Phase structure evolution and chemical durability studies of Gd1−xYb x PO4 ceramics for immobilization of minor actinides
- 109 Downloads
Rare earth phosphates (REPO4) are considered as promising materials to immobilize the high-level radioactive waste. In the paper, Gd1−xYb x PO4 (x = 0, 0.1, 0.2, 0.4, 0.6, 0.8 and 1.0) series were prepared via the solid-state reaction using Gd as the surrogate for minor actinide Am and Cm, and the structure, phase transformation and morphology were characterized by XRD, Raman, TEM and SEM. With the calcination temperature ranging from 1200 to 1500 °C, the coexisted phases of monazite- and xenotime-type structure are observed in Gd0.9Yb0.1PO4. The monophasic xenotime-type Gd0.9Yb0.1PO4 is obtained at 1600 °C. The monazite → xenotime transformation of Gd1−xYb x PO4 depends on the substitution of Gd3+ by Yb3+ ions. With the decrease in Gd3+ content, the gradual changes of FWHM and the hypsochromic shift of P-O symmetrical stretching vibration (Vs) are observed in the Raman spectra, indicating that the distortion of PO4 tetrahedra occurs during the phase transformation process. The chemical durability test is measured by the ASTM product consistency test leaching method, and the normalized mass loss (NLGd) of Gd and (NLYb) of Yb is extremely low and shown in the order of 10−6–10−7 g/m2 for all the ceramics.
This project was supported by the National High-Tech Research and Development Program of China (863 Program) (No. 2015AA034701).
- 27.ASTM (2014) Standard test methods for determining chemical durability of nuclear, hazardous, and mixed waste glasses and multiphase glass ceramics: the product consistency test (PCT). https://doi.org/10.1520/c1285-14
- 28.Meng C, Ding X, Zhao J et al (2016) Phase evolution and microstructural studies of Gd1−xYbxPO4 (0 ≤ x ≤ 1) ceramics for radioactive waste storage. J Eur Ceram Soc 36:773–779. https://doi.org/10.1016/j.jeurceramsoc.2015.10.045 CrossRefGoogle Scholar
- 46.Danelska A, Ulkowska U, Socha RP, Szafran M (2013) Surface properties of nanozirconia and their effect on its rheological behaviour and sinterability. J Eur Ceram Soc 33:1875–1883. https://doi.org/10.1016/j.jeurceramsoc.2013.01.019 CrossRefGoogle Scholar