CVD-grown three-dimensional sulfur-doped graphene as a binder-free electrocatalytic electrode for highly effective and stable hydrogen evolution reaction
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Three-dimensional sulfur-doped graphene (3DSG) with high sulfur-doping content (2.9%) was synthesized on nickel foam by chemical vapor deposition using solid organic source of thianthrene as both the carbon source and sulfur dopant. The 3DSG further treated by Ar plasma (3DSG-Ar) was demonstrated as a free-standing and binder-free electrocatalyst without any polymeric binders for electrode fabrication. Particularly, 3DSG-Ar can be used as highly effective and stable electrocatalyst for hydrogen evolution reaction (HER). It delivers a very low Tafel slope of 64 mV dec−1, which is superior or comparable to most metal-free carbon-based electrocatalysts ever reported; moreover, it shows superior long-term electrocatalytic stability even after 2000 cycles. The excellent HER performances of 3DSG-Ar can be attributed to its well-designed porous, conductive and flexible 3D sulfur-doped graphene structure. Sulfur doping combing with plasma treatment cause a synergistic effect to effectively provide many more electrocatalytic active sites, resulting in significantly improved HER performance. In addition, the conductive, porous and flexible 3D graphene skeleton can not only act as free-standing and binder-free electrocatalytic electrode, but also guarantee the interconnected conductive paths in the whole electrode, leading to facilitate the charge transportation between the electrocatalyst and electrolyte and thus enhance its HER performances.
The research was supported by the National Natural Science Foundation of China (Grant Nos. 21773024, 51372033) and National High Technology Research and Development Program of China (Grant No. 2015AA034202).
- 1.Fei H, Dong J, Arellano-Jimenez MJ, Ye G, Kim ND, Samuel ELG, Peng Z, Zhu Z, Qin F, Bao J, Yacaman MJ, Ajayan PM, Chen D, Tour JM (2015) Atomic cobalt on nitrogen-doped graphene for hydrogen generation. Nat Commun 6:9668–9676Google Scholar
- 24.Zheng B, Chen Y, Li P, Wang Z, Cao B, Qi F, Liu J, Qiu Z, Zhang W (2017) Ultrafast ammonia-driven, microwave-assisted synthesis of nitrogen-doped graphene quantum dots and their optical properties. Nanophotonics 6:259–267Google Scholar
- 33.Tian Y, Wei Z, Wang X, Peng S, Zhang X, Liu WM (2016) Plasma-etched, S-doped graphene for effective hydrogen evolution reaction. Int J Hydrogen Energy 7:4184–4192Google Scholar
- 49.Islam MM, Subramaniyam CM, Akhter T, Faisal SN, Minett AI, Liu HK, Konstantinov K, Dou SX (2017) Three dimensional cellular architecture of sulfur doped graphene: self-standing electrode for flexible supercapacitors, lithium ion and sodium ion batteries. J Mater Chem A 5:5290–5302CrossRefGoogle Scholar