Journal of Materials Science

, Volume 53, Issue 9, pp 6366–6377 | Cite as

Phase structure evolution and chemical durability studies of Gd1−xYb x PO4 ceramics for immobilization of minor actinides

  • Wenqi Li
  • Xingeng Ding
  • Cheng Meng
  • Chunrong Ren
  • Huating Wu
  • Hui Yang


Rare earth phosphates (REPO4) are considered as promising materials to immobilize the high-level radioactive waste. In the paper, Gd1−xYb x PO4 (x = 0, 0.1, 0.2, 0.4, 0.6, 0.8 and 1.0) series were prepared via the solid-state reaction using Gd as the surrogate for minor actinide Am and Cm, and the structure, phase transformation and morphology were characterized by XRD, Raman, TEM and SEM. With the calcination temperature ranging from 1200 to 1500 °C, the coexisted phases of monazite- and xenotime-type structure are observed in Gd0.9Yb0.1PO4. The monophasic xenotime-type Gd0.9Yb0.1PO4 is obtained at 1600 °C. The monazite → xenotime transformation of Gd1−xYb x PO4 depends on the substitution of Gd3+ by Yb3+ ions. With the decrease in Gd3+ content, the gradual changes of FWHM and the hypsochromic shift of P-O symmetrical stretching vibration (Vs) are observed in the Raman spectra, indicating that the distortion of PO4 tetrahedra occurs during the phase transformation process. The chemical durability test is measured by the ASTM product consistency test leaching method, and the normalized mass loss (NLGd) of Gd and (NLYb) of Yb is extremely low and shown in the order of 10−6–10−7 g/m2 for all the ceramics.



This project was supported by the National High-Tech Research and Development Program of China (863 Program) (No. 2015AA034701).

Supplementary material

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Supplementary material 1 (DOC 3274 kb)


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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Wenqi Li
    • 1
  • Xingeng Ding
    • 1
    • 2
  • Cheng Meng
    • 1
  • Chunrong Ren
    • 1
  • Huating Wu
    • 1
  • Hui Yang
    • 1
    • 2
  1. 1.School of Materials Science and EngineeringZhejiang UniversityHangzhouChina
  2. 2.Zhejiang California International Nano Systems InstituteHangzhouChina

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