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Effect of graphene concentration on thermal properties of alumina–graphene composites formed using spark plasma sintering

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Abstract

The thermal conductivity of carbon nanotubes (CNTs) and graphene is extremely high; nevertheless, the addition of CNTs into alumina produced conflicting results on its thermophysical characteristics. In the present study, a small amount, 0.88–8.5 vol%, of graphene was mixed with alumina. The green compacts were prepared by tape casting and laminating techniques. The composites were subsequently densified with spark plasma sintering technique. The addition of graphene produces lower density and smaller grain size after sintering. Consequently, these microstructure characteristics result in lower thermal conductivity. After correcting the effect of porosity and grain size, the addition of a small amount of graphene enhances slightly the thermal conductivity of alumina. As the amount of graphene is higher than 8 vol%, the thermal conductivity of composite is close to that of pure fine-grained alumina.

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References

  1. Rincón A, Chinelatto ASA, Moreno R (2014) Tape casting of alumina/zirconia suspensions containing graphene oxide. J Eur Ceram Soc 34(7):1819–1827

    Article  Google Scholar 

  2. Tjong SC (2013) Recent progress in the development and properties of novel metal matrix nanocomposites reinforced with carbon nanotubes and graphene nanosheets. Mater Sci Eng R 74(10):281–350

    Article  Google Scholar 

  3. Zhang SC, Fahrenholtz WG, Hilmas GE, Yadlowsky EJ (2010) Pressureless sintering of carbon nanotube-Al2O3 composites. J Eur Ceram Soc 30(6):1373–1380

    Article  Google Scholar 

  4. Porwal H, Tatarko P, Grasso S, Khaliq J, Dlouhý I, Reece MJ (2013) Graphene reinforced alumina nano-composites. Carbon 64:359–369

    Article  Google Scholar 

  5. Zhan GD, Kuntz JD, Wang H, Wang CM, Mukherjee AK (2004) Anisotropic thermal properties of single-wall-carbon-nanotube-reinforced nanoceramics. Phil Mag Lett 84(7):419–423

    Article  Google Scholar 

  6. Kumari L, Zhang T, Du GH et al (2008) Thermal properties of CNT-Alumina nanocomposites. Compos Sci Technol 68(9):2178–2183

    Article  Google Scholar 

  7. Ahmad K, Wei P, Wan CL (2014) Thermal conductivities of alumina-based multiwall carbon nanotube ceramic composites. J Mater Sci 49(17):6048–6055. doi:10.1007/s10853-014-8327-8

    Article  Google Scholar 

  8. Sung CM, Hu SC, Lin IC, Yu CP (2015) Graphene and hexagonal boron nitride planes and associated methods. US patent application publication 2015/0079352

  9. Rashad M, Pan FS, Tang AT, Asif M (2014) Effect of graphene nanoplatelets addition on mechanical properties of pure aluminum using a semi-powder method. Prog Nat Sci: Mater Int 24(2):101–108

    Article  Google Scholar 

  10. Chen CY, Tuan WH (2002) Evolution of mullite texture on firing tape-cast kaolin bodies. J Am Ceram Soc 85(5):1121–1126

    Article  Google Scholar 

  11. Bennison SJ, Harmer MP (1985) Swelling of hot-pressed Al2O3. J Am Ceram Soc 68(11):591–597

    Article  Google Scholar 

  12. Pop E, Varshney V, Roy AK (2012) Thermal properties of graphene: fundamentals and applications. MRS Bull 37(12):1273–1281

    Article  Google Scholar 

  13. Schlichting KW, Padture NP, Klemens PG (2001) Thermal conductivity of dense and porous yttria-stabilized zirconia. J Mater Sci 36(12):3003–3010. doi:10.1023/A:1017970924312

    Article  Google Scholar 

  14. Jang BK, Sakka Y (2008) Influence of microstructure on the thermophysical properties of sintered SiC ceramics. J Alloy Compd 463(1–2):493–497

    Article  Google Scholar 

  15. Hsu HC, Tuan WH (2016) Thermal characteristics of a two-phase composite. Adv Powder Tech 27:929–934

    Article  Google Scholar 

  16. Ashby MF (1993) Criteria for selecting the components of composites. Acta Metall Mater 41(5):1313–1335

    Article  Google Scholar 

  17. Inagaki M, Kaburagi Y, Hishiyama Y (2014) Thermal management material: graphite. Adv Eng Mater 16(5):494–506

    Article  Google Scholar 

Download references

Acknowledgements

The present study was supported by the Ministry of Science and Technology through the contract of MOST 104-2221-E-002-041.

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Authors and Affiliations

  1. Department of Materials Science and Engineering, National Taiwan University, Taipei, 106, Taiwan

    Chung-Jung Lin & Wei-Hsing Tuan

  2. RitaDia Co., Shin-Chu, 303, Taiwan

    I-Chiao Lin

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  1. Chung-Jung Lin
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  2. I-Chiao Lin
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  3. Wei-Hsing Tuan
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Correspondence to Wei-Hsing Tuan.

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Lin, CJ., Lin, IC. & Tuan, WH. Effect of graphene concentration on thermal properties of alumina–graphene composites formed using spark plasma sintering. J Mater Sci 52, 1759–1766 (2017). https://doi.org/10.1007/s10853-016-0467-6

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  • DOI: https://doi.org/10.1007/s10853-016-0467-6

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