Journal of Materials Science

, Volume 50, Issue 20, pp 6688–6699 | Cite as

Relationship between microstructure and mechanical properties in acid-treated carbon nanotube-reinforced alumina composites

  • Keiichi ShirasuEmail author
  • Go Yamamoto
  • Yo Nozaka
  • Weili Wang
  • Toshiyuki Hashida
Original Paper


Alumina composites reinforced with multiwalled carbon nanotubes (MWCNTs) at up to 3.7 vol% are prepared by a precursor method followed by a spark plasma sintering. We systematically and quantitatively investigate the effects of acid-treatment time of the MWCNTs on not only bending strength and fracture toughness of the composites but also on the mechanical strength and dispersibility of the MWCNTs, the grain size of the alumina matrix, and the interfacial strength between MWCNT and alumina. The main objective of this study is to evaluate how these parameters influence the mechanical properties with the aid of multiple regression analysis. We demonstrate that the matrix grain size, the mechanical strength of the MWCNTs, and the interfacial strength have little impact on the mechanical properties for the composites prepared in this study. On the other hand, the dispersibility of MWCNTs has the significant influence on the mechanical properties. Both the dispersibility of the MWCNTs and the mechanical properties of the composites increase as the acid-treatment time increases up to 2 h at low MWCNT content (0.9 vol%). Conversely, at a higher amount of MWCNTs, the degradation in the mechanical properties is shown to be associated with the deterioration of MWCNTs’ dispersibility. As MWCNT agglomerates are anticipated to act as imperfections, they may override the effects of the strength of MWCNTs, matrix grain size, and interfacial strength. By means of the multiple regression analysis, we quantitatively show that improving MWCNTs’ dispersibility is one of the most important factors in enhancing the mechanical properties of MWCNT/alumina composites.


Fracture Toughness Spark Plasma Sinter Alumina Matrix Interfacial Strength Dispersion Index 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.



The authors thank Dr. T. Miyazaki of the Technical Division, the School of Engineering, Tohoku University, for technical assistance in the TEM analysis. Dr. M. Watanabe, Industry Creation Hatchery Center, Tohoku University, is gratefully appreciated for his help in multiple regression analysis. This research was partially supported by the Grant-in-Aid for Scientific Research (S) 21226004 and Grant-in-Aid for Japan Society for the Promotion of Science (JSPS) 243582 and 2402358. This work was performed under the inter-university cooperative research program of the Advanced Research Center of Metallic Glasses, the Institute for Materials Research, Tohoku University.

Supplementary material

10853_2015_9223_MOESM1_ESM.docx (5.1 mb)
Supplementary material 1 (DOCX 5256 kb)


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Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • Keiichi Shirasu
    • 1
    Email author
  • Go Yamamoto
    • 1
  • Yo Nozaka
    • 1
  • Weili Wang
    • 2
  • Toshiyuki Hashida
    • 1
  1. 1.Fracture and Reliability Research InstituteTohoku UniversitySendaiJapan
  2. 2.Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, Ministry of EducationShandong UniversityJinanPeople’s Republic of China

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