Abstract
Photocatalytic reduction of aqueous Cr(VI) was successfully achieved on SnS2/reduced graphene oxide (SnS2/RGO) nanocomposites. The SnS2/RGO nanocomposites have been synthesized via facile in situ hydrothermal reactions of SnCl4·5H2O, thiourea (NH2CSNH2), and graphene oxide nanosheets without any modified reagents. The physical and chemical properties of SnS2/RGO were studied by field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), Raman spectra, and UV–vis diffuse reflectance spectra. The photocatalytic reduction of aqueous Cr(VI) by SnS2/RGO nanocomposites was evaluated at ambient temperature under visible light (λ > 420 nm) irradiation. The SnS2/RGO nanocomposites exhibit excellent reduction efficiency of Cr(VI) (~90 %) than that of pure SnS2.
Similar content being viewed by others
References
Zhang YC, Li J, Xu HY (2012) One-step in situ solvothermal synthesis of SnS2/TiO2 nanocomposites with high performance in visible light-driven photocatalytic reduction of aqueous Cr(VI). Appl Catal B 123–124:18–26
Mouedhen G, Feki M, Ayedi HF (2009) Electrochemical removal of Cr(VI) from aqueous media using iron and aluminum as electrode materials: towards a better understanding of the involved phenomena. J Hazard Mater 168:983–991
Zhang YC, Du ZN, Li KW, Zhang M (2011) Size-controlled hydrothermal synthesis of SnS2 nanoparticles with high performance in visible light-driven photocatalytic degradation of aqueous methyl orange. Sep Purif Technol 81:101–107
Zhang YC, Li J, Zhang M, Dionysiou DD (2011) Size-tunable hydrothermal synthesis of SnS2 nanocrystals with high performance in visible light-driven photocatalytic reduction of aqueous Cr(VI). Environ Sci Technol 45:9324–9331
Hoffmann MR, Martin ST, Choi WY, Bahnemann DW (1995) Environmental applications of semiconductor photocatalysis. Chem Rev 95:69–96
Toh ML, Tan KJ, Wei FX, Zhang KK, Jiang H, Kloc C (2013) Intercalation of organic molecules into SnS2 single crystals. J Solid State Chem 198:224–230
Umar A, Akhtar MS, Dar GN, Abaker M, Al-Hajry A, Baskoutas S (2013) Visible-light-driven photocatalytic and chemical sensing properties of SnS2 nanoflakes. Talanta 114:183–190
Yao L, Zhang YC, Li J, Chen Y (2014) Photocatalytic properties of SnS2/SnO2 nanocomposite prepared by thermal oxidation of SnS2 nanoparticles in air. Sep Purif Tech 122:1–5
Liu X, Bai H (2013) Hydrothermal synthesis of visible light active zinc-doped tin disulfide photocatalyst for the reduction of aqueous Cr(VI). Powder Tech 237:610–615
Liu H, Su Y, Chen P, Wang Y (2013) Microwave-assisted solvothermal synthesis of 3D carnation-like SnS2 nanostructures with high visible light photocatalytic activity. J Mol Catal A 378:285–292
Wang QF, Huang Y, Miao J, Zhao Y, Wang Y (2013) Synthesis and electrochemical characterizations of Ce doped SnS2 anode materials for rechargeable lithium ion batteries. Electrochim Acta 93:120–130
Zhang YC, Yao L, Zhang GS, Dionysiou DD, Li J, Du XH (2014) One-step hydrothermal synthesis of high-performance visible-light-driven SnS2/SnO2 nanoheterojunction photocatalyst for the reduction of aqueous Cr(VI). Appl Catal B 144:730–738
Li J, Du XH, Yao L, Zhang YC (2014) Synthesis of SnS2/WO3 nanocomposite with enhanced photocatalytic activity. Mater Lett 121:44–46
Kim HS, Chung YH, Kang SH, Sung YE (2009) Electrochemical behavior of carbon-coated SnS2 for use as the anode in lithium-ion batteries. Electrochim Acta 54:3606–3610
Zhang QQ, Li R, Zhang M, Zhang B, Gou X (2014) SnS2/reduced graphene oxide nanocomposites with superior lithium storage performance. Electrochim Acta 115:425–433
Bian X, Lu X, Xue Y, Zhang C, Kong L, Wang C (2013) A facile one-pot hydrothermal method to produce SnS2/reduced graphene oxide with flake-on-sheet structures and their application in the removal of dyes from aqueous solution. J. Colloid Interf Sci 406:37–43
Xiang QJ, Yu JG, Jaroniec M (2012) Graphene-based semiconductor photocatalysts. Chem Soc Rev 41:782–796
Xiang QJ, Yu JG (2013) Graphene-based photocatalysts for hydrogen generation. J Phys Chem Lett 4:753–759
Yang XF, Cui HY, Li Y, Qin JL, Zhang RX, Tang H (2013) Fabrication of Ag3PO4-graphene composites with highly efficient and stable visible light photocatalytic performance. ACS Catal 3:363–369
Shi JJ, Zhou XY, Liu Y, Su QM, Zhang J, Du GH (2014) Sonochemical synthesis of CuS/reduced graphene oxide nanocomposites with enhanced absorption and photocatalytic performance. Mater Lett 126:220–223
Chang K, Chen WX (2011) L-Cysteine-assisted synthesis of Layered MoS2/graphene composites with excellent electrochemical performances for lithium ion batteries. ACS Nano 5:4720–4728
Chang K, Wang Z, Huang GC, Li H, Chen WX, Lee JY (2012) Few-layer SnS2/graphene hybrid with exceptional electrochemical performance as lithium-ion battery anode. J Power Sources 201:259–266
Xu YX, Sheng KX, Li C, Shi GQ (2010) Self-assembled graphene hydrogel via a one-step hydrothermal process. ACS Nano 4:4324–4330
Mu R, Xu Z, Li L, Shao Y, Wan H, Zheng S (2010) On the photocatalytic properties of elongated TiO2 nanoparticles for phenol degradation and Cr(VI) reduction. J Hazard Mater 176:495–502
Idris A, Hassan N, Ismail NSM, Misran E, Yusof NM, Ngomsik AF, Bee A (2010) Photocatalytic magnetic separable beads for chromium (VI) reduction. Water Res 44:1683–1688
Yang QL, Kang SZ, Chen H, Bu W, Mu J (2011) La2Ti2O7: an efficient and stable photocatalyst for the photoreduction of Cr(VI) ions in water. Desalination 266:149–153
Acknowledgements
This work was financially supported by the National Science Foundation of China (51272147), the Academic Backbone Cultivation Program of Shaanxi University of Science & Technology (XSGP201203), and the Graduate Innovation Found of Shaanxi University of Science and Technology.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Liu, H., Deng, L., Zhang, Z. et al. One-step in-situ hydrothermal synthesis of SnS2/reduced graphene oxide nanocomposites with high performance in visible light-driven photocatalytic reduction of aqueous Cr(VI). J Mater Sci 50, 3207–3211 (2015). https://doi.org/10.1007/s10853-015-8886-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-015-8886-3