Abstract
The development of fluorescent materials with low energy consumption, low cost and desirable optical properties is needed for the perspective of practical application. Here, functional NaLa(MoO4)2@CdTe core–shell microspheres with high fluorescence were prepared by layer-by-layer self-assembly technique. Through the consecutive electrostatic adsorption of charged cetyltrimethyl ammonium bromide and CdTe quantum dots (QDs), the uniform and regular multilayer shell of CdTe QDs was synthesized. The NaLa(MoO4)2@CdTe microspheres exhibited improved photoluminescence intensity and stability of red emission, compared with that of the CdTe QDs powder, and the fluorescence enhancement mechanism were investigated. The CdTe QDs multilayer shell is expected to supersede the Eu3+ ion for producing a novel red phosphor.








Similar content being viewed by others
Explore related subjects
Discover the latest articles and news from researchers in related subjects, suggested using machine learning.References
Caruso F, Caruso RA, Möhwald H (1998) Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating. Science 282:1111
Fu J, Wang M, Zhang C, Wang X, Wang H, Xu Q (2013) Template-induced covalent assembly of hybrid particles for the facile fabrication of magnetic Fe3O4-polymer hybrid hollow microspheres. J Mater Sci 48:3557
Wei S, Wang Q, Zhu J, Sun L, Lin H, Guo Z (2011) Multifunctional composite core–shell nanoparticles. Nanoscale 3:4474
Sukhorukov GB, Donath E, Lichtenfeld H, Knippel E, Knippel M, Budde A, Möhwald H (1998) Layer-by-layer self assembly of polyelectrolytes on colloidal particles. Coll Surf A: Physicochem Eng Asp 137:253
Oh JS, Luong ND, Hwang TS, Hong JP, Lee YK, Nam JD (2013) In situ fabrication of platinum/graphene composite shell on polymer microspheres through reactive self-assembly and in situ reduction. J Mater Sci 48:1127
Caruso F, Möhwald H (1999) Preparation and characterization of ordered nanoparticle and polymer composite multilayers on colloids. Langmuir 15:8276
Yang D, Tian M, Wang W, Li D, Li R, Liu H, Zhang L (2012) Controllable dielectric and electrical performance of polymer composites with novel core/shell-structured conductive particles through biomimetic method. Electrochim Acta 87:9
Zhang H, Cui Z, Wang Y, Zhang K, Ji X, Lü C, Gao M (2003) From water-soluble CdTe nanocrystals to fluorescent nanocrystal-polymer transparent composites using polymerizable surfactants. Adv Mater 15:777
Gao MY, Lesser C, Kirstein S, Mohwald H, Rogach AL, Well H (2000) Electroluminescence of different colors from polycation/CdTe nanocrystal self-assembled films. J Appl Phys 87:2297
Caruso F (2001) Nanoengineering of particle surfaces. Adv Mater 13:11
Zhang W, Mu B, Wang A (2013) Preparation of manganese dioxide/multiwalled carbon nanotubes hybrid hollow microspheres via layer-by-layer assembly for supercapacitor. J Mater Sci 48:7581
Hu J, Chen M, Fang XS, Wu LM (2011) Fabrication and application of inorganic hollow spheres. Chem Soc Rev 40:5472
Lin YW, Tseng WL, Chang HT (2006) Using a layer-by-layer assembly technique to fabricate multicolored-light-emitting films of CdSe@CdS and CdTe quantum dots. Adv Mater 18:1381
Yang Y, Wen Z, Dong Y, Gao M (2006) Incorporating CdTe nanocrystals into polystyrene microspheres: towards robust fluorescent beads. Small 2:898
Li Y, Wang G, Pan K, Zhou W, Wang C, Fan N, Zhao B (2012) Controlled synthesis and luminescence properties of rhombic NaLn(MoO4)2 submicrocrystals. Cryst EngComm 14:5015
Wu T, Liu Y, Lu Y, Wei L, Gao H, Chen H (2013) Morphology-controlled synthesis, characterization, and luminescence properties of KEu(MoO4)2 microcrystals. CrystEngComm 15:2761
Kumar A, Kumar J (2011) Perspective on europium activated fine-grained metal molybdate phosphors for solid state illumination. J Mater Chem 21:3788
Liu J, Xu B, Song C, Luo H, Zou X, Han L, Yu X (2012) Shape-controlled synthesis of monodispersed nano-/micro-NaY(MoO4)2 (doped with Eu3+) without capping agents via a hydrothermal process. Cryst Eng Comm 14:2936
Bendall JS, Paderi M, Ghigliotti F, Pira NL, Lambertini V, Lesnyak V, Marchese L (2010) Layer-by-layer all-inorganic quantum-dot-based LEDs: a simple procedure with robust performance. Adv Funct Mater 20:3298
Gong Y, Gao M, Wang D, Möhwald H (2005) Incorporating fluorescent CdTe nanocrystals into a hydrogel via hydrogen bonding: toward fluorescent microspheres with temperature-responsive properties. Chem Mat 17:2648
Voigt A, Lichtenfeld H, Sukhorukov GB, Zastrow H, Donath E, Bäumler H, Möhwald H (1999) Membrane filtration for microencapsulation and microcapsules fabrication by layer-by-layer polyelectrolyte adsorption. Ind Eng Chem Res 38:4037
Donath E, Sukhorukov GB, Caruso F, Davis SA, Möhwald H (1998) Novel hollow polymer shells by colloid-templated assembly of polyelectrolytes. Angew Chem Int Ed 37:2201
Vesely CJ, Langer DW (1971) Electronic core levels of the IIB–VIA compounds. Phys Rev B 4:451
Zhang H, Yang B, Wang R, Zhang G, Hou X, Wu L (2002) Fabrication of a covalently attached self-assembly multilayer film based on CdTe nanoparticles. J Coll Interface Sci 247:361
Rogach AL, Klar TA, Lupton JM, Meijerink A, Feldmann J (2009) Energy transfer with semiconductor nanocrystals. J Mater Chem 19:1208
Lee YB, Park S, Lee S, Kim J, Lee KS, Joo J (2013) Nanoscale luminescence characteristics of CdSe/ZnS quantum dots hybridized with organic and metal nanowires: energy transfer effects. J Mater Chem C 1:2145
Zhang H, Zhou Z, Yang B, Gao M (2003) The Influence of carboxyl groups on the photoluminescence of mercaptocarboxylic acid-stabilized CdTe nanoparticles. J Phys Chem B 107:8
Gao M, Kirstein S, Möhwald H, Rogach AL, Kornowski A, Eychmüller A, Weller H (1998) Strongly photoluminescent CdTe nanocrystals by proper surface modification. J Phys Chem B 102:8360
Ni T, Nagesha DK, Robles J, Materer NF, Müssig S, Kotov NA (2002) CdS Nanoparticles modified to chalcogen sites: new supramolecular complexes, butterfly bridging, and related optical effects. J Am Chem Soc 124:3980
Gerbec JA, Magana D, Washington A, Strouse GF (2005) Microwave-enhanced reaction rates for nanoparticle synthesis. J Am Chem Soc 127:15791
Takagahara T (1993) Effects of dielectric confinement and electron-hole exchange interaction on excitonic states in semiconductor quantum dots. Phys Rev B 47:4569
Biju V, Makita Y, Sonoda A, Yokoyama H, Baba Y, Ishikawa M (2005) Temperature-sensitive photoluminescence of CdSe quantum dot clusters. J Phys Chem B 109:13899
Acknowledgements
The authors acknowledge the financial support from Priority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions and Program for Changjiang Scholars and Innovative Research Team in University (PCSIRT), IRT1146.
Author information
Authors and Affiliations
Corresponding authors
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Chen, H., Liu, Y., Lu, Y. et al. Using layer-by-layer assembly to fabricate NaLa(MoO4)2@CdTe core–shell microspheres with high fluorescence. J Mater Sci 49, 4506–4512 (2014). https://doi.org/10.1007/s10853-014-8149-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-014-8149-8


