Abstract
In the present work, a high-strength lightweight Al/Ti multilayered film was fabricated using a magnetron sputtering method, and its deformation behaviour was studied under nanoindentation. The Al and Ti layers were approximately 70 and 50 nm, respectively, in thickness, with the total film thickness of 2.4 μm. According to the measured hardness, the specific strength of the Al/Ti multilayer film was estimated at 245 kN m/kg, higher than most reported nanostructured metallic multilayer films. After nanoindentation, the deformation behaviour of each layer was examined in detail using SEM–FIB. It shows that the two materials exhibited co-deformation behaviour when the layers were thinned to approximately 30 nm. It was also found that the co-deformation behaviour of the Al/Ti multilayers resulted in cooperative-layer-induced shear bands under nanoindentation. Further, nanoscratch-induced deformation behaviour of the Al/Ti multilayers, such as layer buckling, was investigated.
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References
Misra A, Hirth J, Hoagland R (2005) Length-scale-dependent deformation mechanisms in incoherent metallic multilayered composites. Acta Mater 53:4817–4824
Armstrong RW, Chou YT, Fisher RM, Louat N (1966) The limiting grain size dependence of the strength of a polycrystalline aggregate. Philos Mag 14:943–951
Misra A, Hirth JP, Kung H (2002) Single-dislocation-based strengthening mechanisms in nanoscale metallic multilayers. Philos Mag A 82:2935–2951
Chen Y, Liu Y, Sun C, Yu K, Song M, Wang H, Zhang X (2012) Microstructure and strengthening mechanisms in Cu/Fe multilayers. Acta Mater 60:6312–6321
Zhu X, Liu X, Zong R, Zeng F, Pan F (2010) Microstructure and mechanical properties of nanoscale Cu/Ni multilayers. Mater Sci Eng, A 527:1243–1248
Callisti M, Polcar T (2017) Combined size and texture-dependent deformation and strengthening mechanisms in Zr/Nb nano-multilayers. Acta Mater 124:247–260
Li Y, Zhu X, Zhang G, Tan J, Wang W, Wu B (2010) Investigation of deformation instability of Au/Cu multilayers by indentation. Philos Mag 90:3049–3067
Zhou Q, Huang P, Liu M, Wang F, Xu K, Lu T (2017) Grain and interface boundaries governed strengthening mechanisms in metallic multilayers. J Alloy Compd 698:906–912
Li Y, Zhu X, Tan J, Wu B, Zhang G (2009) Two different types of shear-deformation behaviour in Au–Cu multilayers. Philos Mag Lett 89:66–74
Li Y, Tan J, Zhang G (2008) Interface instability within shear bands in nanoscale Au/Cu multilayers. Scr Mater 59:1226–1229
Zhang G, Liu Y, Wang W, Tan J (2006) Experimental evidence of plastic deformation instability in nanoscale Au/Cu multilayers. Appl Phys Lett 88:013105.1–013105.3
Yan J, Zhu X, Zhang G, Yan C (2013) Evaluation of plastic deformation ability of Cu/Ni/W metallic multilayers. Thin Solid Films 527:227–231
Phillips M, Clemens B, Nix W (2003) A model for dislocation behaviour during deformation of Al/Al3Sc (fcc/L12) metallic multilayers. Acta Mater 51:3157–3170
Li X, Kreuter T, Luo XM, Schwaiger R, Zhang GP (2017) Detecting co-deformation behavior of Cu–Au nanolayered composites. Mater Res Lett 5:20–28
Misra A, Hoagland RG (2007) Plastic flow stability of metallic nanolaminate composites. J Mater Sci 42(5):1765–1771. doi:10.1007/s10853-006-0895-9
Bhattacharyya D, Mara NA, Dickerson P, Hoagland RG, Misra A (2010) A transmission electron microscopy study of the deformation behavior underneath nanoindents in nanoscale Al–TiN multilayered composites. Philos Mag 90(13):1711–1724
Dang C, Li J, Wang Y, Yang Y, Wang Y, Chen J (2017) Influence of multi-interfacial structure on mechanical and tribological properties of TiSiN/Ag multilayer coatings. J Mater Sci 52(5):2511–2523. doi:10.1007/s10853-016-0545-9
Banerjee R, Ahuja R, Fraser HL (1996) Dimensionally induced structural transformations in titanium–aluminum multilayers. Phys Rev Lett 76(20):3778–3781
Bhattacharyya D, Mara NA, Dickerson P, Hoagland RG, Misra A (2011) Compressive flow behavior of Al–TiN multilayers at nanometer scale layer thickness. Acta Mater 59(10):3804–3816
Verma N, Jayaram V (2012) The influence of Zr layer thickness on contact deformation and fracture in a ZrN–Zr multilayer coating. J Mater Sci 47(4):1621–1630. doi:10.1007/s10853-011-6001-y
Liu Y, Chen Y, Yu KY, Wang H, Chen J, Zhang X (2013) Stacking fault and partial dislocation dominated strengthening mechanisms in highly textured Cu/Co multilayers. Int J Plast 49:152–163
Zhang JY, Liu Y, Chen J, Chen Y, Liu G, Zhang X, Sun J (2012) Mechanical properties of crystalline Cu/Zr and crystal-amorphous Cu/Cu–Zr multilayers. Mater Sci Eng, A 552:392–398
Ahuja R, Fraser HL (1994) Structure and mechanical properties of nanolaminated Ti–Al thin films. JOM 46(10):35–39
Banerjee R, Zhang XD, Dregia SA, Fraser HL (1999) Phase stability in Al/Ti multilayers. Acta Mater 47(4):1153–1161
Li N, Wang H, Misra A, Wang J (2014) In situ nanoindentation study of plastic co-deformation in Al–TiN nanocomposites. Sci Rep 4:6633.1–6633.5
Fu KK, Chang L, Zheng BL, Tang YH, Wang HJ (2015) On the determination of representative stress-strain relation of metallic materials using instrumented indentation. Mater Des 65:989–994
Oliver WC, Pharr GM (1992) An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments. J Mater Res 7:1564–1583
Zhou X, Jiang Z, Wang H, Yu R (2008) Investigation on methods for dealing with pile-up errors in evaluating the mechanical properties of thin metal films at sub-micron scale on hard substrates by nanoindentation technique. Mater Sci Eng, A 488:318–332
Korsunsky AM, McGurk MR, Bull SJ, Page TF (1998) On the hardness of coated systems. Surf Coat Technol 99:171–183
Jang JI, Lance MJ, Wen S, Tsui TY, Pharr GM (2005) Indentation-induced phase transformations in silicon: influences of load, rate and indenter angle on the transformation behavior. Acta Mater 53:1759–1770
Yang D, Cizek P, Hodgson P, Wen CE (2010) Ultrafine equiaxed-grain Ti/Al composite produced by accumulative roll bonding. Scr Mater 62:321–324
Misra A, Verdier M, Lu YC, Kung H, Mitchell TE, Nastasi M, Embury JD (1998) Structure and mechanical properties of Cu-X (X = Nb, Cr, Ni) nanolayered composites. Scr Mater 39:555–560
Li YP, Zhu XF, Tan J, Wu B, Wang W, Zhang GP (2009) Comparative investigation of strength and plastic instability in Cu/Au and Cu/Cr multilayers by indentation. J Mater Res 24:728–735
Baker SP, Nix WD (1994) Mechanical properties of compositionally modulated Au–Ni thin films: nanoindentation and microcantilever deflection experiments. J Mater Res 9:3131–3144
Ham B, Zhang X (2011) High strength Mg/Nb nanolayer composites. Mater Sci Eng, A 528:2028–2033
Wang D, Kups T, Schawohl J, Schaaf P (2012) Deformation behavior of Au/Ti multilayers under indentation. J Mater Sci: Mater Electron 23:1077–1082. doi:10.1007/s10854-011-0550-3
Li J, Chen Y, Xue S, Wang H, Zhang X (2016) Comparison of size dependent strengthening mechanisms in Ag/Fe and Ag/Ni multilayers. Acta Mater 114:154–163
McKeown J, Misra A, Kung H, Hoagland RG, Nastasi M (2002) Microstructures and strength of nanoscale Cu–Ag multilayers. Scr Mater 46:593–598
Bufford D, Bi Z, Jia Q, Wang H, Zhang X (2012) Nanotwins and stacking faults in high-strength epitaxial Ag/Al multilayer films. Appl Phys Lett 101:223112.1–223112.5
Fu EG, Li N, Misra A, Hoagland RG, Wang H, Zhang X (2008) Mechanical properties of sputtered Cu/V and Al/Nb multilayer films. Mater Sci Eng, A 493:283–287
Mara NA, Bhattacharyya D, Dickerson P, Hoagland RG, Misra A (2008) Deformability of ultrahigh strength 5 nm Cu/Nb nanolayered composites. Appl Phys Lett 92(23):231901.1–231901.3
Topić M, Favaro G, Bucher R (2011) Scratch resistance of platinum–vanadium single and multilayer systems. Surf Coat Technol 205(20):4784–4790
Papachristos V, Panagopoulos C, Christoffersen L, Markaki A (2001) Young’s modulus, hardness and scratch adhesion of Ni–P–W multilayered alloy coatings produced by pulse plating. Thin Solid Films 396(1):174–183
Huang JC, Lee JW, Li CL (2011) Nano-scratching and nano-machining in different environments on Cr2N/Cu multilayer thin films. Thin Solid Films 519(15):4992–4996
Shang H, Li J, Shao T (2014) Mechanical properties and thermal stability of TiAlN/Ta multilayer film deposited by ion beam assisted deposition. Appl Surf Sci 310:317–320
Roa J, Rico V, Oliva-Ramírez M, González-Elipe A, Jiménez-Piqué E (2016) Nanoindentation and scratch resistance of multilayered TiO2–SiO2 coatings with different nanocolumnar structures deposited by PV-OAD. J Phys D Appl Phys 49(13):135104.1–135104.7
Khlifi K, Dhiflaoui H, Zoghlami L, Larbi A (2015) Study of mechanical behaviour, deformation, and fracture of nano-multilayer coatings during microindentation and scratch test. J Coating Technol Res 12(3):513–524
Callisti M, Polcar T (2014) The role of Ni–Ti–(Cu) interlayers on the mechanical properties and nano-scratch behaviour of solid lubricant W–S–C coatings. Surf Coat Technol 254:260–269
Acknowledgement
This research was supported by funding from the Faculty of Engineering and Information Technologies, the University of Sydney, under the Faculty Research Cluster Program. The authors also acknowledge the scientific and technical input and support from the Australian Microscopy and Microanalysis Research Facility node at the University of Sydney.
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Fu, K., Chang, L., Yang, C. et al. Plastic behaviour of high-strength lightweight Al/Ti multilayered films. J Mater Sci 52, 13956–13965 (2017). https://doi.org/10.1007/s10853-017-1478-7
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DOI: https://doi.org/10.1007/s10853-017-1478-7