Abstract
The influence of B-site deficiency on the stability of electrically induced long-range ferroelectric order of the stoichiometric Bi0.5+xNa0.5−xTi1−0.5x□0.5xO3 (BNT-xVTi) (“□” denotes vacancies) ceramics is studied. The depolarization and ferroelectric to relaxor transition are identified as separate and discrete processes in BNT-based materials. For BNT-0.02VTi, the resonance and anti-resonance peaks on dielectric permittivity-frequency curves indicate dominating ferroelectric phase at room temperature. The depolarization temperature, determined by thermally stimulated depolarization current, is ~ 65 °C. However, the ferroelectric to relaxor transition temperature is absent, as no distinct frequency-independent anomalies for the dielectric permittivity exist. This depolarization process can be ascribed to nanoscale ferroelectric domain at room temperature for BNT-0.02VTi, which is induced by chemical disorder and strong random field as VTi generated. Hence, the results imply that the B-site deficiency in BNT is a very effective route to tailor the stability of electrically induced long-range ferroelectric order.
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References
Liu W, Ren X (2009) Large piezoelectric effect in Pb-free ceramics. Phys Rev Lett 103:257602
Yuan R, Liu Z, Balachandran PV, Xue D, Zhou Y, Ding X, Sun J, Xue D, Lookman T (2018) Accelerated discovery of large electrostrains in BaTiO3-based piezoelectrics using active learning. Adv Mater 30:1702884
Kroutvar M, Ducommun Y, Heiss D, Bichler M, Schuh D, Abstreiter G, Finley JJ (2004) Optically programmable electron spin memory using semiconductor quantum dots. Nature 432:81–84
Li P, Zhai J, Shen B, Zhang S, Li X, Zhu F, Zhang X (2018) Ultrahigh piezoelectric properties in textured (K, Na)NbO3-based lead-free ceramics. Adv Mater 30:1705171
Yin J, Zhang Y, Lv X, Wu J (2018) Ultrahigh energy-storage potential under low electric field in bismuth sodium titanate-based perovskite ferroelectrics. J Mater Chem A 6:9823–9832
Zhang S-T, Kounga AB, Aulbach E, Ehrenberg H, Rödel J (2007) Giant strain in lead-free piezoceramics Bi0.5Na0.5TiO3–BaTiO3–K0.5Na0.5NbO3 system. Appl Phys Lett 91:112906
Liu X, Shi J, Zhu F, Du H, Li T, Liu X, Lu H (2018) Ultrahigh energy density and improved discharged efficiency in bismuth sodium titanate based relaxor ferroelectrics with A-site vacancy. J Materiomics 4:202–207
Liu X, Tan X (2016) Giant strains in non-textured (Bi1/2Na1/2)TiO3-based lead-free ceramics. Adv Mater 28:574–578
Hao J, Li W, Zhai J, Chen H (2018) Progress in high-strain perovskite piezoelectric ceramics. Mater Sci Eng R 135:1–57
Chen J, Wang Y, Zhang Y, Yang Y, Jin R (2017) Giant electric field-induced strain at room temperature in LiNbO3-doped 0.94(Bi0.5Na0.5)TiO3–0.06BaTiO3. J Eur Ceram Soc 37:2365–2371
Dinh TH, Kang J-K, Lee J-S, Khansur NH, Daniels J, Lee H-Y, Yao F-Z, Wang K, Li J-F, Han H-S, Jo W (2016) Nanoscale ferroelectric/relaxor composites: origin of large strain in lead-free Bi-based incipient piezoelectric ceramics. J Eur Ceram Soc 36:3401–3407
Schütz D, Deluca M, Krauss W, Feteira A, Jackson T, Reichmann K (2012) Lone-pair-induced covalency as the cause of temperature- and field-induced instabilities in bismuth sodium titanate. Adv Funct Mater 22:2285–2294
Zuo R, Li F, Fu J, Zheng D, Zhao W, Qi H (2016) Electric field forced c-axis oriented growth of polar nanoregions and rapid switching of tetragonal domains in BNT-PT-PMN ternary system. J Eur Ceram Soc 36:515–525
Dittmer R, Jo W, Rödel J, Kalinin S, Balke N (2012) Nanoscale insight into lead-free BNT–BT–xKNN. Adv Funct Mater 22:4208–4215
Liu X, Xue S, Li F, Ma J, Zhai J, Shen B, Wang F, Zhao X, Yan H (2018) Giant electrostrain accompanying structural evolution in lead-free NBT-based piezoceramics. J Mater Chem C 6:814–822
Wu J, Xiao D, Zhu J (2015) Potassium-sodium niobate lead-free piezoelectric materials: past, present, and future of phase boundaries. Chem Rev 115:2559–2595
Chen J, Wang Y, Zhang Y, Yang Y, Jin R (2017) Giant electric field-induced strain at room temperature in LiNbO3-doped 0.94(Bi0.5Na0.5)TiO3–0.06BaTiO3. J Eur Ceram Soc 37:2365–2371
Anton E-M, Jo W, Damjanovic D, Rödel J (2011) Determination of depolarization temperature of (Bi1/2Na1/2)TiO3-based lead-free piezoceramics. J Appl Phys 110:094108
Liu X, Li F, Zhai J, Shen B, Li P, Zhang Y, Liu B (2018) Enhanced electrostrictive effects in nonstoichiometric 0.99Bi0.505(Na0.8K0.2)0.5–xTiO3–0.01SrTiO3 lead-free ceramics. Mater Res Bull 97:215–221
Zhang J, Pan Z, Guo FF, Liu WC, Ning H, Chen YB, Lu MH, Yang B, Chen J, Zhang ST, Xing X, Rödel J, Cao W, Chen YF (2015) Semiconductor/relaxor 0-3 type composites without thermal depolarization in Bi0.5Na0.5TiO3-based lead-free piezoceramics. Nat Commun 6:6615
Jo W, Daniels J, Damjanovic D, Kleemann W, Rödel J (2013) Two-stage processes of electrically induced-ferroelectric to relaxor transition in 0.94(Bi1/2Na1/2)TiO3–0.06BaTiO3. Appl Phys Lett 102:192903
Rao BN, Datta R, Chandrashekaran S, Mishra DK, Sathe V, Senyshyn A, Ranjan R (2012) Local structural disorder and its influence on the average global structure and polar properties in Na0.5Bi0.5TiO3. Phys Rev B 88:224103
Sapper E, Schaab S, Jo W, Granzow T, Rödel J (2012) Influence of electric fields on the depolarization temperature of Mn-doped (1−x)Bi1/2Na1/2TiO3–xBaTiO3. J Appl Phys 111:014105
Shi J, Fan H, Liu X, Li Q (2014) Giant strain response and structure evolution in (Bi0.5Na0.5)0.945−x(Bi0.2Sr0.7□0.1)xBa0.055TiO3 ceramics. J Alloys Compd 627:463–467
Shi J, Liu X, Tian W (2018) High energy-storage properties of Bi0.5Na0.5TiO3–BaTiO3–SrTi0.875Nb0.1O3 lead-free relaxor ferroelectrics. J Mater Sci Technol 34:2371–2374
Rao BN, Fitch A, Ranjan R (2013) Ferroelectric-ferroelectric phase coexistence in Na1/2Bi1/2TiO3. Phys Rev B 87:060102
Rao BN, Ranjan R (2012) Electric-field-driven monoclinic-to-rhombohedral transformation in Na1/2Bi1/2TiO3. Phys Rev B 86:134103
Guo H, Liu X, Rödel J, Tan X (2015) Nanofragmentation of ferroelectric domains during polarization fatigue. Adv Funct Mater 25:270–277
Acknowledgements
This work was supported by the National Natural Science Foundation (51702249, 51602252), the China Postdoctoral Science Foundation (2017M613065) and the Shaanxi Province Science Foundation (2017JQ5072).
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Shi, J., Liu, X. & Tian, W. Structure evolution and ferroelectric properties in stoichiometric Bi0.5+xNa0.5−xTi1−0.5xO3. J Mater Sci 54, 5249–5255 (2019). https://doi.org/10.1007/s10853-018-03262-1
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DOI: https://doi.org/10.1007/s10853-018-03262-1