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Journal of Materials Science

, Volume 53, Issue 17, pp 12065–12078 | Cite as

Visible-light responsive Cr(VI) reduction by carbonyl modification Nb3O7(OH) nanoaggregates

  • Tianning Wang
  • Jinshu Wang
  • Junshu Wu
  • Yucheng Du
  • Yongli Li
  • Hongyi Li
  • Yilong Yang
  • Xinjian Jia
Chemical routes to materials
  • 126 Downloads

Abstract

Nanostructured photocatalysts have become a subject of much interest, with most research focusing on the visible-light sensitization in order to effectively utilize incoming solar energy for environmental remediation. Herein, we design an acetic acid-assisted solvothermal strategy, enabling Nb3O7(OH) nanoaggregates with C=C and C=O functional groups on the surface and extending the absorption edge located at 550 nm approximately. The success extension of harvesting light from intrinsic UV region below 380 nm to visible region relies on effective surface modification by carbonyl groups originated from citric acid in acetic acid solution. Specifically, the unique C=O-rich surface state and advantageous structural features render them particularly attractive for Cr(VI) photoreduction applications with the assistance of hole scavenger tartaric acid. No phase or morphology transition occurs during Cr(VI) reduction. The reaction rate slows down and the photoresponse area turns back into intrinsic UV region of Nb3O7(OH) with the prolonging reaction time, originating from the exhaustion of surface C=O functional groups. This work is expected to help to elucidate the rational design and efficient synthesis of visible-light absorption catalyst materials for actual applications in the near future.

Notes

Acknowledgements

This study was funded by National Key R&D Program of China (2017YFB0310804), National Natural Science Foundation (51402008, 51534009, 51621003, 52621003, 51225402), Beijing Natural Science Foundation (2151001), Beijing Municipal Commission of Education Foundation (KZ201610005002), and Beijing municipal high-level innovative team building program (IDHT 20170502).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

10853_2018_2496_MOESM1_ESM.doc (18.4 mb)
Supplementary material 1 (DOC 18808 kb)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.School of Materials Science and EngineeringBeijing University of TechnologyChaoyang District, BeijingChina

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