Abstract
Magnesium (Mg)-modified mesoporous alumina with different type and content of Mg was prepared and then used as the support for platinum-tin catalyst in propane dehydrogenation. It was found that the property of Mg in Al2O3 varied with the way of the addition of Mg precursors. For the grafted Mg species, the connection between Al2O3 and Mg was increased by the forming of Mg–O–Al bonds in the inner surface of Al2O3 pore. While for the traditional impregnation, Mg was attached loosely to the outer Al2O3 surface by the aggregation of MgO. Moreover, modifying the internal framework of Al2O3 by suitable content of Mg can enhance the interaction between Sn and support, leading to more amounts of tin in their oxidized states, which was beneficial to enhance the interaction of Pt with SnOx species. As a result, agglomerations of metallic particles were suppressed and the catalyst exhibited the best catalytic performance in terms of activity and stability.
Similar content being viewed by others
References
Chen MA, Xu J, Cao Y, He HY, Fan KN, Zhuang JH (2010) Dehydrogenation of propane over In2O3–Al2O3 mixed oxide in the presence of carbon dioxide. J Catal 272:101–108
Jibril BY, Atta AY, Melghit K, El-Hadi ZM, Al-Muhtaseb AH (2012) Performance of supported Mg(0.15)V(2)O(5.15)2.4H(2)O nanowires in dehydrogenation of propane. Chem Eng J 193:391–395
Zhang YW, Zhou YM, Tang MH, Liu X, Duan YZ (2012) Effect of La calcination temperature on catalytic performance of PtSnNaLa/ZSM-5 catalyst for propane dehydrogenation. Chem Eng J 181:530–537
Sun P, Siddiqi G, Vining WC, Chi M, Bell AT (2011) Novel Pt/Mg(In)(Al)O catalysts for ethane and propane dehydrogenation. J Catal 282:165–174
Vu BK, Song MB, Ahn IY, Suh YW, Suh DJ, Kim WI, Koh HL, Choi YG, Shin EW (2011) Pt–Sn alloy phases and coke mobility over Pt–Sn/Al2O3 and Pt–Sn/ZnAl2O4 catalysts for propane dehydrogenation. Appl Catal A 400:25–33
Zhang YW, Zhou YM, Shi JJ, Sheng XL, Duan YZ, Zhou SJ, Zhang ZW (2012) Effect of zinc addition on catalytic properties of PtSnK/gamma-Al2O3 catalyst for isobutane dehydrogenation. Fuel Process Technol 96:220–227
Yu CL, Xu HY, Ge QJ, Li WZ (2007) Properties of the metallic phase of zinc-doped platinum catalysts for propane dehydrogenation. J Mol Catal A 266:80–87
Silvestre-Albero J, Serrano-Ruiz JC, Sepulveda-Escribano A, Rodriguez-Reinoso F (2008) Zn-modified MCM-41 as support for Pt catalysts. Appl Catal A 351:16–23
He SB, Sun CL, Bai ZW, Dai XH, Wang B (2009) Dehydrogenation of long chain paraffins over supported Pt–Sn–K/Al2O3 catalysts: a study of the alumina support effect. Appl Catal A 356:88–98
Zhang YW, Zhou YM, Shi JJ, Zhou SJ, Sheng XL, Zhang ZW, Xiang SM (2014) Comparative study of bimetallic Pt–Sn catalysts supported on different supports for propane dehydrogenation. J Mol Catal A 381:138–147
Zhang YW, Zhou YM, Shi JJ, Zhou SJ, Zhang ZW, Zhang SC, Guo MP (2013) Propane dehydrogenation over PtSnNa/La-doped Al2O3 catalyst: effect of La content. Fuel Process Technol 111:94–104
Zhang YW, Zhou YM, Qiu AD, Wang Y, Xu Y, Wu PC (2006) Propane dehydrogenation on PtSn/ZSM-5 catalyst: effect of tin as a promoter. Catal Commun 7:860–866
Angel GD, Bonilla A, Pena Y, Navarrete J, Fierro JLG, Acosta DR (2003) Effect of lanthanum on the catalytic properties of PtSn/gamma-Al2O3 bimetallic catalysts prepared by successive impregnation and controlled surface reaction. J Catal 219:63–73
Balasamy RJ, Tope BB, Khurshid A, Al-Ali AAS, Atanda LA, Sagata K, Asamoto M, Yahiro H, Nomura K, Sano T, Takehira K, Al-Khattaf SS (2011) Ethylbenzene dehydrogenation over FeOx/(Mg, Zn)(Al)O catalysts derived from hydrotalcites: role of MgO as basic sites. Appl Catal A 398:113–122
Kley I, Traa Y (2012) Influence of acid sites on the propene selectivity during propane dehydrogenation on zeolite Pt/Zn, Na-MCM-22. Microporous Mesoporous Mater 164:145–147
Zhang SB, Zhou YM, Zhang YW, Huang L (2010) Effect of K addition on catalytic performance of PtSn/ZSM-5 catalyst for propane dehydrogenation. Catal Lett 135:76–82
Bai LY, Zhou YM, Zhang YW, Liu H, Tang MH (2009) Influence of calcium addition on catalytic properties of PtSn/ZSM-5 catalyst for propane dehydrogenation. Catal Lett 129:449–456
Armendariz H, Guzman A, Toledo JA, Llanos ME, Vazquez A, Aguilar-Rios G (2001) Isopentane dehydrogenation on Pt–Sn catalysts supported on Al–Mg–O mixed oxides: effect of Al/Mg atomic ratio. Appl Catal A 211:69–80
Bai LY, Zhou YM, Zhang YW, Liu H, Sheng XL (2009) Effect of magnesium addition to PtSnNa/ZSM-5 on the catalytic properties in the dehydrogenation of propane. Ind Eng Chem Res 48:9885–9891
Zhang YW, Zhou YM, Wan LH, Xue MW, Duan YZ, Liu X (2011) Effect of magnesium addition on catalytic performance of PtSnK/gamma-Al2O3 catalyst for isobutane dehydrogenation. Fuel Process Technol 92:1632–1638
Xue MW, Zhou YM, Zhang YW, Huang L, Duan YZ (2012) Effects of Mg addition on catalytic performance of PtNa/Sn-ZSM-5 in propane dehydrogenation. Acta Phys Chim Sin 28:928–934
Dorado F, Romero R, Canizares P (2002) Hydroisomerization of n-butane over Pd/HZSM-5 and Pd/H beta with and without binder. Appl Catal A 236:235–243
Duan YZ, Zhou YM, Zhang YW, Sheng XL, Zhou SJ, Zhang ZW (2012) Effect of aluminum modification on catalytic properties of PtSn-based catalysts supported on SBA-15 for propane dehydrogenation. J Nat Gas Chem 21:207–214
Niknaddaf S, Soltani M, Farjoo A, Khorassheh F (2013) Modeling of coke formation and catalyst deactivation in propane dehydrogenation over a commercial Pt-Sn/gamma-Al2O3 catalyst. Pet Sci Technol 31:2451–2462
Valente JS, Lima E, Toledo-Antonio JA, Cortes-Jacome MA, Lartundo-Rojas L, Montiel R, Prince J (2010) Comprehending the thermal decomposition and reconstruction process of sol–gel MgAl layered double hydroxides. J Phys Chem C 114:2089–2099
Kumar PA, Reddy MP, Hyun-Sook B, Phil HH (2009) Influence of Mg addition on the catalytic activity of alumina supported Ag for C3H6-SCR of NO. Catal Lett 131:85–97
Gusmano G, Montesperelli G, Traversa E, Mattogno G (1993) Microstructure and electrical-properties of Mg-Al thin-films for humidity sensing. J Am Ceram Soc 76:743–750
Iriondo A, Barrio VL, Cambra JF, Arias PL, Guemez MB, Navarro RM, Sanchez-Sanchez MC, Fierro JLG (2008) Hydrogen production from glycerol over nickel catalysts supported on Al(2)O(3) modified by Mg, Zr, Ce or La. Top Catal 49:46–58
Xu BJ, Long J, Tian HP, Zhu YX, Sun X (2009) Synthesis and characterization of mesoporous gamma-alumina templated by saccharide molecules. Catal Today 147:46–50
Vu BK, Song MB, Ahn IY, Suh YW, Suh DJ, Kim WI, Koh HL, Choi YG, Shin EW (2011) Propane dehydrogenation over Pt–Sn/Rare-earth-doped Al2O3: influence of La, Ce, or Y on the formation and stability of Pt–Sn alloys. Catal Today 164:214–220
Kogan SB, Schramm H, Herskowitz M (2001) Dehydrogenation of propane on modified Pt/theta-alumina performance in hydrogen and steam environment. Appl Catal A 208:185–191
Barias OA, Holmen A, Blekkan EA (1995) Propane dehydrogenation over supported platinum catalysts—effect of tin as a promoter. Catal Today 24:361–364
Zhang YW, Zhou YM, Liu H, Wang Y, Xu Y, Wu PC (2007) Effect of La addition on catalytic performance of PtSnNa/ZSM-5 catalyst for propane dehydrogenation. Appl Catal A 333:202–210
Yu CL, Ge QJ, Xu HY, Li WZ (2006) Effects of Ce addition on the Pt–Sn/γ-Al2O3 catalyst for propane dehydrogenation to propylene. Appl Catal A 315:58–67
Burch R, Garla LC (1981) Platinum-tin reforming catalysts: activity and selectivity in hydrocarbon in hydrocarbon hydrocarbon reactions. J Catal 71:360–372
Ballarini AD, Ricci CG, de Miguel SR, Scelza OA (2008) Use of Al2O3–SnO2 as a support of Pt for selective dehydrogenation of light paraffins. Catal Today 133:28–34
Morales R, Melo L, Llanos A, Zaera F (2005) Characterization of bifunctional PtSn/H Al ZSM5 catalysts: a comparison between two impregnation strategies. J Mol Catal A 228:227–232
Larsson M, Hulten M, Blekkan EA, Andersson B (1996) The effect of reaction conditions and time on stream on the coke formed during propane dehydrogenation. J Catal 164:44–53
Acknowledgements
The authors are grateful to the financial supports of the National Natural Science Foundation of China (Grant No. 21376051, 21106017, 21306023 and 51077013), the Natural Science Foundation of Jiangsu (Grant No. BK20131288), Fund Project for Transformation of Scientific and Technological Achievements of Jiangsu Province of China (Grant No. BA2011086), Specialized Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20100092120047), Key Program for the Scientific Research Guiding Found of Basic Scientific Research Operation Expenditure of Southeast University (Grant No. 3207043101) and Instrumental Analysis Fund of Southeast University.
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Shi, J., Zhou, Y., Zhang, Y. et al. Synthesis of magnesium-modified mesoporous Al2O3 with enhanced catalytic performance for propane dehydrogenation. J Mater Sci 49, 5772–5781 (2014). https://doi.org/10.1007/s10853-014-8303-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-014-8303-3