tin oxide nanoparticles with compositionally tunable surface plasmon resonance frequencies in the near-IR region. J Am Chem Soc 131:17736–17737
Garcia G, Buonsanti R, Runnerstrom EL, Mendelsberg RJ, Llordes A, Anders A, Richardson TJ, Milliron DJ (2011) Dynamically modulating the surface plasmon resonance of doped semiconductor nanocrystals. Nano Lett 11:4415–4420
Xu J, Li L, Wang S, Ding H, Zhang Y, Li G (2013) Influence of Sb doping on the structural and optical properties of tin oxide nanocrystals. CrystEngComm 15:3296–3300
Esro M, Georgakopoulos S, Lu H, Vourlias G, Krier A, Milne W, Gillin W, Adamopoulos G (2016) Solution processed SnO2: Sb transparent conductive oxide as an alternative to indium tin oxide for applications in organic light emitting diodes. J Mater Chem C 4:3563–3570
Gordon TR, Paik T, Klein DR, Naik GV, Caglayan H, Boltasseva A, Murray CB (2013) Shape-dependent plasmonic response and directed self-assembly in a new semiconductor building block, indium-doped cadmium oxide (ICO). Nano Lett 13:2857–2863
Wang F, Wang Q, Xu G, Hui R, Wu J (2013) Light trapping on plasmonic-photonic nanostructured fluorine-doped tin oxide. J Phys Chem C 117:11725–11730
Manthiram K, Alivisatos AP (2012) Tunable localized surface plasmon resonances in tungsten oxide nanocrystals. J Am Chem Soc 134:3995–3998
Ghosh S, Saha M, De SK (2014) Tunable surface plasmon resonance and enhanced electrical conductivity of In doped ZnO colloidal nanocrystals. Nanoscale 6:7039–7051
Liang X, Ren Y, Bai S, Zhang N, Dai X, Wang X, He H, Jin C, Ye Z, Chen Q (2014) Colloidal indium-doped zinc oxide nanocrystals with tunable work function: rational synthesis and optoelectronic applications. Chem Mater 26:5169–5178
Yibi Y, Chen JW, Xue J, Song JZ, Zeng HB (2017) Enhancement of adjustable localized surface plasmon resonance in ZnO nanocrystals via a dual doping approach. Sci Bull 62:693–699
Saha M, Ghosh S, Ashok VD, De S (2015) Carrier concentration dependent optical and electrical properties of Ga doped ZnO hexagonal nanocrystals. Phys Chem Chem Phys 17:16067–16079
Hamza M, Bluet JM, Masenelli-Varlot K, Canut B, Boisron O, Melinon P, Masenelli B (2015) Tunable mid IR plasmon in GZO nanocrystals. Nanoscale 7:12030–12037
Buonsanti R, Llordes A, Aloni S, Helms BA, Milliron DJ (2011) Tunable infrared absorption and visible transparency of colloidal aluminum-doped zinc oxide nanocrystals. Nano Lett 11:4706–4710
Della Gaspera E, Duffy NW, van Embden J, Waddington L, Bourgeois L, Jasieniak JJ, Chesman AS (2015) Plasmonic Ge-doped ZnO nanocrystals. Chem Commun 51:12369–12372
Park J, An K, Hwang Y, Park JG, Noh HJ, Kim JY, Park JH, Hwang NM, Hyeon T (2004) Ultra-large-scale syntheses of monodisperse nanocrystals. Nat Mater 3:891–895
Narayanaswamy A, Xu H, Pradhan N, Kim M, Peng X (2006) Formation of nearly monodisperse In2O3 nanodots and oriented-attached nanoflowers: hydrolysis and alcoholysis vs pyrolysis. J Am Chem Soc 128:10310–10319
Choi SH, Kim EG, Park J, An K, Lee N, Kim SC, Hyeon T (2005) Large-scale synthesis of hexagonal pyramid-shaped ZnO nanocrystals from thermolysis of Zn-oleate complex. J Phys. Chem. B 109:14792–14794
Song JZ, Kulinich SA, Li JH, Liu YL, Zeng HB (2015) A general one-pot strategy for the synthesis of high-performance transparent-conducting-oxide nanocrystal inks for all-solution-processed devices. Angew Chem 127:472–476
Luo SJ, Feng JY, Ng KM (2014) Large scale synthesis of nearly monodisperse, variable-shaped In2O3 nanocrystals via a one-pot pyrolysis reaction. CrystEngComm 16:9236–9244
Dou Q, Ng KM (2016) Synthesis of various metal stearates and the corresponding monodisperse metal oxide nanoparticles. Powder Technol 301:949–958
Luo SJ, Yang DN, Feng JY, Ng KM (2014) Synthesis and application of non-agglomerated ITO nanocrystals via pyrolysis of indium-tin stearate without using additional organic solvents. J Nanopart Res 16:2561
Bryan JD, Gamelin DR (2005) Doped semiconductor nanocrystals: synthesis, characterization, physical properties, and applications. Prog Inorg Chem 54:47–126
Norris DJ, Efros AL, Erwin SC (2008) Doped nanocrystals. Science 319:1776–1779
Jansons AW, Plummer LK, Hutchison JE (2017) Living nanocrystals. Chem Mater 29:5415–5425
Jansons AW, Koskela KM, Crockett BM, Hutchison JE (2017) Transition metal-doped metal oxide nanocrystals: efficient substitutional doping through a continuous growth process. Chem Mater 29:8167–8176
Crockett BM, Jansons AW, Koskela KM, Johnson DW, Hutchison JE (2017) Radial dopant placement for tuning plasmonic properties in metal oxide nanocrystals. ACS Nano 11:7719–7728
Jansons AW, Hutchison JE (2016) Continuous growth of metal oxide nanocrystals: enhanced control of nanocrystal size and radial dopant distribution. ACS Nano 10:6942–6951
Gu Y, Zhu ZF, Song JZ, Zeng HB (2017) Triangle-, tripod-, and tetrapod-branched ITO nanocrystals for anisotropic infrared plasmonics. Nanoscale 9:19374
Della Gaspera E, Chesman AS, van Embden J, Jasieniak JJ (2014) Non-injection synthesis of doped zinc oxide plasmonic nanocrystals. ACS Nano 8:9154–9163
Mendelsberg RJ, Garcia G, Milliron DJ (2012) Extracting reliable electronic properties from transmission spectra of indium tin oxide thin films and nanocrystal films by careful application of the Drude theory. J Appl Phys 111:063515
Mendelsberg RJ, Zhu Y, Anders A (2012) Determining the nonparabolicity factor of the CdO conduction band using indium doping and the Drude theory. J Phys D Appl Phys 45:425302
Pignataro B, Grasso G, Renna L, Marletta G (2002) Adhesion properties on nanometric scale of silicon oxide and silicon nitride surfaces modified by 1-octadecene. Surf Interface Anal 33:54–58
Schimpf AM, Ochsenbein ST, Buonsanti R, Milliron DJ, Gamelin DR (2012) Comparison of extra electrons in colloidal n-type Al3+-doped and photochemically reduced ZnO nanocrystals. Chem Commun 48:9352–9354
Buonsanti R, Milliron DJ (2013) Chemistry of doped colloidal nanocrystals. Chem Mater 25:1305–1317
Srivastava BB, Jana S, Karan NS, Paria S, Jana NR, Sarma D, Pradhan N (2010) Highly luminescent Mn-doped ZnS nanocrystals: gram-scale synthesis. J Phys Chem Lett 1:1454–1458
Yang Y, Jin Y, He H, Wang Q, Tu Y, Lu H, Ye Z (2010) Dopant-induced shape evolution of colloidal nanocrystals: the case of zinc oxide. J Am Chem Soc 132:13381–13394
Felde UZ, Maase M, Weller H (2000) Electrochromism of highly doped nanocrystalline SnO2: Sb. J Phys Chem B 104:9388–9395
Agrawal A, Cho SH, Zandi O, Ghosh S, Johns RW (2017) Localized surface plasmon resonance in semiconductor nanocrystals. Chem Rev 118:3121–3207
Boschloo G, Fitzmaurice D (1999) Spectroelectrochemistry of highly doped nanostructured tin dioxide electrodes. J Phys Chem B 103:3093–3098
Gassenbauer Y, Schafranek R, Klein A (2006) Surface states, surface potentials, and segregation at surfaces of tin-doped In2O3. Phys Rev 73:245312
Gassenbauer Y, Andreas K (2004) Electronic surface properties of rf-magnetron sputtered In2O3:Sn. Solid State Ionics 173:141–145
Fan JC, Goodenough JB (1977) X-ray photoemission spectroscopy studies of Sn-doped indium-oxide films. J Appl Phys 48:3524–3531
Boles MA, Ling D, Hyeon T, Talapin DV (2016) The surface science of nanocrystals. Nat Mater 15:141–153
Houtepen AJ, Hens Z, Owen JS, Infante I (2017) On the origin of surface traps in colloidal II–VI semiconductor nanocrystals. Chem Mater 29:752–761
Veamatahau A, Jiang B, Seifert T, Makuta S, Latham K, Kanehara M, Teranishi T, Tachibana Y (2015) Origin of surface trap states in CdS quantum dots: relationship between size dependent photoluminescence and sulfur vacancy trap states. Phys Chem Chem Phys 17:2850–2858
Greenberg BL, Ganguly S, Held JT, Kramer NJ, Mkhoyan KA, Aydil ES, Kortshagen UR (2015) Nonequilibrium-plasma-synthesized ZnO nanocrystals with plasmon resonance tunable via Al doping and quantum confinement. Nano Lett 15:8162–8169
Jang Y, Shapiro A, Isarov M, Rubin-Brusilovski A, Safran A, Budniak AK, Horani F, Dehnel J, Sashchiuk A, Lifshitz E (2017) Interface control of electronic and optical properties in IV–VI and II–VI core/shell colloidal quantum dots: a review. Chem Commun 53:1002–1024
Lounis SD, Runnerstrom EL, Bergerud A, Nordlund D, Milliron DJ (2014) Influence of dopant distribution on the plasmonic properties of indium tin oxide nanocrystals. J Am Chem Soc 136:7110–7116
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Dou, Q., Wong, K.W., Li, Y. et al. Influence of solvents on the plasmonic properties of indium-doped zinc oxide nanocrystals. J Mater Sci 53, 14456–14468 (2018). https://doi.org/10.1007/s10853-018-2624-6
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DOI: https://doi.org/10.1007/s10853-018-2624-6