Journal of Materials Science

, Volume 51, Issue 9, pp 4470–4480

Robust mesoporous silica compacts: multi-scale characterization of microstructural changes related to physical–mechanical properties

  • Harsh Maheshwari
  • John D. Roehling
  • Bryce A. Turner
  • Jamal Abdinor
  • Tien B. Tran-Roehling
  • Milind D. Deo
  • Michael H. Bartl
  • Subhash H. Risbud
  • Klaus van Benthem
Original Paper

DOI: 10.1007/s10853-016-9759-0

Cite this article as:
Maheshwari, H., Roehling, J.D., Turner, B.A. et al. J Mater Sci (2016) 51: 4470. doi:10.1007/s10853-016-9759-0


Spark plasma sintering (SPS) was used to compact chemically synthesized mesoporous silica powders with ordered hexagonal nanopore channels (~5 nm). Solid compact disks (~19 mm diameter) densified at processing temperatures from 600 to 1000 °C were characterized at multiple length scales using scanning electron microscopy, transmission electron microscopy, Vickers hardness tests, and Brunauer–Emmett–Teller gas adsorption measurements. Microscopy revealed both micro- and nanoporosity in the compacted disks and the hexagonal mesopore channels in the starting powders were retained during SPS at temperatures up to 850 °C under a uniaxial pressure of 10.6 MPa. The degree of macroporosity in SPS samples was correlated to the mechanical properties, surface area, and pore morphology. The macroporosity is retained up to 950 °C under the same pressure, and the degree of macroporosity increases when the mesopores collapse due to individual particle shrinkage. The results of multi-scale characterization of the mesoporous silica compacts were used to shed light on the role of nanostructure and microstructure on the mechanical and physical properties of SPS processed compacted disks.

Supplementary material

10853_2016_9759_MOESM1_ESM.gif (20.1 mb)
Supplementary material 1 (GIF 20555 kb)
10853_2016_9759_MOESM2_ESM.mpg (11.2 mb)
Supplementary material 2 (MPG 11455 kb)
10853_2016_9759_MOESM3_ESM.pdf (119 kb)
Supplementary material 3 (PDF 118 kb)

Funding information

Funder NameGrant NumberFunding Note
Army Research Office
  • W911NF1210491
National Science Foundation
  • DMR-1005382

Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  1. 1.Department of Chemical Engineering and Materials ScienceUniversity of California, DavisDavisUSA
  2. 2.Department of ChemistryUniversity of UtahSalt Lake CityUSA
  3. 3.Department of Chemical EngineeringUniversity of UtahSalt Lake CityUSA
  4. 4.Department of Mechanical EngineeringUniversity of the PacificStocktonUSA

Personalised recommendations