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Journal of Materials Science

, Volume 51, Issue 12, pp 5802–5810 | Cite as

Expanded graphite supported copper catalyst for effective oxidation of cyclohexene with molecular oxygen under mild conditions

  • Ruirong ZhangEmail author
  • Ruiren Tang
Original Paper

Abstract

A novel cross-shaped copper catalyst supported on an expanded graphite (Cu/EG) substrate was prepared by intermittent feeding. The catalyst was further characterized by scanning electronic microscopy, transmission electron microscopy, inductively coupled plasma, and X-ray diffraction. The results indicated that the Cu/EG exhibited a very high substrate conversion (99.1 %) and a good product (2-cyclohexene-1-one) selectivity (65.5 %) for the oxidation of cyclohexene using oxygen as the only oxidant under mild reaction conditions, and it could be reused with almost the same activity. Furthermore, if the economic benefits was considered, the 4.29 % Cu/EG might be the best catalyst in order to get more 2-cyclohexene-1-one.

Keywords

Cyclohexene Molecular Oxygen Expanded Graphite Flake Graphite Copper Catalyst 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  1. 1.Cleaner Electronics, School of Engineering and DesignBrunel University LondonLondonUK
  2. 2.School of Chemistry and Chemical EngineeringCentral South UniversityChangshaChina

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