Tailoring graphitic nanostructures in hard carbons as anode materials achieving efficient and ultrafast sodium storage

  • Yuxiang Chen
  • Jie Li
  • Yanqing Lai
  • Junming Li
  • Zhian Zhang
Energy materials
  • 13 Downloads

Abstract

Hard carbons appear to be promising anode candidates in high-performance sodium-ion batteries (SIBs) for large-scale stationary energy storage due to their large interlayer distance and amorphous structure, which facilitate sodium ions insertion/desertion. However, several major hurdles to address are poor rate performances and the low initial coulombic efficiency (ICE). Herein, a facile strategy to tailor hard carbons with graphitic nanostructures and rational specific surface area is proposed to improve sodium storage. Resin-derived carbon nanobroccolis (CNB) with in situ decorated graphitic nanostructures have been successfully synthesized by self-assembly and low-temperature catalytic carbonization process. As a result, attribute to in situ tailored graphitic nanostructures in hard carbons and rational specific surface area, CNB electrodes possess less charge transfer resistance and excellent sodium ions diffusion kinetics and successfully achieve fast and efficient sodium storage. When used as anode for sodium-ion batteries, CNB electrodes exhibit excellent high-rate capability of 137 mAh g−1 at 1000 mA g−1 and enhanced ICE of 52.6%. Our strategy reported here opens a door to design high-performance carbon anode materials for SIBs particularly focusing on efficient sodium ions storage and fast sodium ions diffusion.

Notes

Acknowledgements

The authors thank the financial support of the National Natural Science Foundation of China (Grant No. 51674297) and the Natural Science Foundation of Hunan Province (Grant No. 2016JJ2137). The authors thank the financial support of the Basic Research Program of Shenzhen, China (Grant No. JCYJ20170307140332076).

Compliance with ethical standards

Conflicts of interest

The authors declare no competing financial interest.

Supplementary material

10853_2018_2295_MOESM1_ESM.doc (1.5 mb)
Supplementary material 1 (DOC 1574 kb)

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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.School of Metallurgy and EnvironmentCentral South UniversityChangshaChina
  2. 2.Engineering Research Center of High Performance Battery Materials and DevicesResearch Institute of Central South University in ShenzhenShenzhenChina

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