Abstract
In this study, the Cr was added into Cu–Al–Mn alloys for replacing Cu and Mn, and the microstructure, martensitic transformation, stress–strain behavior, superelasticity and shape memory effect of quaternary Cu–Al–Mn–Cr shape memory alloys were investigated. All the studied alloys exhibit a mixed microstructure consisted of dominant L21 parent, small amounts of A2(Cr) and 2H(γ1′) martensite, as well as a reversible martensitic transformation. Although the alloys are main L21 parent before deformation, partial stress-induced 2H(γ1′) martensite can be stabilized and retained after unloading. Therefore, the same alloy under a certain deformation temperature not only exhibits superelasticity property during deformation, but also the deformed alloy also shows shape memory effect when heated. The results further show that Cu–12.8Al–7.5Mn–2.5Cr alloy has a good superelasticity strain of 2.9% as well as a shape memory effect of 1.5%. Cu–12.7Al–6.9Mn–1.8Cr alloy possesses much the best superelasticity strain close to 5.0% under a pre-deformation of 10% and a shape memory effect of 2.0%. The best shape memory effect up to 2.5% with 10% of pre-deformation and a superelasticity strain of 2.8% are obtained in Cu–12.5Al–5.8Mn–4.1Cr alloy.
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References
Otsuka K, Wayman CM (1998) Shape memory materials. Cambridge University Press, Cambridge
Otsuka K, Shimizu K (1986) Pseudoelasticity and shape memory effects in alloys. Int Met Rev 31:93–114
Otsuka K, Ren XB (1999) Recent developments in the research of shape memory alloys. Intermetallics 7:511–528
Otsuka K, Ren X (2005) Physical metallurgy of Ti–Ni-based shape memory alloys. Prog Mater Sci 50:511–678
Bonnot E, Romero R, Morin M et al (2008) In-situ observations of a martensitic transformation in a Cu–Zn–Al single crystal driven by stress or strain. J Mater Sci 43:3832. doi:10.1007/s10853-007-2218-1
Sarı U, Kırındı T (2008) Effects of deformation on microstructure and mechanical properties of a Cu–Al–Ni shape memory alloy. Mater Charact 59:920–929
Araki Y, Endo T, Omori T, Sutou Y In-situ observations of a martensitic transformation in a Cu–Zn–Al single crystal driven by stress or strain at springer link, Koetaka Y, Kainuma R et al (2011) Potential of superelastic Cu–Al–Mn alloy bars for seismic applications. Earthq Eng Struct Dyn 40:107–115
Stanford N, Dunne DP (2007) Martensite/particle interactions and the shape memory effect in an Fe–Mn–Si-based alloy. J Mater Sci 42:4334–4343. doi:10.1007/s10853-006-0686-3
Liu Y, Van Humbeeck J, Stalmans R, Delaey L (1997) Some aspects of the properties of NiTi shape memory alloy. J Alloy Compd 247:115–121
Kainuma R, Satoh N, Liu XJ, Ohnuma I, Ishida K (1998) Phase equilibria and Heusler phase stability in the Cu-rich portion of the Cu–Al–Mn system. J Alloy Compd 266:191–200
Xu HB (2001) Cu-based high-temperature shape-memory alloys and their thermal stability. Mater Sci Forum 394–3:375–382
Kainuma R, Takahashi S, Ishida K (1996) Thermoelastic martensite and shape memory effect in ductile Cu–Al–Mn alloys. MMTA 27:2187
Yang SY, Su Y, Wang CP, Liu XJ (2014) Microstructure and properties of Cu–Al–Fe high-temperature shape memory alloys. Mater Sci Eng B 185:67–73
Matlakhova LA, Pereira EC, Matlakhov AN, Monteiroa SN, Toledo R (2008) Mechanical behavior and fracture characterization of a monocrystalline Cu–Al–Ni subjected to thermal cycling treatments under load. Mater Charact 59:1630–1637
Nakata Y, Tadaki T, Shimizu K (1985) Thermal cycling effects in a Cu–Al–Ni shape memory alloy. J Jpn Inst Met 26:646–652
Wang CP, Su Y, Yang SY, Shi Z, Liu XJ (2014) A new type of Cu–Al–Ta shape memory alloy with high martensitic transformation temperature. Smart Mater Struct 23:025018–1–025018–7
Kainuma R, Takahashi S, Ishida K (1995) Ductility shape memory alloys of the Cu–Al–Mn system. J de Phys IV 5:961–966
Mallik US, Sampath V (2008) Influence of aluminum and manganese concentration on the shape memory characteristics of Cu–Al–Mn shape memory alloys. J Alloy Compd 59:142–147
Mallik US, Sampath V (2008) Effect of alloying on microstructure and shape memory characteristics of Cu–Al–Mn shape memory alloys. Mater Sci Eng A 481–482:680–683
Oliveira JP, Panton B et al (2016) Laser welded superelastic Cu–Al–Mn shape memory alloy wires. Mater Des 90:122–128
Sutou Y, Omori T, Okamoto T, Kainuma R, Ishida K (2001) Effect of grain refinement on the mechanical and shape memory properties of Cu–Al–Mn base alloys. J Phys IV France 11:185–190
Sutou Y, Omori T, Kainuma R, Ishida K (2013) Grain size dependence of pseudoelasticity in polycrystalline Cu–Al–Mn-based shape memory sheets. Acta Mater 61:3842–3850
Oliveira JP, Zeng Z et al (2016) Improvement of damping properties in laser processed superelastic Cu–Al–Mn shape memory alloys. Mater Des 98:280–284
Sutou Y, Koeda N, Omori T, Kainuma R, Ishida K (2009) Effects of aging on stress-induced martensitic transformation in ductile Cu–Al–Mn-based shape memory alloys. Acta Mater 57:5759–5770
Sutou Y, Koeda N, Omori T, Kainuma R, Ishida K (2009) Effects of aging on bainitic and thermally induced martensitic transformation in ductile Cu–Al–Mn-based shape memory alloys. Acta Mater 57:5748–5758
Sutou Y, Kainuma R, Ishida K (1999) Effect of alloying elements on the shape memory properties of ductile Cu–Al–Mn alloys. Mater Sci Eng A 273–275:375–379
Mallik US, Sampath V (2009) Influence of quaternary alloying additions on transformation temperatures and shape memory properties of Cu–Al–Mn shape memory alloy. J Alloy Compd 469:156–163
Ma YQ, Yang SY, Liu Y, Liu XJ (2009) The ductility and shape-memory properties of Ni–Mn–Co–Ga high-temperature shape-memory alloys. Acta Mater 57:3232–3241
Canbay CA, Gudeloglu S, Genc ZK (2015) Investigation of the enthalpy/entropy variation and structure of Cu–Al–Mn–Fe shape memory alloys. Int J Thermophys 36:783–794
Ortin J, Planes A (1988) Thermodynamic analysis of thermal measurements in thermoelastic martensitic transformations. Acta Metall 36:1873–1889
Canbay CA, Aydogdu A (2013) Thermal analysis of Cu–14.82 wt% Al–0.4 wt% Be shape memory alloy. J Therm Anal Calorim 113:731–737
Kainuma R et al (2006) Magnetic-field-induced shape recovery by reverse phase transformation. Nature 439:957–959
Tanaka Y et al (2010) Ferrous polycrystalline shape-memory alloy showing huge superelasticity. Science 327:1488–1490
Otsuka K, Wayman CM, Nakai K, Sakamota H, Shimizu K (1976) Superelasticity effects and stress-induced martensitic transformations in Cu–Al–Ni alloys. Acta Metall 24:207–226
Picornell C, Pons J, Cesari E (2001) Stabilization of martensite by applying compressive stress in Cu–Al–Ni single crystals. Acta Mater 49:4221–4230
Sedmák P, Šittner P, Pilch J, Curfs C (2015) Instability of cyclic superelastic deformation of NiTi investigated by synchrotron X-ray diffraction. Acta Mater 94:257–270
Oliveira JP, Miranda RM, Schell N, Fernandes FMB (2016) High strain and long duration cycling behavior of laser welded NiTi sheets. Int J Fatigue 83:195–200
Oliveira JP, Fernandes FMB, Schell N, Miranda RM (2016) Martensite stabilization during superelastic cycling of laser welded NiTi plates. Mater Lett 171:273–276
Yang SY, Omori T, Wang CP, Liu Y, Makoto N et al (2016) A jumping shape memory alloy under heat. Sci Rep 6:21754
Villars P, Calvert LD (1991) Pearson’s handbook of crystallographic data for intermetallic phases, 2nd edn. ASM, Materials Park
Massalski TB (1990) Binary alloy phase diagrams, 2nd edn. ASM International, Metals Park
Lee BJ (1993) A thermodynamic evaluation of the Cr–Mn and Fe–Cr–Mn systems. Metall Trans A 24A:1919–1933
Omori T, Kusama T et al (2013) Abnormal grain growth induced by cyclic heat treatment. Science 341:1500–1502
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We acknowledge the financial supports from the Fundamental Research Funds for the Central Universities, Grant number 20720160078, the National Natural Science Foundation of China, Grant numbers 51201145 and 51571168.
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Yang, S., Zhang, F., Wu, J. et al. Microstructure characterization, stress–strain behavior, superelasticity and shape memory effect of Cu–Al–Mn–Cr shape memory alloys. J Mater Sci 52, 5917–5927 (2017). https://doi.org/10.1007/s10853-017-0827-x
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DOI: https://doi.org/10.1007/s10853-017-0827-x