Abstract
To improve the carbon dioxide (CO2) absorption performance of lithium orthosilicate (Li4SiO4), tablet-like Li4Si1−x Ti x O4 and Li3.9Na0.1Si0.96Ti0.04O4 sorbents with loose and porous texture were prepared by a sol–gel process. The relationship between the Ti doping and volume expansion was studied for the first time. The results indicated that the Ti presence into the Li4SiO4 structure inhibited the growth of grains and abated the volume expansion. The X-ray diffraction and scanning electron microscopy results showed that the loose and porous solid solutions with similar phase crystallite but different grain sizes could obtain by heat treatment of precursor at 700 °C. The optimum Ti content of Li4Si1−x Ti x O4 seems to be 0.04 of Li4Si0.96Ti0.04O4. And the CO2 capture behaviors of Li3.9Na0.1Si0.96Ti0.04O4 were better than Li4Si0.96Ti0.04O4.
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Xu H, Cheng W, Jin X (2013) Effect of the particle size of quartz powder on the synthesis and CO2 absorption properties of Li4SiO4 at high temperature. Ind Eng Chem Res 52(5):1886–1891
Seggiani M, Puccini M, Vitolo S (2011) High-temperature and low concentration CO2 sorption on Li4SiO4 based sorbents: study of the used silica and doping method effects. Int J Greenh Gas Control 5(4):741–748
Qi Z, Daying H, Yang L (2013) Analysis of CO2 sorption/desorption kinetic behaviors and reaction mechanisms on Li4SiO4. AIChE J 59(3):901–911
Nair BN, Burwood RP, Goh VJ (2009) Lithium based ceramic materials and membranes for high temperature CO2 separation. Prog Mater Sci 54(5):511–541
Mejía-Trejo VL, Fregoso-Israel E, Pfeiffer H (2008) Textural, structural, and CO2 chemisorption effects produced on the lithium orthosilicate by its doping with sodium (Li4−xNaxSiO4). Chem Mater 20(22):7171–7176
Radfarnia HR, liuta MCI (2011) Surfactant-template/ultrasound-assisted method for the preparation of porous nanoparticle lithium zirconate. Ind Eng Chem Res 50(15):9295–9305
Kato M, Yoshikawa S, Nakagawa KJ (2002) Carbon dioxide absorption by lithium orthosilicate in a wide range of temperature and carbon dioxide concentrations. J Mater Sci Lett 21(16):485–487
Gauer C, Heschel W (2006) Doped lithium orthosilicate for absorption of carbon dioxide. J Mater Sci 41(8):2405–2409. doi:10.1007/s10853-006-7070-1
Ida JI, Xiong R, Lin YS (2004) Synthesis and CO2 sorption properties of pure and modified lithium zirconate. Sep Purif Technol 36(1):41
Xiong R, Ida J, Lin YS (2003) Kinetics of carbon dioxide sorption on potassium-doped lithium zirconate. Chem Eng Sci 58(19):4377–4385
Essaki K, Kato M, Nakagawa K (2006) CO2 removal at high temperature using pace bed of lithium silicate pellets. J Ceram Soc Jpn 114(9):739–742
Rodrı´guez-Mosqueda R, Pfeiffer H (2010) Thermokinetic analysis of the CO2 chemisorption on Li4SiO4 by using different gas flow rates and particle sizes. J Phys Chem A 114(13):4535–4541
Venegas MJ, Fregoso-Israel E, Escamilla R (2007) Kinetic and reaction mechanism of CO2 sorption on Li4SiO4: study of the particle size effect. Ind Eng Chem Res 46(8):2407–2412
Zhang S, Zhang Q, Wang H (2014) Absorption behaviors study on doped Li4SiO4 under a humidified atmosphere with low CO2 concentration. Int J Hydrogen Energy 39(31):17913–17920
Pfeiffer H, Lima E, Bosch P (2006) Lithium-Sodium metazirconate solid solutions, Li2−x Na x ZrO3 (0 ≤ x ≤ 2): a hierarchical architecture. Chem Mater 18(11):2642–2647
Pfeiffer H, Vazquez C, Lara VH, Bosch P (2007) Thermal behavior and CO2 absorption of Li2−x Na x ZrO3 solid solutions. Chem Mater 19(4):922–926
Veliz-Enriquez MY, Gonzalez G, Pfeiffer H (2007) Synthesis and CO2 capture evaluation of Li2−x K x ZrO3 solid solutions and crystal structure of a new lithium–potassium zirconate phase. J Solid State Chem 180(9):2485–2492
Alcántar-Vázquez B, Diaz C, Romero-Ibarra IC (2013) Structural and CO2 chemisorption analyses on Na2(Zr1−x Al x )O3 solid solutions. J Phys Chem C 117(32):16483–16491
Ortiz-Landeros J, Romero-Ibarra IC, Gómez-Yáñez C (2013) Li4+x (Si1−x Al x )O4 Solid solution mechanosynthesis and kinetic analysis of the CO2 chemisorption process. J Phys Chem C. 117(12):6303–6311
Subha PV, Nair BN, Hareesh P (2014) Enhanced CO2 absorption kinetics in lithium silicate platelets synthesized by a sol–gel approach. J Mater Chem A 2(32):12792–12798
Ortiz-Landeros J, Gómez-Yáñez C, Palacios-Romero LM (2012) Structural and thermochemical chemisorption of CO2 on Li4+x (Si1−x Al x )O4 and Li4–x (Si1−x V x )O4 solid solutions. J Phys Chem A 116(12):3163–3171
Knitter R, Kolb MHH, Kaufmann U (2013) Fabrication of modified lithium orthosilicate pebbles by addition of titania. J Nucl Mater 442(1):S433–S436
Huheey JE (1981) Inorganic Chemistry, 2nd edn. Harper and Row, New York
Cotton FA, Wilkinson G (2001) Advanced inorganic chemistry, 9th edn. Limusa Noriega, Mexico
Duan Y, Pfeiffer H, Li B (2013) CO2 capture properties of lithium silicates with different ratios of Li2O/SiO2: an ab initio thermodynamic and experimental approach. Phys Chem Chem Phys 15(32):13538–13558
Khomane RB, Sharma BK, Saha S (2006) Reverse microemulsion mediated sol–gel synthesis of lithium silicate nanoparticles under ambient conditions: scope for CO2 sequestration. Chem Eng Sci 61(10):3415–3418
Choi KH, Korai Y, Mochida I (2003) Preparation of CO2 absorbent by spray pyrolysis. Chem Lett 32(10):924–925
Acknowledgements
This work has been financially supported by the National Natural Science Foundation of China (Nos. 51372017 and 51172019) and International Thermonuclear Experimental Reactor (ITER) Project of China (No. 2014GB123000).
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Xiang, M., Zhang, Y., Hong, M. et al. CO2 absorption properties of Ti- and Na-doped porous Li4SiO4 prepared by a sol–gel process. J Mater Sci 50, 4698–4706 (2015). https://doi.org/10.1007/s10853-015-9020-2
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DOI: https://doi.org/10.1007/s10853-015-9020-2