Journal of Materials Science

, Volume 50, Issue 8, pp 3065–3074 | Cite as

Magnetically recoverable nano Pd/Fe3O4/ZnO catalyst: preparation, characterization, and application for the synthesis of 2-oxazolines and benzoxazoles

  • Mona Hosseini-Sarvari
  • Ameneh Khanivar
  • Fatemeh Moeini
Original Paper


A novel palladium-based catalysts supported on Fe3O4/ZnO nanoparticles have been prepared by a simple method. The catalyst was characterized by transmission electron microscopy, X-ray powder diffraction, X-ray photoelectron spectroscopy, atomic absorption spectrophotometry, FT-IR, and BET analysis. The catalyst afforded efficient synthesis of 2-oxazolines and benzoxazoles from aromatic nitriles under solvent-free conditions. The significant features of this method are short reaction times, good to high yields of the products, simple operation, solvent-free condition, non-toxicity, reusability of the catalyst without significant loss of catalytic activity, and using ultra small amount of Pd (0.004 g of catalyst contains 9.16 × 10−3 mmol Pd which was determined by ICP).


Benzonitrile External Magnet Benzoxazole Nanoparticle Catalyst Amino Alcohol 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.



We gratefully acknowledge the support of this work by the Shiraz University. We are also grateful to Mr. H. Sajedian Fard for helpful cooperation.


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Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • Mona Hosseini-Sarvari
    • 1
  • Ameneh Khanivar
    • 1
  • Fatemeh Moeini
    • 1
  1. 1.Department of ChemistryShiraz UniversityShirazIslamic Republic of Iran

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