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Journal of Materials Science

, Volume 52, Issue 11, pp 6486–6497 | Cite as

Layered microstructures based on BaZr0.85Y0.15O3−δ by pulsed laser deposition for metal-supported proton ceramic electrolyser cells

  • Elena StefanEmail author
  • Marit StangeEmail author
  • Christelle Denonville
  • Yngve Larring
  • Nicolas Hildenbrand
  • Truls Norby
  • Reidar Haugsrud
Original Paper

Abstract

Planar metal-supported cell designs provide cost-effective scaling-up of solid oxide fuel cells and electrolysers. Here, we report on the fabrication of a BaZr0.85Y0.15O3−δ–NiO (BZY15–NiO) composite electrode and BaZr0.85Y0.15O3−δ (BZY15) proton-conducting electrolyte films on metal and ceramic substrates using pulsed laser deposition (PLD). The results demonstrate successful sequential deposition of porous electrode and dense electrolyte structure by PLD at moderate temperatures, without the need for subsequent high-temperature sintering. The decrease in roughness of the metal substrate used for deposition by spray-coating intermediary oxide layers had significant importance to the fabrication of functional layers as thin films. Crystalline porous BZY15–NiO and dense BZY15 films were sequentially deposited at high substrate temperature on metal supports (MS) with or without an electron-conducting barrier oxide layer, e.g. MS/(BZY15–Ni)/(BZY15–NiO)/BZY15 and MS/CeO2/(BZY15–NiO)/BZY15. The different microstructures for electrode and electrolyte were achieved with deposition steps at different substrate temperatures (800, 600 °C) and a gradual decrease in the pressure of O2 in the deposition chamber.

Keywords

CeO2 Pulse Laser Deposition Electrolyte Film High Substrate Temperature Electrolyte Layer 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgements

Financial support from the Research Council of Norway (RCN) through the ENERGIX program (Project No: 228819/E20) is gratefully acknowledged.

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Copyright information

© Springer Science+Business Media New York 2017

Authors and Affiliations

  1. 1.Department of Chemistry, SMN/FERMiOUniversity of OsloOsloNorway
  2. 2.SINTEFOsloNorway
  3. 3.Solmates BVEnschedeThe Netherlands

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