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Randomly oriented Ni–P/nanofiber/nanotube composite prepared by electrolessly plated nickel–phosphorus alloys for fuel cell applications

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Abstract

In this work, we have synthesized a new type of hybridized composites, Ni–P/CNT–CNFs, which refers to carbon nanotube (CNT)—hybridized carbon nanofibers (CNFs) through electrolessly plated nickel–phosphorus (Ni–P) alloys. The composites combine the merits of CNTs with high electronic conductivity and CNFs with abundant defect sites via the junction of electrolessly deposited Ni–P. The materials have been extensively characterized by scanning electron microscope, transmission electron microscopy, X-ray diffraction, Brunauer–Emmett–Teller (BET), thermogravimetric analysis and hydrophilicity analysis. Electrochemical evaluations for oxygen reduction reaction (ORR) are carried out in 0.1 M KOH with and without 1 M methanol. In addition to serving as desirable candidates as electrocatalyst supports, the randomly oriented hybridized composites show satisfactory activities to ORR and excellent methanol tolerance in alkaline solutions. This generalized method is applicable for the preparation of a broad range of composite materials with different active components simply by variations in electroless plating bath (for example, copper\cobalt or bimetallic plating).

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References

  1. Rabis A, Rodriguez P, Schmidt TJ (2012) Electrocatalysis for polymer electrolyte fuel cells: recent achievements and future challenges. ACS Catal 2:864–890

    Article  Google Scholar 

  2. Huang XQ, Zhao ZP, Cao L, Chen Y, Zhu EB, Lin ZT, Li MF, Yan AM, Zettl A, Wang YM, Duan XF, Mueller T, Huang Y (2015) High-performance transition metal-doped Pt3Ni octahedra for oxygen reduction reaction. Science 348:1230–1234

    Article  Google Scholar 

  3. Guo L, Jiang WJ, Zhang Y, Hu JS, Wei ZD, Wan LJ (2015) Embedding Pt nanocrystals in N-doped porous carbon/carbon nanotubes toward highly stable electrocatalysts for the oxygen reduction reaction. ACS Catal 5:2903–2909

    Article  Google Scholar 

  4. Piela B, Olson TS, Atanassov P, Zelenay P (2010) Highly methanol-tolerant non-precious metal cathode catalysts for direct methanol fuel cell. Electrochim Acta 55:7615–7621

    Article  Google Scholar 

  5. Cheng QQ, Wang YL, Jiang JJ, Zou Z, Zhou Y, Fang JH, Yang HJ (2015) Shape-controlled porous heterogeneous PtRu/C/Nafion microspheres enabling high performance direct methanol fuel cells. J Mater Chem A 3:15177–15183

    Article  Google Scholar 

  6. Fu G, Wu K, Lin J, Tang Y, Chen Y, Zhou Y, Lu T (2013) One-pot water-based synthesis of Pt–Pd alloy nanoflowers and their superior electrocatalytic activity for the oxygen reduction reaction and remarkable methanol-tolerant ability in acid media. J Phys Chem C 117:9826–9834

    Article  Google Scholar 

  7. Liao MY, Wang YL, Chen GQ, Zhou H, Li YH, Zhong CJ, Chen BH (2014) Reducing Pt use in the catalysts for formic acid electrooxidation via nanoengineered surface structure. J Power Sources 257:45–51

    Article  Google Scholar 

  8. Alia SM, Jensen KO, Pivovar BS, Yan Y (2012) Platinum-coated palladium nanotubes as oxygen reduction reaction electrocatalysts. ACS Catal 2:858–863

    Article  Google Scholar 

  9. Dang D, Zou HB, Xiong ZA, Hou SY, Shu T, Nan HX, Zeng XY, Zeng JH, Liao SJ (2015) High-Performance, ultralow platinum membrane electrode assembly fabricated by in situ deposition of a Pt shell layer on carbon-supported Pd nanoparticles in the catalyst layer using a facile pulse electrodeposition approach. ACS Catal 5:4318–4324

    Article  Google Scholar 

  10. Zheng YY, Zhan HT, Fang YX, Zeng JH, Liu H, Yang J, Liao SJ (2017) Uniformly dispersed carbon-supported bimetallic ruthenium–platinum electrocatalysts for the methanol oxidation reaction. J Mater Sci 52:3457–3466. doi:10.1007/s10853-016-0635-8

    Article  Google Scholar 

  11. Zhong GY, Wang HJ, Yu H, Peng F (2015) Nitrogen doped carbon nanotubes with encapsulated ferric carbide as excellent electrocatalyst for oxygen reduction reaction in acid and alkaline media. J Power Sources 286:495–503

    Article  Google Scholar 

  12. Yang LJ, Larouche N, Chenitz R, Zhang GX, Lefèvre M, Dodelet JP (2015) Activity, performance, and durability for the reduction of oxygen in PEM fuel cells, of Fe/N/C electrocatalysts obtained from the pyrolysis of metal-organic-framework and iron porphyrin precursors. Electrochim Acta 159:184–197

    Article  Google Scholar 

  13. Gu LZ, Jiang LH, Jin JJ, Liu J, Sun GQ (2015) Yolk–shell structured iron carbide/N-doped carbon composite as highly efficient and stable oxygen reduction reaction electrocatalyst. Carbon 82:572–578

    Article  Google Scholar 

  14. Kolla P, Lai CL, Mishra S, Fong H, Rhine W, Smirnova A (2014) CVD grown CNTs within iron modified and graphitized carbon aerogel as durable oxygen reduction catalysts in acidic medium. Carbon 79:518–528

    Article  Google Scholar 

  15. Wang CD, Jiang J, Zhou XL, Wang WL, Zuo J, Yang Q (2015) Alternative synthesis of cobalt monophosphide@C core–shell nanocables for electrochemical hydrogen production. J Power Sources 286:464–469

    Article  Google Scholar 

  16. Park JC, Park SH, Chung MW, Choi CH, Kho BK, Woo SI (2015) Optimization of catalyst layer composition for PEMFC using graphene-based oxygen reduction reaction catalysts. J Power Sources 286:166–174

    Article  Google Scholar 

  17. Zhang J, Wu SY, Chen X, Pan M, Mu SC (2014) Egg derived nitrogen-self-doped carbon/carbon nanotube hybrids as noble-metal-free catalysts for oxygen reduction. J Power Sources 271:522–529

    Article  Google Scholar 

  18. Liu HY, Zhu XF, Li MB, Tang QW, Sun GQ, Yang WS (2014) Single crystal (Mn, Co)3O4 octahedra for highly efficient oxygen reduction reactions. Electrochim Acta 144:31–41

    Article  Google Scholar 

  19. Yi QF, Zhang YH, Liu XP, Xiang BL, Yang YH (2014) Fe/Co/C–N nanocatalysts for oxygen reduction reaction synthesized by directly pyrolyzing Fe/Co-doped polyaniline. J Mater Sci 49:729–736. doi:10.1007/s10853-013-7754-2

    Article  Google Scholar 

  20. Huang JJ, Zhu NW, Yang TT, Zhang TP, Wu PX, Dang Z (2015) Nickel oxide and carbon nanotube composite (NiO/CNT) as a novel cathode non-precious metal catalyst in microbial fuel cells. Biosen Bioelectron 72:332–339

    Article  Google Scholar 

  21. Zhu JL, He GQ, Liang LZ, Wan Q, Shen PK (2015) Direct anchoring of platinum nanoparticles on nitrogen and phosphorus-dual-doped carbon nanotube arrays for oxygen reduction reaction. Electrochim Acta 158:374–382

    Article  Google Scholar 

  22. Song P, Bo XJ, Nsabimana A, Guo LP (2014) Additional doping of phosphorus into polypyrrole functionalized nitrogenous carbon nanotubes as novel metal-free oxygen reduction electrocatalyst in alkaline solution. Int J Hydrogen Energy 39:15464–15473

    Article  Google Scholar 

  23. Goubert R, Stephanie NS, Wieckowski A (2011) Ni and/or Co nanoparticles as catalysts for oxygen reduction reaction (ORR) at room temperature. J Electroanal Chem 652:44–51

    Article  Google Scholar 

  24. Ma YT, Li H, Wang H, Ji S, Linkov V, Wang RF (2014) Ultrafine amorphous PtNiP nanoparticles supported on carbon as efficiency electrocatalyst for oxygen reduction reaction. J Power Sources 259:87–91

    Article  Google Scholar 

  25. von Deak D, Biddinger EJ, Luthman KA, Ozkan US (2010) The effect of phosphorus in nitrogen-containing carbon nanostructures on oxygen reduction in PEM fuel cells. Carbon 48:3637–3639

    Article  Google Scholar 

  26. Savych I, Bernard d’Arbigny J, Subianto S, Cavaliere S, Jones DJ, Rozière J (2014) On the effect of non-carbon nanostructured supports on the stability of Pt nanoparticles during voltage cycling: a study of TiO2 nanofibres. J Power Sources 257:147–155

    Article  Google Scholar 

  27. Nakagawa N, Ito Y, Tsujiguchi T, Ishitobi H (2014) Improved reaction kinetics and selectivity by the TiO2-embedded carbon nanofiber support for electro-oxidation of ethanol on PtRu nanoparticles. J Power Sources 248:330–336

    Article  Google Scholar 

  28. Stamatin SN, Borghei M, Dhiman R, Andersen SM, Ruiz V, Kauppinen E, Skou EM (2015) Activity and stability studies of platinized multi-walled carbon nanotubes as fuel cell electrocatalysts. Appl Catal B Environ 162:289–299

    Article  Google Scholar 

  29. Gong J, Liu J, Jiang ZW, Feng JD, Chen XC, Wang L, Mijowska E, Wen X, Tang T (2014) Striking influence of chain structure of polyethylene on the formation of cup-stacked carbon nanotubes/carbon nanofibers under the combined catalysis of CuBr and NiO. Appl Catal B Environ 147:592–601

    Article  Google Scholar 

  30. Du S, Lu Y, Malladi SK, Xu Q, Steinberger-Wilckens R (2014) A simple approach for PtNi-MWCNT hybrid nanostructures as high performance electrocatalysts for the oxygen reduction reaction. J Mater Chem A 2:692–698

    Article  Google Scholar 

  31. Li MW, Wu X, Zeng JH, Hou ZH, Liao SJ (2015) Heteroatom doped carbon nanofibers synthesized by chemical vapor deposition as platinum electrocatalyst supports for polymer electrolyte membrane fuel cells. Electrochim Acta 182:351–360

    Article  Google Scholar 

  32. Cui ZT, Wang SG, Zhang YH, Cao MH (2014) Engineering hybrid between nickel oxide and nickel cobaltate to achieve exceptionally high activity for oxygen reduction reaction. J Power Sources 272:808–815

    Article  Google Scholar 

  33. Youn DH, Bae G, Han S, Kim JY, Jang JW, Park H, Choi SH, Lee JS (2013) A highly efficient transition metal nitride-based electrocatalyst for oxygen reduction reaction: TiN on a CNT–graphene hybrid support. J Mater Chem A 1:8007–8015

    Article  Google Scholar 

  34. Sebastian D, Alegre C, Galvez ME, Moliner R, Lazaro MJ, Arico AS, Baglio V (2014) Towards new generation fuel cell electrocatalysts based on xerogel-nanofiber carbon composites. J Mater Chem A 2:13713–13722

    Article  Google Scholar 

  35. Kuo PL, Hsu CH, Li WT, Jhan JY, Chen WF (2010) Sea urchin-like mesoporous carbon material grown with carbon nanotubes as a cathode catalyst support for fuel cells. J Power Sources 195:7983–7990

    Article  Google Scholar 

  36. Wu X, Liu Z, Zeng JH, Hou ZH, Zhou WY, Liao SJ (2017) Platinum nanoparticles on interconnected Ni3P/carbon nanotube-carbon nanofiber hybrid supports with enhanced catalytic activity for fuel cells. ChemElectroChem 4:109–114

    Article  Google Scholar 

  37. Wang F, Arai S, Endo M (2005) The preparation of multi-walled carbon nanotubes with a Ni–P coating by an electroless deposition process. Carbon 43:1716–1721

    Article  Google Scholar 

  38. Zhang Y, Qi SH, Zhang F (2012) Preparation and characterization of multi-walled carbon nanotubes with nickel-phosphorous layers of high magnetic properties. Mater Res Bull 47:3743–3746

    Article  Google Scholar 

  39. Yang J, Lee JY, Deivaraj TC, Too HP (2004) Preparation and characterization of positively charged ruthenium nanoparticles. J Colloid Interf Sci 271:308–312

    Article  Google Scholar 

  40. Jarrah NA, Li F, Van Ommen JG, Lefferts L (2005) Immobilization of a layer of carbon nanofibres (CNFs) on Ni foam: a new structured catalyst support. J Mater Chem 15:1946–1953

    Article  Google Scholar 

  41. Lin JD, Kuo CL, Hsia CJ (2013) The influence of microwave-assisted hydrogen plasma treatment on electroless Ni–P coatings. Mater Chem Phys 137:848–858

    Article  Google Scholar 

  42. Xiang JY, Wang XL, Zhong J, Zhang D, Tu JP (2011) Enhanced rate capability of multi-layered ordered porous nickel phosphide film as anode for lithium ion batteries. J Power Sources 196:379–385

    Article  Google Scholar 

  43. Yang WB, Luo SK, Zhang BJ, Huang Z, Tang XH (2008) Electroless preparation and characterization of magnetic Ni–P plating on polyurethane foam. Appl Surf Sci 254:7427–7430

    Article  Google Scholar 

  44. Zeng JH, Lee JY, Chen JJ, Shen PK, Song SQ (2007) Increased metal utilization in carbon-supported Pt catalysts by adsorption of preformed Pt nanoparticles on colloidal silica. Fuel Cells 7:285–290

    Article  Google Scholar 

  45. Wu DF, Cheng D (2015) Core/shell AgNi/PtAgNi nanoparticles as methanol-tolerant oxygen reduction electrocatalysts. Electrochim Acta 180:316–322

    Article  Google Scholar 

  46. Guo QH, Zhao D, Liu SW, Chen SL, Hanif M, Hou HQ (2014) Free-standing nitrogen-doped carbon nanotubes at electrospun carbon nanofibers composite as an efficient electrocatalyst for oxygen reduction. Electrochim Acta 138:318–324

    Article  Google Scholar 

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Acknowledgements

The authors acknowledge the China Scholarship Council, National Natural Science Foundation of China (51572090) and Natural Science Foundation of Guangdong Province (2016A030313484) for their financial support on this work.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Guangdong Key Lab for Fuel Cell Technology, South China University of Technology, Guangzhou, 510641, China

    Xin Wu, Zhen Liu, Yangcheng Jiang, Jianhuang Zeng & Shijun Liao

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  1. Xin Wu
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  2. Zhen Liu
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Correspondence to Jianhuang Zeng.

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Wu, X., Liu, Z., Jiang, Y. et al. Randomly oriented Ni–P/nanofiber/nanotube composite prepared by electrolessly plated nickel–phosphorus alloys for fuel cell applications. J Mater Sci 52, 8432–8443 (2017). https://doi.org/10.1007/s10853-017-1094-6

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