SnO2 microfibers were prepared using a newly developed centrifugal spinning technology with subsequent thermal treatment. The as-prepared SnO2 microfibers were further treated with chemical vapor deposition (CVD) of acetylene using different durations of 30, 60, and 90 min. The surfaces of the CVD-treated SnO2 microfibers are covered with thin carbon layers, and the surface nanoparticles on the SnO2 microfibers were reduced by carbon, producing nano-sized Sn/C whiskers grafted on the backbones. The X-ray diffraction, scanning electron microscopy, and cyclic voltammetry results demonstrate that longer CVD coating duration promotes the formation of Sn/C whiskers on the SnO2 microfibers. The thin carbon coating layers help stabilize the solid electrolyte interface formation while the grafted Sn/C whiskers facilitate better electrolyte–electrode contact. Hence, the CVD-treated SnO2 microfibers exhibit higher initial capacities than the pristine SnO2 microfibers, as well as enhanced capacity retentions after cycling. The results suggest that centrifugal spinning is a promising approach to produce fibrous electrode materials in a rapid and mass production fashion, and the CVD coating process is an effective method to improve the electrochemical performance of the SnO2-based electrode materials.
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Ji L, Lin Z, Alcoutlabi M, Zhang X (2011) Recent developments in nanostructured anode materials for rechargeable lithium-ion batteries. Energy Environ Sci 4:2682–2699
Xue L, Fu K, Li Y, Xu G, Lu Y, Zhang S, Toprakci O, Zhang X (2013) Si/C composite nanofibers with stable electric conductive network for use as durable lithium-ion battery anode. Nano Energy 2:361–367
Li Y, Sun Y, Xu G, Lu Y, Zhang S, Xue L, Jur JS, Zhang X (2014) Tuning electrochemical performance of Si-based anodes for lithium-ion batteries by employing atomic layer deposition alumina coating. J Mater Chem A 2:11417
Zhang S, Lin Z, Ji L, Li Y, Xu G, Xue L, Li S, Lu Y, Toprakci O, Zhang X (2012) Cr-doped Li2MnSiO4/carbon composite nanofibers as high-energy cathodes for Li-ion batteries. J Mater Chem 22:14661–14666
Wang LP, Yu L, Wang X, Srinivasan M, Xu ZJ (2015) Recent developments in electrode materials for sodium-ion batteries. J Mater Chem A 3:9353–9378
Yabuuchi N, Kubota K, Dahbi M, Komaba S (2014) Research development on sodium-ion batteries. Chem Rev 114:11636–11682
Slater MD, Kim D, Lee E, Johnson CS (2013) Sodium-ion batteries. Adv Funct Mater 23:947–958
Ge P, Fouletier M (1988) Electrochemical intercalation of sodium in graphite. Solid State Ionics 30:1172–1175
Alcántara R, Jiménez Mateos JM, Tirado JL (2002) Negative electrodes for lithium- and sodium-ion batteries obtained by heat-treatment of petroleum cokes below 1000°C. J Electrochem Soc 149:A201–A205
Thomas P, Ghanbaja J, Billaud D, Poincare H, Nancy I (1999) Electrochemical insertion of sodium in pitch-based carbon fibres in comparison with graphite in NaClO4–ethylene carbonate electrolyte. Carbon 45:423–430
Stevens DA, Dahn JR (2001) The mechanisms of lithium and sodium insertion in carbon materials. J Electrochem Soc 148:A803–A811
Alcántara R, Jiménez-Mateos JM, Lavela P, Tirado JL (2001) Carbon black: a promising electrode material for sodium-ion batteries. Electrochem Commun 3:639–642
Wang H, Wu Z, Meng F, Ma D, Huang X, Wang L, Zhang X (2013) Nitrogen-doped porous carbon nanosheets as low-cost, high-performance anode material for sodium-ion batteries. ChemSusChem 6:56–60
Fu L, Tang K, Song K, van Aken PA, Yu Y, Maier J (2014) Nitrogen doped porous carbon fibres as anode materials for sodium ion batteries with excellent rate performance. Nanoscale 6:1384–1389
Cao Y, Xiao L, Sushko ML, Wang W, Schwenzer B, Xiao J, Nie Z, Saraf LV, Yang Z, Liu J (2012) Sodium ion insertion in hollow carbon nanowires for battery applications. Nano Lett 12:3783–3787
Chen T, Liu Y, Pan L, Lu T, Yao Y, Sun Z, Chua DHC, Chen Q (2014) Electrospun carbon nanofibers as anode materials for sodium ion batteries with excellent cycle performance. J Mater Chem A 2:4117–4121
Ge Y, Jiang H, Fu K, Zhang C, Zhu J, Chen C, Lu Y, Qiu Y, Zhang X (2014) Copper-doped Li4Ti5O12/carbon nanofiber composites as anode for high-performance sodium-ion batteries. J Power Sources 272:860–865
Pan H, Lu X, Yu X, Hu YS, Li H, Yang XQ, Chen L (2013) Sodium storage and transport properties in layered Na2Ti3O7 for room-temperature sodium-ion batteries. Adv Energy Mater 3:1186–1194
Ge Y, Jiang H, Zhu J, Lu Y, Chen C, Hu Y, Qiu Y, Zhang X (2015) High cyclability of carbon-coated TiO2 nanoparticles as anode for sodium-ion batteries. Electrochim Acta 157:142–148
Xue L, Xia X, Tucker T, Fu K, Zhang S, Li S, Zhang X (2013) A simple method to encapsulate SnSb nanoparticles into hollow carbon nanofibers with superior lithium-ion storage capability. J Mater Chem A 1:13807–13813
Li Y, Guo B, Ji L, Lin Z, Xu G, Liang Y, Zhang S, Toprakci O, Hu Y, Alcoutlabi M, Zhang X (2013) Structure control and performance improvement of carbon nanofibers containing a dispersion of silicon nanoparticles for energy storage. Carbon 51:185–194
Liu Y, Zhang N, Jiao L, Tao Z, Chen J (2015) Ultrasmall Sn nanoparticles embedded in carbon as high-performance anode for sodium-ion batteries. Adv Funct Mater 25:214–220
Zhu Y, Han X, Xu Y, Liu Y, Zheng S, Xu K, Hu L, Wang C (2013) Electrospun Sb/C fibers for a stable and fast sodium-ion battery anode. ACS Nano 7:6378–6386
Chen C, Fu K, Lu Y, Zhu J, Xue L, Hu Y, Zhang X (2015) Use of a tin antimony alloy-filled porous carbon nanofiber composite for use as anode in sodium-ion batteries. RSC Adv 5:30793–30800
Fu K, Xue L, Yildiz O, Li S, Lee H, Li Y, Xu G, Zhou L, Bradford PD, Zhang X (2013) Effect of CVD carbon coatings on Si@CNF composite as anode for lithium-ion batteries. Nano Energy 22:976–986
Wang Y, Su D, Wang C, Wang G (2013) SnO2@MWCNT nanocomposite as a high capacity anode material for sodium-ion batteries. Electrochem Commun 29:8–11
Su D, Ahn HJ, Wang G (2013) SnO2@graphene nanocomposites as anode materials for Na-ion batteries with superior electrochemical performance. Chem Commun 49:3131–3133
Xie X, Su D, Zhang J, Chen S, Mondal AK, Wang G (2015) A comparative investigation on the effects of nitrogen-doping into graphene on enhancing the electrochemical performance of SnO2/graphene for sodium-ion batteries. Nanoscale 7:3164–3172
Wang YX, Lim YG, Park MS, Chou SL, Kim JH, Liu HK, Dou SX, Kim YJ (2014) Ultrafine SnO2 nanoparticle loading onto reduced graphene oxide as anodes for sodium-ion batteries with superior rate and cycling performances. J Mater Chem A 2:529–534
Zhang X, Lu Y (2014) Centrifugal spinning: an alternative approach to fabricate nanofibers at high speed and low cost. Polym Rev 54:677–701
Lu Y, Fu K, Zhang S, Li Y, Chen C, Zhu J, Yanilmaz M, Dirican M, Zhang X (2015) Centrifugal spinning: a novel approach to fabricate porous carbon fibers as binder-free electrodes for electric double-layer capacitors. J Power Sources 273:502–510
Lu Y, Li Y, Zhang S, Xu G, Fu K, Lee H, Zhang X (2013) Parameter study and characterization for polyacrylonitrile nanofibers fabricated via centrifugal spinning process. Eur Polym J 49:3834–3845
Liu Y, Xu Y, Zhu Y, Culver JN, Lundgren CA, Xu K, Wang C (2013) Tin-coated viral nanoforests as sodium-ion battery anodes. ACS Nano 7:3627–3634
Xu Y, Zhu Y, Liu Y, Wang C (2013) Electrochemical performance of porous carbon/tin composite anodes for sodium-ion and lithium-ion batteries. Adv Energy Mater 3:128–133
Su D, Wang C, Ahn H, Wang G (2013) Octahedral tin dioxide nanocrystals as high capacity anode materials for Na-ion batteries. Phys Chem Chem Phys 15:12543–12550
Li L, Kovalchuk A, Tour JM (2014) SnO2-reduced graphene oxide nanoribbons as anodes for lithium ion batteries with enhanced cycling stability. Nano Res 7:1319–1326
Zhao X, Zhang Z, Yang F, Fu Y, Lai Y, Li J (2015) Core–shell structured SnO2 hollow spheres–polyaniline composite as an anode for sodium-ion batteries. RSC Adv 5:31465–31471
Tian Q, Zhang Z, Yang L, Hirano S, Mater J (2014) Synthesis of SnO2/Sn@ carbon nanospheres dispersed in the interspaces of a three-dimensional SnO2/Sn@ carbon nanowires network, and their application as an anode material for lithium-ion batteries. J Mater Chem A 2:12881–12887
Lian P, Zhu X, Liang S, Li Z, Yang W, Wang H (2011) High reversible capacity of SnO2/graphene nanocomposite as an anode material for lithium-ion batteries. Electrochim Acta 56:4532–4539
Zhou X, Yin YX, Wan LJ, Guo YG (2012) A robust composite of SnO2 hollow nanospheres enwrapped by graphene as a high-capacity anode material for lithium-ion batteries. J Mater Chem 22:17456–17459
This study was supported by National Science Foundation under Award Number CMMI-1231287.
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Lu, Y., Fu, K., Zhu, J. et al. Comparing the structures and sodium storage properties of centrifugally spun SnO2 microfiber anodes with/without chemical vapor deposition. J Mater Sci 51, 4549–4558 (2016). https://doi.org/10.1007/s10853-016-9768-z
- Chemical Vapor Deposition
- Discharge Capacity
- Electrochemical Performance
- Cyclic Voltammetry Curve